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Evidence for the 1-thia-3-sila-2,4-diazetidine heterocyclic system with three parallel lone pairs from an ESR spectroscopic study of its cation radical

, and . Journal of the Chemical Society, Chemical Communications, (1989)
DOI: 10.1039/c39890000469

Abstract

Formation of the new electron-rich heterocyclic system I, an intermediate during the reductive cyclosilylation of Me3CN:S:NCMe3 with Me2SiCl2/2Li, was established by an ESR spectroscopic anal. of its persistent cation radical after oxidn. with AlCl3/CH2Cl2. on SciFinder(R)

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