Article,

Experimental and theoretical studies on the synthesis, spectroscopic data, and reactions of formyl azide

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Angew. Chemie - Int. Ed., 51 (19): 4718–4721 (2012)
DOI: 10.1002/anie.201200029

Abstract

Small is beautiful: spectroscopic proof or any other indication for the existence of formyl azide (HC(O)N(3) ) has until now been lacking. Although it liberates dinitrogen much more rapidly than homologous acyl azides, it has been prepared for the first time by four different methods.

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