A resolved ESR spectrum of a Ru(II) polyazine radical complex was obsd. in the binuclear species ((bpy)4Ru2(dptz)3+ (dptz: 3,6-di-2-pyridyl-1,2,4,5-tetrazine). ESR in conjunction with HMO McLachlan calcns. reveal the localization of the unpaired electron in the tetrazine p system and a strongly polarizing effect of the Ru(bpy)22+ fragment. on SciFinder(R)
%0 Journal Article
%1 Kaim.1985g
%A Kaim, W.
%A Ernst, S.
%A Kohlmann, S.
%A Welkerling, P.
%D 1985
%J Chemical Physics Letters
%K ESR bipyridyl cation;tetrazine complex electron localization pyridyltetrazine ruthenium
%N 4
%P 431--434
%R 10.1016/0009-2614(85)85405-1
%T First observation of resolved ESR hyperfine structure for a reduced ruthenium(II) polyazine complex
%V 118
%X A resolved ESR spectrum of a Ru(II) polyazine radical complex was obsd. in the binuclear species ((bpy)4Ru2(dptz)3+ (dptz: 3,6-di-2-pyridyl-1,2,4,5-tetrazine). ESR in conjunction with HMO McLachlan calcns. reveal the localization of the unpaired electron in the tetrazine p system and a strongly polarizing effect of the Ru(bpy)22+ fragment. on SciFinder(R)
@article{Kaim.1985g,
abstract = {A resolved ESR spectrum of a Ru(II) polyazine radical complex was obsd. in the binuclear species ([(bpy)4Ru2(dptz)]3+ (dptz: 3,6-di-2-pyridyl-1,2,4,5-tetrazine). ESR in conjunction with HMO McLachlan calcns. reveal the localization of the unpaired electron in the tetrazine \textgreek{p} system and a strongly polarizing effect of the [Ru(bpy)2]2+ fragment. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Kaim, W. and Ernst, S. and Kohlmann, S. and Welkerling, P.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/24fc6553d01d07521b0f79e89c285261b/huebleriac},
doi = {10.1016/0009-2614(85)85405-1},
interhash = {aa27df873b9fd167157c743b786fc721},
intrahash = {4fc6553d01d07521b0f79e89c285261b},
issn = {0009-2614},
journal = {Chemical Physics Letters},
keywords = {ESR bipyridyl cation;tetrazine complex electron localization pyridyltetrazine ruthenium},
number = 4,
pages = {431--434},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {First observation of resolved ESR hyperfine structure for a reduced ruthenium(II) polyazine complex},
volume = 118,
year = 1985
}