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Tetranuclear mixed valent manganese complexes with reduced TCNE or TCNQ as h4-bridged ligands

, and . Angewandte Chemie, 99 (3): 257--259 (1987)

Abstract

Photolysis of CpMn(CO)2THF (I, Cp = h5-methylcyclopentadienyl, h5-pentamethylcyclopentadienyl) with TCNE or TCNQ gave CpMn+(CO)2 (L = TCNE, TCNQ, which with addnl. I gave m,h4-L- CpMn+(CO)2CpMn(CO)2. on SciFinder(R)

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