%0 Journal Article %1 Li.2014 %A Li, Yan %A Mondal, Kartik Chandra %A Samuel, Prinson P. %A Zhu, Hongping %A Orben, Claudia M. %A Panneerselvam, Saravanan %A Dittrich, Birger %A Schwederski, Brigitte %A Kaim, Wolfgang %A Mondal, Totan %A Koley, Debasis %A Roesky, Herbert W. %D 2014 %J Angewandte Chemie, International Edition %K air cation cumulene dication radical stable %N 16 %P 4168--4172 %R 10.1002/anie.201310975 %T C4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication %V 53 %X A neutral C4 cumulene 1 that includes a cyclic alkyl(amino) carbene (cAAC), its air-stable radical cation 1.+, and dication 12+ have been synthesized. The redox property of 1.+ was studied by cyclic voltammetry. EPR and theor. calcns. show that the unpaired electron in 1.+ is mainly delocalized over the central C4 backbone. The com. available CBr4 is utilized as a source of dicarbon in the cumulene synthesis. [on SciFinder(R)]

@article{Li.2014, abstract = {A neutral C4 cumulene 1 that includes a cyclic alkyl(amino) carbene (cAAC), its air-stable radical cation 1.+, and dication 12+ have been synthesized. The redox property of 1.+ was studied by cyclic voltammetry. EPR and theor. calcns. show that the unpaired electron in 1.+ is mainly delocalized over the central C4 backbone. The com. available CBr4 is utilized as a source of dicarbon in the cumulene synthesis. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Li, Yan and Mondal, Kartik Chandra and Samuel, Prinson P. and Zhu, Hongping and Orben, Claudia M. and Panneerselvam, Saravanan and Dittrich, Birger and Schwederski, Brigitte and Kaim, Wolfgang and Mondal, Totan and Koley, Debasis and Roesky, Herbert W.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/21276e2ab81aa7eb899c7fe45d4d555d7/huebleriac}, doi = {10.1002/anie.201310975}, interhash = {f9b513e0e90c9725330acac26abe4638}, intrahash = {1276e2ab81aa7eb899c7fe45d4d555d7}, issn = {1433-7851}, journal = {Angewandte Chemie, International Edition}, keywords = {air cation cumulene dication radical stable}, number = 16, pages = {4168--4172}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {C4 Cumulene and the Corresponding Air-Stable Radical Cation and Dication}, volume = 53, year = 2014 }