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3The conjugative bridging of organometallic reaction centers in heterodinuclear complexes [(OC)3ClRe(m-L)MCl(C5Me5)]+, M = Rh or Ir - Spectroscopic consequences of reductive activation
W. Kaim, T. Scheiring, M. Weber, and J. Fiedler. Zeitschrift fuer Anorganische und Allgemeine Chemie, 630 (12): 1883--1893 (2004)
6 years ago by @b_schwederski
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ESR
IR
UV
arom
bis
bridged
chelate
chelate;redox
chelate;rhenium
compd
complex
complex;spectroelectrochem
conjugated
electrochem
half
heterobinuclear
heterocyclic
iridium
ligand;rhodium
nitrogen
potential
prepn;pyrazine
prepn;redn
pyrimidine
rhenium
rhodium
sandwich
tetrazole
ESRIRUVarombisbridgedchelatechelate;redoxchelate;rheniumcompdcomplexcomplex;spectroelectrochemconjugatedelectrochemhalfheterobinuclearheterocycliciridiumligand;rhodiumnitrogenpotentialprepn;pyrazineprepn;rednpyrimidinerheniumrhodiumsandwichtetrazole
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3Substituent effects and perturbation of p systems, XXXV. Radical anions of tin-substituted naphthalenes
H. Bock, W. Kaim, and H. Tesmann. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 33B (11): 1223--1226 (1978)
6 years ago by @b_schwederski
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ESR
anion;stannylnaphthalene
anion;substituent
effect
pi
radical
stannyl
stannylnaphthalene;naphthalene
system
ESRanion;stannylnaphthaleneanion;substituenteffectpiradicalstannylstannylnaphthalene;naphthalenesystem
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3EPR/ENDOR detection of stable titanium(III) and titanium(IV) radical products generated by single electron transfer from (iso-PrO)3TiCH3
M. Moscherosch, and W. Kaim. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, (1992)
6 years ago by @b_schwederski
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ENDOR
ESR
ESR;titanium
complex
dicarbonyl
donor;semiquinone
electron
methyltriisopropoxytitanium;diimine
methyltriisopropoxytitanium;ketone
methyltriisopropoxytitanium;methyltriisopropoxytitanium
prepn
radical
single
stable
titanium
transfer
ENDORESRESR;titaniumcomplexdicarbonyldonor;semiquinoneelectronmethyltriisopropoxytitanium;diiminemethyltriisopropoxytitanium;ketonemethyltriisopropoxytitanium;methyltriisopropoxytitaniumprepnradicalsinglestabletitaniumtransfer
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3Radical ions. XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution
H. Bock, W. Kaim, and H. Rohwer. Journal of Organometallic Chemistry, 135 (1): C14-C19 (1977)
6 years ago by @b_schwederski
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ESR
benzene
benzene;silyl
cation
photoelectron
radical
silyl
spectra
ESRbenzenebenzene;silylcationphotoelectronradicalsilylspectra
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3Organosilicon radical cations
H. Bock, and W. Kaim. Accounts of Chemical Research, 15 (1): 9--17 (1982)
6 years ago by @b_schwederski
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ESR
ESR;silicon
cation
organo
organosilicon
radical
review
ESRESR;siliconcationorganoorganosiliconradicalreview
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3Paramagnetic organoaluminum complexes
W. Kaim. Journal of Organometallic Chemistry, 201 (2): C5-C8 (1980)
6 years ago by @b_schwederski
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ESR
ESR;azaarom
aluminum
azaarom
org
organoaluminum
reaction
ESRESR;azaaromaluminumazaaromorgorganoaluminumreaction
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3Crystalline heterocyclic radical cation salts as stable intermediates of new redox-mediating systems
A. Schulz, W. Kaim, and H. Hausen. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 84 (10): 3207--3214 (1988)
6 years ago by @b_schwederski
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ESR
cation
cation;heterocyclic
pyrazinium
quinoxalinium
radical
salt
ESRcationcation;heterocyclicpyraziniumquinoxaliniumradicalsalt
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3Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes
D. Weinberger, N. Amin SK, K. Mondal, M. Melaimi, G. Bertrand, A. Stuckl, H. Roesky, B. Dittrich, S. Demeshko, B. Schwederski and 3 other author(s). Journal of the American Chemical Society, 136 (17): 6235--6238 (2014)
6 years ago by @b_schwederski
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ESR
cAAC
copper
crystal
electrochem
mol
oxidn
prepn
prepn;mol
prepn;optimized
pyrrolidinylidene
state
structure
zero
ESRcAACcoppercrystalelectrochemmoloxidnprepnprepn;molprepn;optimizedpyrrolidinylidenestatestructurezero
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3EPR spectroelectrochemistry: Spectroelectrochem
P. Murray, and L. Yellowlees (Eds.) Royal Society of Chemistry, (2008)
6 years ago by @b_schwederski
show all tags
ESR
review
spectroelectrochem
ESRreviewspectroelectrochem
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3Semireduced bridging ligands containing N-N multiple bond coordination sites. ESR study of binuclear Group 6 metal carbonyl complexes
W. Kaim, and S. Kohlmann. Inorganic Chemistry, 25 (19): 3442--3448 (1986)
6 years ago by @b_schwederski
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ESR
ESR;ENDOR
ESR;tetrazine
VIB
azobipyridine
azopyridine
binuclear
carbonyl
complex
complex;ESR
complex;pyridyltetrazine
molybdenum
ESRESR;ENDORESR;tetrazineVIBazobipyridineazopyridinebinuclearcarbonylcomplexcomplex;ESRcomplex;pyridyltetrazinemolybdenum
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3Hexaborate cluster radical anions [B6HalnHal'6-n].bul.- and [B6Hal5R].bul.- (Hal, Hal' = Cl, Br, I; R = H, alkyl). Chemical or electrochemical generation, vibrational, UV-Vis and EPR spectroscopy
M. Wanner, W. Kaim, V. Lorenzen, and W. Preetz. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, 54 (9): 1103--1108 (1999)
6 years ago by @b_schwederski
show all tags
ESR
anion
anion;Raman
anion;hexaborate
cluster
halide
hexaborate
prepn;IR
radical
substituted
ESRanionanion;Ramananion;hexaborateclusterhalidehexaborateprepn;IRradicalsubstituted
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3RuII(a-diimine) or RuIII(a-diimine·-)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State
A. Grupp, M. Bubrin, F. Ehret, Q. Zeng, F. Hartl, H. Kvapilova, S. Zalis, and W. Kaim. European Journal of Inorganic Chemistry, 2014 (1): 110--119 (2014)
6 years ago by @b_schwederski
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ESR
acetylacetonato
alpha
charge
complex
configuration
crystal
diazabutadiene
excited
ground
ligand
metal
mol
pentanedionate
prepn
radical
ruthenium
spectroelectrochem;diimine
state
structure;stabilization
transfer
ESRacetylacetonatoalphachargecomplexconfigurationcrystaldiazabutadieneexcitedgroundligandmetalmolpentanedionateprepnradicalrutheniumspectroelectrochem;diiminestatestructure;stabilizationtransfer
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3Synthesis and characterization of the persistent radical [BCl2(bipy)]
S. Mansell, C. Adams, G. Bramham, M. Haddow, W. Kaim, N. Norman, J. McGrady, C. Russell, and S. Udeen. Chemical Communications (Cambridge, United Kingdom), 46 (28): 5070--5072 (2010)
6 years ago by @b_schwederski
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ESR
bipyridine
boron
calcn
chloro
complex
crystal
prepn
radical
structure;DFT
ESRbipyridineboroncalcnchlorocomplexcrystalprepnradicalstructure;DFT
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3Reaction of aromatic phosphine derivatives with electrons, III. Phosphine-boranes, -alanes, and -gallanes
W. Kaim. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 40B (1): 61--66 (1985)
6 years ago by @b_schwederski
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ESR
ESR;borane
ESR;gallane
ESR;phosphine
alane
anion
complex
diphosphine
radical
ESRESR;boraneESR;gallaneESR;phosphinealaneanioncomplexdiphosphineradical
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3Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand
R. Huebner, S. Weber, S. Strobel, B. Sarkar, S. Zalis, and W. Kaim. Organometallics, 30 (6): 1414--1418 (2011)
6 years ago by @b_schwederski
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DFT;mol
DFT;optimized
ESR
crystal
cyclopentadienyl
electrochem
iridium
methylthiophenyliminosemiquinonate
mol
prepn
spectroelectrochem
structure
voltammetry
DFT;molDFT;optimizedESRcrystalcyclopentadienylelectrochemiridiummethylthiophenyliminosemiquinonatemolprepnspectroelectrochemstructurevoltammetry
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3Novel organosilicon radical cations. One-electron oxidation of permethylcyclopolysilanes
H. Bock, W. Kaim, M. Kira, and R. West. Journal of the American Chemical Society, 101 (26): 7667--7670 (1979)
6 years ago by @b_schwederski
show all tags
ESR
ESR;ionization
ESR;photoelectron
MO;oxidn
cyclopentasilane
cyclopoly
cyclopolysilane
deriv;silane
permethyl
permethylcyclopolysilane
permethylcyclopolysilane;permethylcyclopolysilane
potential
radical
spectrum
ESRESR;ionizationESR;photoelectronMO;oxidncyclopentasilanecyclopolycyclopolysilanederiv;silanepermethylpermethylcyclopolysilanepermethylcyclopolysilane;permethylcyclopolysilanepotentialradicalspectrum
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3Stepwise and chemically reversible reduction of (μ-bmtz)[MCl(η6-cym)]2[PF6]2 (M = Ru, Os; bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine) with up to six electrons
M. Glockle, W. Kaim, and J. Fiedler. Zeitschrift fuer Anorganische und Allgemeine Chemie, 627 (7): 1441--1453 (2001)
6 years ago by @b_schwederski
show all tags
ESR
cymene;ruthenium
dinuclear
electrochem
osmium
pyrimidyltetrazine
redn
redn;spectroelectrochem
ruthenium
ESRcymene;rutheniumdinuclearelectrochemosmiumpyrimidyltetrazinerednredn;spectroelectrochemruthenium
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3First stable organometallic analog [mer-(OC)3(PiPr3)2W(m-pyrazine)W(PiPr3)2(CO)3]+ of the Creutz-Taube ion: Similarities and differences
W. Bruns, and W. Kaim. NATO ASI Series, Series C: Mathematical and Physical Sciences, 343 (Mixed Valency Syst.: Appl. Chem., Phys. Biol): 365--370 (1991)
6 years ago by @b_schwederski
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ESR
IR
carbonyl
dinuclear
dinuclear;tungsten
phosphine
pyrazine
tungsten
ESRIRcarbonyldinucleardinuclear;tungstenphosphinepyrazinetungsten
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3Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation
S. Samanta, P. Singh, J. Fiedler, S. Zalis, W. Kaim, and S. Goswami. Inorganic Chemistry, 47 (5): 1625--1633 (2008)
6 years ago by @b_schwederski
show all tags
8
ESR
UV
crystal
diradical
electrochem
metal
osmium
oxidn
phenylaminophenylazopyridine
phenylaminophenylazopyridine;group
prepn
ruthenium
singlet
spectroelectrochem;phenylaminophenylazopyridine
structure
8ESRUVcrystaldiradicalelectrochemmetalosmiumoxidnphenylaminophenylazopyridinephenylaminophenylazopyridine;groupprepnrutheniumsingletspectroelectrochem;phenylaminophenylazopyridinestructure
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3Multistep redox sequences of azopyridyl (L) bridged reaction centers in stable radical complex ions (μ-L)[MCl(η5-C5Me5)]2$\surd$+, M = Rh or Ir: Spectroelectrochemistry and high-frequency EPR spectroscopy
S. Frantz, R. Reinhardt, S. Greulich, M. Wanner, J. Fiedler, C. Duboc-Toia, and W. Kaim. Dalton Transactions, (2003)
6 years ago by @b_schwederski
show all tags
ESR
azopyridyl
azopyrimidine
azopyrimidinyl
bridged
bridged;spectro
cation
cyclopentadienyl
electrochem
ion
iridium
pentamethylcyclopentadienyl
prepn;radical
radical
rhodium
ESRazopyridylazopyrimidineazopyrimidinylbridgedbridged;spectrocationcyclopentadienylelectrochemioniridiumpentamethylcyclopentadienylprepn;radicalradicalrhodium
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3The conjugative bridging of organometallic reaction centers in heterodinuclear complexes [(OC)3ClRe(m-L)MCl(C5Me5)]+, M = Rh or Ir - Spectroscopic consequences of reductive activation

3Substituent effects and perturbation of p systems, XXXV. Radical anions of tin-substituted naphthalenes

3EPR/ENDOR detection of stable titanium(III) and titanium(IV) radical products generated by single electron transfer from (iso-PrO)3TiCH3

3Radical ions. XI. One-electron oxidation of alkylsilyl benzenes in the gas phase and in solution

3Organosilicon radical cations

3Paramagnetic organoaluminum complexes

3Crystalline heterocyclic radical cation salts as stable intermediates of new redox-mediating systems

3Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes

3EPR spectroelectrochemistry: Spectroelectrochem

3Semireduced bridging ligands containing N-N multiple bond coordination sites. ESR study of binuclear Group 6 metal carbonyl complexes

3Hexaborate cluster radical anions [B6HalnHal'6-n].bul.- and [B6Hal5R].bul.- (Hal, Hal' = Cl, Br, I; R = H, alkyl). Chemical or electrochemical generation, vibrational, UV-Vis and EPR spectroscopy

3RuII(a-diimine) or RuIII(a-diimine·-)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State

3Synthesis and characterization of the persistent radical [BCl2(bipy)]

3Reaction of aromatic phosphine derivatives with electrons, III. Phosphine-boranes, -alanes, and -gallanes

3Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand

3Novel organosilicon radical cations. One-electron oxidation of permethylcyclopolysilanes

3Stepwise and chemically reversible reduction of (μ-bmtz)[MCl(η6-cym)]2[PF6]2 (M = Ru, Os; bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine) with up to six electrons

3First stable organometallic analog [mer-(OC)3(PiPr3)2W(m-pyrazine)W(PiPr3)2(CO)3]+ of the Creutz-Taube ion: Similarities and differences

3Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation

3Multistep redox sequences of azopyridyl (L) bridged reaction centers in stable radical complex ions (μ-L)[MCl(η5-C5Me5)]2$\surd$+, M = Rh or Ir: Spectroelectrochemistry and high-frequency EPR spectroscopy

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