%0 Journal Article %1 Dorst:im2412 %A Dorst, Konstantin %A Frey, Wolfgang %A Wang, Dongren %A Buchmeiser, Michael %D 2013 %J Acta Crystallographica Section E %K %N 1 %P m28 %R 10.1107/S1600536812049513 %T ($\eta$$6$-p-Cymene)(1,3-dimesityl-2,3-dihydro-1H-imidazol-2-yl\-idene)bis\-(pentafluorobenzoato-$\kappa$O)ruthenium(II) dichloro\-methane disolvate %U https://doi.org/10.1107/S1600536812049513 %V 69 %X The title compound, [Ru(C$7$F$5$O$2$)$2$(C$10$H$14$)(C$21$H$24$N$2$)]$\cdot$2CH$2$Cl$2$, is formed as an orange crystalline powder by the reaction of RuCl$2$(p-cymene)(IMes) and AgOCOC$6$F$5$ in anhydrous tetra\-hydro\-furan (IMes = 1,3-dimesityl-2,3-di\-hydro-1H-imidazol-2-yl\-idene). The asymetric unit consists of two independent [Ru(C$6$F$5$COO)$2$($\eta$$6$-p-cymene)(IMes)] com\-plexes and four dichloro\-methane solvent mol\-ecules. In each complex molecule, the Ru atom presents a pseudo-octa\-hedral environment with the p-cymene ligand occupying three facial coordination sites, while the remaining coordination positions are occupied by the O atoms of the penta\-fluoro\-benzoate ligands and by the imidazolyl\-idene ligand.

@article{Dorst:im2412, abstract = {The title compound, [Ru(C${\sb 7}$F${\sb 5}$O${\sb 2}$)${\sb 2}$(C${\sb 10}$H${\sb 14}$)(C${\sb 21}$H${\sb 24}$N${\sb 2}$)]{$\cdot$}2CH${\sb 2}$Cl${\sb 2}$, is formed as an orange crystalline powder by the reaction of RuCl${\sb 2}$({\it p}-cymene)(IMes) and AgOCOC${\sb 6}$F${\sb 5}$ in anhydrous tetra{\-}hydro{\-}furan (IMes = 1,3-dimesityl-2,3-di{\-}hydro-1{\it H}-imidazol-2-yl{\-}idene). The asymetric unit consists of two independent [Ru(C${\sb 6}$F${\sb 5}$COO)${\sb 2}$({$\eta$}${\sp 6}$-{\it p}-cymene)(IMes)] com{\-}plexes and four dichloro{\-}methane solvent mol{\-}ecules. In each complex molecule, the Ru atom presents a pseudo-octa{\-}hedral environment with the {\it p}-cymene ligand occupying three facial coordination sites, while the remaining coordination positions are occupied by the O atoms of the penta{\-}fluoro{\-}benzoate ligands and by the imidazolyl{\-}idene ligand.}, added-at = {2025-01-15T10:48:25.000+0100}, author = {Dorst, Konstantin and Frey, Wolfgang and Wang, Dongren and Buchmeiser, Michael}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/2415bb7dbb1599ec6b87ff591c74e5dc3/dwang}, doi = {10.1107/S1600536812049513}, interhash = {0ca2bc25912785eff163f77f8a41b8ff}, intrahash = {415bb7dbb1599ec6b87ff591c74e5dc3}, journal = {Acta Crystallographica Section E}, keywords = {}, month = jan, number = 1, pages = {m28}, timestamp = {2025-01-15T09:48:25.000+0100}, title = {{({$\eta$}${\sp 6}$-{\it p}-Cymene)(1,3-dimesityl-2,3-dihydro-1{\it H}-imidazol-2-yl{\-}idene)bis{\-}(pentafluorobenzoato-{$\kappa$}{\it O})ruthenium(II) dichloro{\-}methane disolvate}}, url = {https://doi.org/10.1107/S1600536812049513}, volume = 69, year = 2013 }