2-Pivaloylpterin, an acylated deriv. of the biochem. relevant pterin 2-amino-4-oxo-(3H)pteridine heterocyclus, undergoes stepwise metalation by the 1,1'-bis(diphenylphosphino)ferrocene-copper(I) cation, (dppf)Cu+. The final product obtained, Cu3(dppf)(m2-dppf)(PP)(PP-H+)2(BF4)4, could be structurally characterized to reveal coordinative satn. with binding of central Cu+ ions to N1,N3,O4,N5,N8 and pivaloyl-O donor atoms. on SciFinder(R)
%0 Journal Article
%1 Jana.2015b
%A Jana, Rajkumar
%A Lissner, Falk
%A Kaim, Wolfgang.
%D 2015
%J Zeitschrift fuer Anorganische und Allgemeine Chemie
%K complex copper diphosphinoferrocene hexanuclear pivaloylpterin prepn structure structure;crystal
%N 2
%P 261--265
%R 10.1002/zaac.201400529
%T Coordinative Saturation of the Pterin Heterocycle by Ferrocenylcopper(I) Complex Fragments
%V 641
%X 2-Pivaloylpterin, an acylated deriv. of the biochem. relevant pterin 2-amino-4-oxo-(3H)pteridine heterocyclus, undergoes stepwise metalation by the 1,1'-bis(diphenylphosphino)ferrocene-copper(I) cation, (dppf)Cu+. The final product obtained, Cu3(dppf)(m2-dppf)(PP)(PP-H+)2(BF4)4, could be structurally characterized to reveal coordinative satn. with binding of central Cu+ ions to N1,N3,O4,N5,N8 and pivaloyl-O donor atoms. on SciFinder(R)
@article{Jana.2015b,
abstract = {2-Pivaloylpterin, an acylated deriv. of the biochem. relevant pterin [2-amino-4-oxo-(3H)pteridine] heterocyclus, undergoes stepwise metalation by the 1,1'-bis(diphenylphosphino)ferrocene-copper(I) cation, [(dppf)Cu]+. The final product obtained, [Cu3(dppf)(\textgreek{m}2-dppf)(PP)(PP-H+)]2(BF4)4, could be structurally characterized to reveal coordinative satn. with binding of central Cu+ ions to N1,N3,O4,N5,N8 and pivaloyl-O donor atoms. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Jana, Rajkumar and Lissner, Falk and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/265c2e9b4201799c2048375bd0bcfb5a3/huebleriac},
doi = {10.1002/zaac.201400529},
interhash = {f30b8bc7db55d8d228eb2d8f9c7364c4},
intrahash = {65c2e9b4201799c2048375bd0bcfb5a3},
issn = {0044-2313},
journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie},
keywords = {complex copper diphosphinoferrocene hexanuclear pivaloylpterin prepn structure structure;crystal},
number = 2,
pages = {261--265},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Coordinative Saturation of the Pterin Heterocycle by Ferrocenylcopper(I) Complex Fragments},
volume = 641,
year = 2015
}