Article,

Radical ions. 9. Radical cations of tetrasilyl-substituted hydrazines

, , and .
Angewandte Chemie, 88 (22): 766--767 (1976)

Abstract

The difference of 14N coupling in bicyclic and open chain hydrazine radical cations (I and II) ($\sim$1.2G) is smaller than the difference of the corresponding coupling consts. for the alkyl derivs. (III and IV)(5.7G). The results were rationalized in terms of differences in SiNSi and CNC bond angles. [on SciFinder(R)]

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