%0 Journal Article %1 Ye.2005b %A Ye, Shengfa %A Sarkar, Biprajit %A Lissner, Falk %A Schleid, Thomas %A van Slageren, Joris %A Fiedler, Jan %A Kaim, Wolfgang. %D 2005 %J Angewandte Chemie, International Edition %K configuration;electrochem copper crystal ligand;magnetic methylthioanilinosemiquinonate methylthioanilinosemiquinonate;EPR nonplanar prepn property radical redox structure %N 14 %P 2103--2106 %R 10.1002/anie.200462339 %T Three-spin system with a twist: A bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center %V 44 %X Structural twisting by $\sim$32° between the semiquinoneiminecopper(II) entities in I caused by weak Cu-S interaction results in a different spin arrangement ($\uparrow$,$\downarrow$,$\uparrow$) than for a planar deriv. without the thioether group ($\uparrow$,$\uparrow$,$\downarrow$). Most revealingly, I has an EPR spectrum typical for a radical whereas the non-thioether analog is known to display a signal for a CuII center. Oxidn. state distributions for the I 2+,+,0,-,2- forms are assigned from UV/visible/NIR spectroelectrochem. on SciFinder(R)

@article{Ye.2005b, abstract = {Structural twisting by $\sim$32° between the semiquinoneiminecopper(II) entities in I caused by weak Cu-S interaction results in a different spin arrangement ($\uparrow$,$\downarrow$,$\uparrow$) than for a planar deriv. without the thioether group ($\uparrow$,$\uparrow$,$\downarrow$). Most revealingly, I has an EPR spectrum typical for a radical whereas the non-thioether analog is known to display a signal for a CuII center. Oxidn. state distributions for the I 2+,+,0,-,2- forms are assigned from UV/visible/NIR spectroelectrochem. [on SciFinder(R)]}, added-at = {2022-06-15T11:26:56.000+0200}, author = {Ye, Shengfa and Sarkar, Biprajit and Lissner, Falk and Schleid, Thomas and {van Slageren}, Joris and Fiedler, Jan and Kaim, Wolfgang.}, biburl = {https://puma.ub.uni-stuttgart.de/bibtex/299b4e62c5bb358062f4166db8bd84665/huebleriac}, doi = {10.1002/anie.200462339}, interhash = {063d2af668decd55fc00cd88ace03fe0}, intrahash = {99b4e62c5bb358062f4166db8bd84665}, issn = {1433-7851}, journal = {Angewandte Chemie, International Edition}, keywords = {configuration;electrochem copper crystal ligand;magnetic methylthioanilinosemiquinonate methylthioanilinosemiquinonate;EPR nonplanar prepn property radical redox structure}, number = 14, pages = {2103--2106}, timestamp = {2022-06-15T09:26:56.000+0200}, title = {Three-spin system with a twist: A bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center}, volume = 44, year = 2005 }