Complex Series Ru(tpy)(dpk)(X)n+ (tpy = 2,2': 6',2''-Terpyridine; dpk = 2,2'-Dipyridyl Ketone; X = Cl-, CH3CN, NO2-, NO+, NO.bul., NO-): Substitution and Electron Transfer, Structure, and Spectroscopy. Inorganic Chemistry, (44)17:6092--6099, 2005. [PUMA: reactivity nitroso radical electrochem complex cation redox ligand anion ruthenium precursor;kinetics complex;nitrosyl nitrosyl dipyridyl terpyridine ketone oxidn prepn]
Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3e) or Reduction (2e) to Spectroelectrochemically Characterized Species. Chemistry - A European Journal, (15)28:6932-6939, S6932/1-S6932/7, 2009. [PUMA: MO trisferrocenylcopper level hexaazatrinaphthylene crystal structure;unsubstituted mol redn spectroelectrochem deriv ligand EPR;reversible energy ferrocenium tetrafluoroborate ferrocene oxidn couple;trisferrocenylcopper prepn]
Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin. Organometallics, (27)14:3321--3324, 2008. [PUMA: complex;styryl centered tetradonor complex olefin ethene ligand structure ruthenium styryl tetranuclear delocalization calcn electron complex;mol phosphine oxidn prepn]
Divinylphenylene-Bridged Diruthenium Complexes Bearing Ru(CO)Cl(PiPr3)2 Entities. Organometallics, (25)15:3701--3712, 2006. [PUMA: addn radical electrochem complex stereoselective cation;divinylphenylene complex;diruthenium ligand ruthenium divinylphenylene prepn;electrochem bridged hydro bridging oxidn diruthenium DFT;DFT complex;diethynylbenzene]
Application of a Structure/Oxidation-State Correlation to Complexes of Bridging Azo Ligands. Chemistry - A European Journal, (18)35:11007-11018, S11007/1-S11007/28, 2012. [PUMA: structure;structure crystal complex;ruthenium complex azobispyridine ligand ruthenium transfer relationship noninnocent state electron oxidn prepn]
\dqGuilty\dq Verdict - Evidence for the Noninnocence of Cyanide. Angewandte Chemie, International Edition, (50)45:10498--10500, 2011. [PUMA: noninnocence compd review state cyanide oxidn coordination ligand]
Discovering More Non-Innocence: Triazenido versus Triazenyl Radical Ligand Function, and a Comment on NO2n as a \dqSuspect\dq Ligand. Angewandte Chemie, International Edition, (52)17:4673--4675, 2013. [PUMA: noninnocence complex;triazenido ESR;electrochem crystal radical complex triazenido aryl ligand structure ruthenium DFT triazenyl vs oxidn prepn]