Publications

Christian Bessenbacher, Wolfgang Kaim, and Thomas. Stahl. Electron-rich olefins. 4. Electron-rich compounds with thiophosphinamide, carboxamide, O-silylurethane and O-silylisourea functionality. Synthesis, spectroscopy, chemical and electrochemical reactivity. Chemische Berichte, (122)5:933--939, 1989. [PUMA: NMR addn carbon cation chloride;silyldihydropyrazine dihydropyrazine dihydropyrazine;pyrazine dioxide electrochem;ESR electron insertion isocyanate radical redn rich thiophosphine]

Axel Klein, Steffen Hasenzahl, and Wolfgang. Kaim. EPR study of electron transfer and group transfer in organoplatinum(II) and (IV) compounds. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12:2573--2577, 1997. [PUMA: 4 anion;ESR chelate chelate;electron chelate;homolysis diazabutadiene diazabutadiene;methyl diazabutadiene;platinum electrochem group mesityl methyl organoplatinum photochem platinum radical radical;photohomolysis redn transfer]

Wolfgang Kaim, Peter Haenel, and Hans. Bock. The reduction of triphenylphosphine derivatives to their radical anions and to the radical dianion of dibenzophosphole. Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, (37B)11:1382--1387, 1982. [PUMA: ESR;triphenylphosphine anion anion;phosphine dianion;ESR dibenzophosphole oxide radical redn sulfide triphenyl triphenylphosphine]

Cueneyt Kavakli, Anders Gabrielsson, Monika Sieger, Brigitte Schwederski, Mark Niemeyer, and Wolfgang. Kaim. Reversible radical complex formation of an organometallic diplatinum(IV) compound. Journal of Organometallic Chemistry, (692)15:3151--3155, 2007. [PUMA: complex complex;ESR complex;trimethyl crystal electrochem methylpyridyl mol platinum prepn radical redn spectra structure tetrazine trimethylplatinum]

Wolfgang. Kaim. Organoaluminum radical complexes of nitrogen heterocycles. I. Pyridine derivatives. Journal of Organometallic Chemistry, (215)3:325--335, 1981. [PUMA: alkali alkylaluminum;ESR aluminum bipyridine cation;pyridine meta pyridine radical reaction redn]

Helmut Sitzmann, Thomas Dezember, Wolfgang Kaim, Frank Baumann, Dietmar Stalke, Joerg Kaercher, Elmar Dormann, Hubert Winter, Christoph wachter, and Marc. Kelemen. High-spin cyclopentadienyl complexes. 1. Synthesis and characterization of the stable dicarbonyl(cyclopentadienyl)iron radical (C5R5)Fe(CO)2 (R = CHMe2). Angewandte Chemie, International Edition in English, (35)23/24:2872--2875, 1997. [PUMA: 2 bromo carbonyl carbonyl;regiospecific complex;iron crystal cyclopentadienyl dimer;high dimer;redn elimination iron isopropylcyclopentadienyl prepn;mol propene radical redn spin structure]

Ulrich Fekl, Biprajit Sarkar, Wolfgang Kaim, Marco Zimmer-De Iuliis, and Neilson. Nguyen. Tuning of the Spin Distribution between Ligand- and Metal-Based Spin: Electron Paramagnetic Resonance of Mixed-Ligand Molybdenum Tris(dithiolene) Complex Anions. Inorganic Chemistry, (50)18:8685--8687, 2011. [PUMA: ESR anion coupling hyperfine molybdenum radical redn thiolene]