%0 Journal Article %1 Kaim.1981c %A Kaim, Wolfgang. %D 1981 %J Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie %K anion beryllium complex complex;ESR complex;magnesium complex;pyrazine complex;zinc metal pyrazine radical %N 9 %P 1110--1116 %T Coordination chemistry of reduced N-heterocycles. Complexes of pyrazine anion radical with phenyl metal cations +MPh of beryllium, magnesium and zinc %V 36B %X The diphenyls MPh2 (M = Be, Mg, Zn, Cd, Hg) were treated with pyrazine (Pz) in THF. Only the Mg deriv. undergoes electron transfer to yield the 1:1 radical complex [Pz(MgPh)]. However, in the presence of Na or K, persistent 1:2 complexes I are formed with M = Be, Mg, Zn. Use of the higher homologs CdPh2 and HgPh2 leads to redn. to the metals. The 1:2 complexes were characterized by ESR spectroscopy; metal coupling consts. of 9Be, 25Mg and 67Zn could be detd. in natural isotopic abundance. [on SciFinder(R)]

@article{Kaim.1981c, abstract = {The diphenyls MPh2 (M = Be, Mg, Zn, Cd, Hg) were treated with pyrazine (Pz) in THF. Only the Mg deriv. undergoes electron transfer to yield the 1:1 radical complex [Pz(MgPh)]. However, in the presence of Na or K, persistent 1:2 complexes I are formed with M = Be, Mg, Zn. Use of the higher homologs CdPh2 and HgPh2 leads to redn. to the metals. The 1:2 complexes were characterized by ESR spectroscopy; metal coupling consts. of 9Be, 25Mg and 67Zn could be detd. in natural isotopic abundance. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/26ddcc582d2ade5611086cd8d0e7aeda2/huebleriac}, interhash = {08097bfc0588edcdd5a3176bb6894c51}, intrahash = {6ddcc582d2ade5611086cd8d0e7aeda2}, issn = {0340-5087}, journal = {Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie}, keywords = {anion beryllium complex complex;ESR complex;magnesium complex;pyrazine complex;zinc metal pyrazine radical}, number = 9, pages = {1110--1116}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Coordination chemistry of reduced N-heterocycles. Complexes of pyrazine anion radical with phenyl metal cations +MPh of beryllium, magnesium and zinc}, volume = {36B}, year = 1981 }