%0 Journal Article %1 Kumbhare.2010 %A Kumbhare, Liladhar B. %A Wadawale, Amey P. %A Jain, Vimal K. %A Sieger, Monika %A Kaim, Wolfgang. %D 2010 %J Inorganic Chemistry Communications %K binuclear bridged complex complex;rhodium crystal iridium metalated monoselenocarboxylate ortho phenylcarboselenolate prepn prepn;mol structure %N 4 %P 475--478 %R 10.1016/j.inoche.2010.01.012 %T Binuclear rhodium(III) and iridium(III) monoselenocarboxylates: Synthesis, spectroscopy and structure of an ortho-metalated iridium complex featuring an IrCCC(m-Se) chelate ring %V 13 %X Monoselenocarboxylate-bridged binuclear complexes of RhIII and IrIII, [(Cp*MCl)2(m-SeCOAr)2] (M = Rh or Ir; Cp* = pentamethylcyclopentadienyl; Ar = Ph, C6H4Me-4), have been isolated either by the reaction between [Cp*2M2(m-Cl)2Cl2] with KSeCOAr in acetonitrile or by treatment of [Cp*MCl(solvent)2][PF6] with KSeCOAr in acetone. The novel binuclear complexes, [Cp*IrCl(m-SeCOAr)(k2-SeCOC6H3R-)IrCp*] (R = H or Me-4) with ortho-metalation at one of the iridium centers have been isolated following the use of excess AgPF6. The single crystal structure of [Cp*IrCl(m-SeCOC6H5)(k2-SeCOC6H4-)IrCp*] exhibits two phenylcarboselenolate moieties situated in syn fashion with respect to the \dqIr2Se2\dq plane, one of which leans towards the metal center in order to undergo ortho-metalation after iridium-chlorine bond dissocn. [on SciFinder(R)]

@article{Kumbhare.2010, abstract = {Monoselenocarboxylate-bridged binuclear complexes of RhIII and IrIII, [(Cp*MCl)2(\textgreek{m}-SeCOAr)2] (M = Rh or Ir; Cp* = pentamethylcyclopentadienyl; Ar = Ph, C6H4Me-4), have been isolated either by the reaction between [Cp*2M2(\textgreek{m}-Cl)2Cl2] with KSeCOAr in acetonitrile or by treatment of [Cp*MCl(solvent)2][PF6] with KSeCOAr in acetone. The novel binuclear complexes, [Cp*IrCl(\textgreek{m}-SeCOAr)(\textgreek{k}2-SeCOC6H3R-)IrCp*] (R = H or Me-4) with ortho-metalation at one of the iridium centers have been isolated following the use of excess AgPF6. The single crystal structure of [Cp*IrCl(\textgreek{m}-SeCOC6H5)(\textgreek{k}2-SeCOC6H4-)IrCp*] exhibits two phenylcarboselenolate moieties situated in syn fashion with respect to the {\dq}Ir2Se2{\dq} plane, one of which leans towards the metal center in order to undergo ortho-metalation after iridium-chlorine bond dissocn. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kumbhare, Liladhar B. and Wadawale, Amey P. and Jain, Vimal K. and Sieger, Monika and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2ee9bdb2bde10fd4d1578a16aa8fa3190/huebleriac}, doi = {10.1016/j.inoche.2010.01.012}, interhash = {f94f77c9e40d915f6e8bf5ba432aafca}, intrahash = {ee9bdb2bde10fd4d1578a16aa8fa3190}, issn = {1387-7003}, journal = {Inorganic Chemistry Communications}, keywords = {binuclear bridged complex complex;rhodium crystal iridium metalated monoselenocarboxylate ortho phenylcarboselenolate prepn prepn;mol structure}, number = 4, pages = {475--478}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Binuclear rhodium(III) and iridium(III) monoselenocarboxylates: Synthesis, spectroscopy and structure of an ortho-metalated iridium complex featuring an IrCCC(\textgreek{m}-Se) chelate ring}, volume = 13, year = 2010 }