Article,

An optogalvanic gas sensor based on Rydberg excitations

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Journal of Physics B: Atomic, Molecular and Optical Physics, 53 (9): 094001 (March 2020)
DOI: 10.1088/1361-6455/ab728e

Abstract

We investigate the properties of a trace-gas sensing scheme based on Rydberg excitations at the example of an idealized model system. Rydberg states in thermal rubidium (Rb) are created using a 2-photon cw excitation. These Rydberg-excited atoms ionize via collisions with a background gas of nitrogen (N2). The emerging charges are then measured as an electric current, which is on the order of several picoampere. Due to the 2-photon excitation, this sensing method has a large intrinsic selectivity combined with a promising sensitivity of 10 ppb at an absolute concentration of 1 ppm. The determination of the detection limit is limited by the optical reference measurement but is at least 500 ppb.

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