%0 Journal Article %1 Kohlmann.1985 %A Kohlmann, Stephan %A Ernst, Sylvia %A Kaim, Wolfgang. %D 1985 %J Angewandte Chemie %K azodipyridine charge dipyridyltetrazine dipyridyltetrazine;molybdenum dipyridyltetrazine;ruthenium dipyridyltetrazine;transition dipyridyltetrazine;tungsten metal transfer;dipyridyltetrazine transfer;manganese transition %N 8 %P 698--699 %T Extremely long-wavelength charge-transfer absorption of binuclear complexes with azo-modified 2,2'-bipyridyl ligands %V 97 %X [M(CO)4]2L (M = Mo, W; L = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine), [fac-Mn(CO)3Br]2L, [Ru(bpy)2]2L(PF6)4 (bpy = 2,2'-bipyridine), [Mo(CO)4]2L1 (L1 = azo-2,2'-dipyridine), and [Ru(bpy)2]2L1(PF6)4 were prepd. The long wavelength charge-transfer absorption max. is obsd. in the near-IR region for all the complexes. [M(CO)4]2L, [Ru(bpy)2]2L(PF6)4, and [Mo(CO)4]2L1 were reduced electrochem. at $\sim$0 V. The complexes were characterized by NMR spectra. [on SciFinder(R)]

@article{Kohlmann.1985, abstract = {[M(CO)4]2L (M = Mo, W; L = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine), [fac-Mn(CO)3Br]2L, {[Ru(bpy)2]2L}(PF6)4 (bpy = 2,2'-bipyridine), [Mo(CO)4]2L1 (L1 = azo-2,2'-dipyridine), and {[Ru(bpy)2]2L1}(PF6)4 were prepd. The long wavelength charge-transfer absorption max. is obsd. in the near-IR region for all the complexes. [M(CO)4]2L, {[Ru(bpy)2]2L}(PF6)4, and [Mo(CO)4]2L1 were reduced electrochem. at $\sim$0 V. The complexes were characterized by NMR spectra. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kohlmann, Stephan and Ernst, Sylvia and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2be508f5a9c96e9010174c2020dcb3806/huebleriac}, interhash = {b2b6bb70421b93d007791aac89569e2d}, intrahash = {be508f5a9c96e9010174c2020dcb3806}, issn = {0044-8249}, journal = {Angewandte Chemie}, keywords = {azodipyridine charge dipyridyltetrazine dipyridyltetrazine;molybdenum dipyridyltetrazine;ruthenium dipyridyltetrazine;transition dipyridyltetrazine;tungsten metal transfer;dipyridyltetrazine transfer;manganese transition}, number = 8, pages = {698--699}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Extremely long-wavelength charge-transfer absorption of binuclear complexes with azo-modified 2,2'-bipyridyl ligands}, volume = 97, year = 1985 }