%0 Journal Article %1 Kaim.1981j %A Kaim, Wolfgang. %D 1981 %J Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie %K ESR;phosphoranylidene electrochem phosphinylbenzene redn %N 2 %P 150--156 %T Reaction of aromatic phosphoranylidene derivatives with electrons. I %V 36B %X The compds. p-Me2P(X)C6H4P(X)Me2 (X = O, S, Se, NPh) undergo one-electron redn. at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixt. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2PC6H4PMe2̅.bul. with the coordinated groups X. on SciFinder(R)

@article{Kaim.1981j, abstract = {The compds. p-Me2P(X)C6H4P(X)Me2 (X = O, S, Se, NPh) undergo one-electron redn. at a mercury cathode or on reaction with solvated electrons in a K/18-crown-6/THF mixt. The radical anions formed are persistent and have been characterized by ESR. They may be described as complexes of the spin-bearing moiety p-Me2PC6H4PMe2̅.bul. with the coordinated groups X. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2d2b8da9b0a85b99367089ba3f9d1f5a2/huebleriac}, interhash = {256447d7eb1ac11f00bc84b681a9fbd4}, intrahash = {d2b8da9b0a85b99367089ba3f9d1f5a2}, issn = {0340-5087}, journal = {Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie}, keywords = {ESR;phosphoranylidene electrochem phosphinylbenzene redn}, number = 2, pages = {150--156}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Reaction of aromatic phosphoranylidene derivatives with electrons. I}, volume = {36B}, year = 1981 }