%0 Journal Article %1 Albrecht.2000 %A Albrecht, Markus %A Hubler, Klaus %A Kaim, Wolfgang. %D 2000 %J Zeitschrift fuer Anorganische und Allgemeine Chemie %K complex complex;silver crystal prepn silver structure thiomethylbenzimidazole %N 5 %P 1033--1037 %R 10.1002/(SICI)1521-3749(200005)626:5\textless1033::AID-ZAAC1033\textgreater3.0.CO;2-A %T Syntheses, structures, and properties of the complexes Ag(N-S)n(X), N-S = 1-methyl-2-(alkylthiomethyl)-1H-benzimidazoles, X = PF6 (n = 2) or PO2F2 (n = 1) %V 626 %X Ag(h2-N-S)2(PF6), N-S = 1-methyl-2-(methylthiomethyl)-1H-benzimidazole, mmb (1) or 1-methyl-2-(tert-butylthiomethyl)-1H-benzimidazole, mtb (2), and Ag(m,h2-mmb)(m,h2-O2PF2) (3) were synthesized and characterized by x-ray crystallog. Long Ag-S ($\sim$2.70 \AA) and shorter Ag-N bonds ($\sim$2.23 \AA) are part of characteristically distorted tetrahedral coordination arrangements at the Ag(I) ions in 1 and 2. Unexpectedly, the comparison with Cu(h2-mmb)2(PF6) reveals a more tetrahedral and less linear coordination arrangement for the corresponding Ag species. 3 As obtained by hydrolysis of the PF6 ion or using AgPO2F2 exhibits bridging mmb and h2-difluorophosphate ligands in a chain-type structure. on SciFinder(R)

@article{Albrecht.2000, abstract = {[Ag(\textgreek{h}2-N-S)2](PF6), N-S = 1-methyl-2-(methylthiomethyl)-1H-benzimidazole, mmb (1) or 1-methyl-2-(tert-butylthiomethyl)-1H-benzimidazole, mtb (2), and [Ag(\textgreek{m},\textgreek{h}2-mmb)(\textgreek{m},\textgreek{h}2-O2PF2)] (3) were synthesized and characterized by x-ray crystallog. Long Ag-S ($\sim$2.70 {\AA}) and shorter Ag-N bonds ($\sim$2.23 {\AA}) are part of characteristically distorted tetrahedral coordination arrangements at the Ag(I) ions in 1 and 2. Unexpectedly, the comparison with [Cu(\textgreek{h}2-mmb)2](PF6) reveals a more tetrahedral and less linear coordination arrangement for the corresponding Ag species. 3 As obtained by hydrolysis of the PF6 ion or using AgPO2F2 exhibits bridging mmb and \textgreek{h}2-difluorophosphate ligands in a chain-type structure. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Albrecht, Markus and Hubler, Klaus and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/26d71583a55cee7f3b28d887f79d231ec/huebleriac}, doi = {10.1002/(SICI)1521-3749(200005)626:5{\textless}1033::AID-ZAAC1033{\textgreater}3.0.CO;2-A}, interhash = {0ff8dce8e831836636986f5f2033b84e}, intrahash = {6d71583a55cee7f3b28d887f79d231ec}, issn = {0044-2313}, journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie}, keywords = {complex complex;silver crystal prepn silver structure thiomethylbenzimidazole}, number = 5, pages = {1033--1037}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Syntheses, structures, and properties of the complexes [Ag(N-S)n](X), N-S = 1-methyl-2-(alkylthiomethyl)-1H-benzimidazoles, X = PF6 (n = 2) or PO2F2 (n = 1)}, volume = 626, year = 2000 }