%0 Journal Article %1 Bulak.2021 %A Bulak, Ece %A Dogan, Ilknur %A Varnali, Tereza %A Schwederski, Brigitte %A Gunal, Sule Erol %A Lonnecke, Peter %A Bubrin, Martina %A Kaim, Wolfgang %D 2021 %J European Journal of Inorganic Chemistry %K imported %N 24 %P 2425-2432 %R 10.1002/ejic.202100277 %T An Acyclic Diaminocarbene Complex of Platinum Formed by Desulfurization of 1,3-Bis(3-methylpyridin-2-yl)thiourea %V 2021 %X The reaction of the ambidentate ligand 1,3-bis(3-methylpyridin-2-yl)thiourea (1) with [PtCl2(dmso)2] in dichloromethane led to formation of a poorly soluble compound 2, characterized as a conventional chelate complex [PtCl2(1)] = 2. Reaction in methanol resulted in desulfurization to produce a fluorescing cationic diaminocarbene-platinum(II) complex 3, the structure of which was elucidated by x-ray crystallog., mass spectrometry and NMR. Exptl. findings were supported by DFT calculations

@article{Bulak.2021, abstract = {The reaction of the ambidentate ligand 1,3-bis(3-methylpyridin-2-yl)thiourea (1) with [PtCl2(dmso)2] in dichloromethane led to formation of a poorly soluble compound 2, characterized as a conventional chelate complex [PtCl2(1)] = 2. Reaction in methanol resulted in desulfurization to produce a fluorescing cationic diaminocarbene-platinum(II) complex 3, the structure of which was elucidated by x-ray crystallog., mass spectrometry and NMR. Exptl. findings were supported by DFT calculations}, added-at = {2022-06-15T12:05:25.000+0200}, author = {Bulak, Ece and Dogan, Ilknur and Varnali, Tereza and Schwederski, Brigitte and Gunal, Sule Erol and Lonnecke, Peter and Bubrin, Martina and Kaim, Wolfgang}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/246ac01885a5be38bbf903feaec9380b1/huebleriac}, doi = {10.1002/ejic.202100277}, interhash = {b5a216d8e8f9b2d5ebdd80b9c40f6d3b}, intrahash = {46ac01885a5be38bbf903feaec9380b1}, issn = {1434-1948}, journal = {European Journal of Inorganic Chemistry}, keywords = {imported}, number = 24, pages = {2425-2432}, timestamp = {2022-06-15T10:05:25.000+0200}, title = {An Acyclic Diaminocarbene Complex of Platinum Formed by Desulfurization of 1,3-Bis(3-methylpyridin-2-yl)thiourea}, volume = 2021, year = 2021 }