Benzyldimethylarsine complexes of Pd(II) and Pt(II) [MX2(BzAsMe2)2] (X = Cl, Br, I), [M2Cl2(m-Cl)2(BzAsMe2)2], [Pd2Cl2(m-OAc)2(BzAsMe2)2], [Pd2Me2(m-Cl)2(BzAsMe2)2] and [Pd2X2(m-N-N)2(BzAsMe2)2] (M = Pd or Pt; N-N = pyrazolate (pz) or 3,5-dimethylpyrazolate (dmpz)) were prepd. All complexes were characterized by elemental anal., IR, UV-visible absorption and NMR (1H, 13C, 195Pt) spectroscopy. The mol. structures of [MX2(BzAsMe2)2] (M = Pt or Pd; X = Cl, Br or I) were established by NMR spectroscopy and single crystal x-ray diffraction anal. and reveal a clear dichotomy in soln. and in the solid between the compds. with X = Cl in a cis configuration and the trans configured bromide and iodide complexes. [on SciFinder(R)]
%0 Journal Article
%1 Phadnis.2003b
%A Phadnis, Prasad P.
%A Jain, Vimal K.
%A Klein, Axel
%A Weber, Michael
%A Kaim, Wolfgang.
%D 2003
%J Inorganica Chimica Acta
%K NMR;cis acetato benzyldimethylarsine benzyldimethylarsine;crystal bridged chloro cis correlation dinuclear halo isomer mononuclear palladium platinum prepn pyrazolato structure trans trans;platinum
%P 119--128
%R 10.1016/S0020-1693(02)01375-0
%T Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures
%V 346
%X Benzyldimethylarsine complexes of Pd(II) and Pt(II) [MX2(BzAsMe2)2] (X = Cl, Br, I), [M2Cl2(m-Cl)2(BzAsMe2)2], [Pd2Cl2(m-OAc)2(BzAsMe2)2], [Pd2Me2(m-Cl)2(BzAsMe2)2] and [Pd2X2(m-N-N)2(BzAsMe2)2] (M = Pd or Pt; N-N = pyrazolate (pz) or 3,5-dimethylpyrazolate (dmpz)) were prepd. All complexes were characterized by elemental anal., IR, UV-visible absorption and NMR (1H, 13C, 195Pt) spectroscopy. The mol. structures of [MX2(BzAsMe2)2] (M = Pt or Pd; X = Cl, Br or I) were established by NMR spectroscopy and single crystal x-ray diffraction anal. and reveal a clear dichotomy in soln. and in the solid between the compds. with X = Cl in a cis configuration and the trans configured bromide and iodide complexes. [on SciFinder(R)]
@article{Phadnis.2003b,
abstract = {Benzyldimethylarsine complexes of Pd(II) and Pt(II) [MX2(BzAsMe2)2] (X = Cl, Br, I), [M2Cl2(\textgreek{m}-Cl)2(BzAsMe2)2], [Pd2Cl2(\textgreek{m}-OAc)2(BzAsMe2)2], [Pd2Me2(\textgreek{m}-Cl)2(BzAsMe2)2] and [Pd2X2(\textgreek{m}-N-N)2(BzAsMe2)2] (M = Pd or Pt; N-N = pyrazolate (pz) or 3,5-dimethylpyrazolate (dmpz)) were prepd. All complexes were characterized by elemental anal., IR, UV-visible absorption and NMR (1H, 13C, 195Pt) spectroscopy. The mol. structures of [MX2(BzAsMe2)2] (M = Pt or Pd; X = Cl, Br or I) were established by NMR spectroscopy and single crystal x-ray diffraction anal. and reveal a clear dichotomy in soln. and in the solid between the compds. with X = Cl in a cis configuration and the trans configured bromide and iodide complexes. [on SciFinder(R)]},
added-at = {2022-06-15T11:26:56.000+0200},
author = {Phadnis, Prasad P. and Jain, Vimal K. and Klein, Axel and Weber, Michael and Kaim, Wolfgang.},
biburl = {https://puma.ub.uni-stuttgart.de/bibtex/207a2f3ef6fa31097e3b66e2af5ebf7b0/huebleriac},
doi = {10.1016/S0020-1693(02)01375-0},
interhash = {84a828c84e707709202dc089040c0615},
intrahash = {07a2f3ef6fa31097e3b66e2af5ebf7b0},
issn = {0020-1693},
journal = {Inorganica Chimica Acta},
keywords = {NMR;cis acetato benzyldimethylarsine benzyldimethylarsine;crystal bridged chloro cis correlation dinuclear halo isomer mononuclear palladium platinum prepn pyrazolato structure trans trans;platinum},
pages = {119--128},
timestamp = {2022-06-15T09:26:56.000+0200},
title = {Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures},
volume = 346,
year = 2003
}
