Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N-Heterocyclic Carbene Complexes : NMR data and link to crystallographic data
R. Schowner, W. Frey, and M. Buchmeiser. Dataset, (2021)Related to: Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N-Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922. doi: 10.1002/ejic.201900021.
DOI: 10.18419/darus-1705
Abstract
Data on novel synthetic approaches to molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl-substituted imido ligands, highly basic 6-Mes (6-Mes = 1,3-dimesityl-3,4,5,6-tetrahydropyrimidin-2-ylidene) NHC ligands and the preparation of the first representatives of cationic 14-electron Mo imido alkylidene NHC catalysts bearing sterically demanding anionic terphenoxide ligands. Synthetic approaches and data are presented in the research article. Herein, we publish all primary data files of NMR measurements related to the research article mentioned under related publications. The data files are structured according to the numbering of the molecules in the research article. Additionally, a PDF-file including all the molecular structures and their numbers has been added. Crystallographic data was published in the CCDC as stated under related datasets . This dataset contains the following data types: NMR data (raw data, Bruker-zip files)
Related to: Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N-Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922. doi: 10.1002/ejic.201900021
%0 Generic
%1 schowner2021replication
%A Schowner, Roman
%A Frey, Wolfgang
%A Buchmeiser, Michael
%D 2021
%K darus mult ubs_10003 ubs_10018 ubs_20003 ubs_20023 ubs_30034 ubs_30036 ubs_30203 ubs_40064 unibibliografie
%R 10.18419/darus-1705
%T Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N-Heterocyclic Carbene Complexes : NMR data and link to crystallographic data
%X Data on novel synthetic approaches to molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl-substituted imido ligands, highly basic 6-Mes (6-Mes = 1,3-dimesityl-3,4,5,6-tetrahydropyrimidin-2-ylidene) NHC ligands and the preparation of the first representatives of cationic 14-electron Mo imido alkylidene NHC catalysts bearing sterically demanding anionic terphenoxide ligands. Synthetic approaches and data are presented in the research article. Herein, we publish all primary data files of NMR measurements related to the research article mentioned under related publications. The data files are structured according to the numbering of the molecules in the research article. Additionally, a PDF-file including all the molecular structures and their numbers has been added. Crystallographic data was published in the CCDC as stated under related datasets . This dataset contains the following data types: NMR data (raw data, Bruker-zip files)
@misc{schowner2021replication,
abstract = {Data on novel synthetic approaches to molybdenum imido alkylidene N-heterocyclic carbene (NHC) complexes including the first NHC alkylidene complexes featuring pentafluorophenyl-substituted imido ligands, highly basic 6-Mes (6-Mes = 1,3-dimesityl-3,4,5,6-tetrahydropyrimidin-2-ylidene) NHC ligands and the preparation of the first representatives of cationic 14-electron Mo imido alkylidene NHC catalysts bearing sterically demanding anionic terphenoxide ligands. Synthetic approaches and data are presented in the research article. Herein, we publish all primary data files of NMR measurements related to the research article mentioned under related publications. The data files are structured according to the numbering of the molecules in the research article. Additionally, a PDF-file including all the molecular structures and their numbers has been added. Crystallographic data was published in the CCDC as stated under related datasets . This dataset contains the following data types: NMR data (raw data, Bruker-zip files)},
added-at = {2022-03-08T18:43:13.000+0100},
affiliation = {Schowner, Roman/Universität Stuttgart, Frey, Wolfgang/Universität Stuttgart, Buchmeiser, Michael/Universität Stuttgart},
author = {Schowner, Roman and Frey, Wolfgang and Buchmeiser, Michael},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2596c40bbcf547eb1015038dc3b2489eb/unibiblio},
doi = {10.18419/darus-1705},
howpublished = {Dataset},
interhash = {9b01d4220f8a989065fe11922dd0fcdd},
intrahash = {596c40bbcf547eb1015038dc3b2489eb},
keywords = {darus mult ubs_10003 ubs_10018 ubs_20003 ubs_20023 ubs_30034 ubs_30036 ubs_30203 ubs_40064 unibibliografie},
note = {Related to: Schowner, R., Frey, W. and Buchmeiser, M.R. (2019), Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N-Heterocyclic Carbene Complexes. Eur. J. Inorg. Chem., 2019, 1911-1922. doi: 10.1002/ejic.201900021},
orcid-numbers = {Schowner, Roman/0000-0003-1728-2203, Frey, Wolfgang/0000-0002-6522-4190, Buchmeiser, Michael/0000-0001-6472-5156},
timestamp = {2022-06-02T07:50:43.000+0200},
title = {Replication data for: Understanding Synthetic Peculiarities of Cationic Molybdenum(VI) Imido Alkylidene N-Heterocyclic Carbene Complexes : NMR data and link to crystallographic data},
year = 2021
}