Theoretical and experimental evidence for a new kind of spin-coupled singlet species: Isomeric mixed-valent complexes bridged by a radical anion ligand. Angewandte Chemie, International Edition, (44)35:5655--5658, 2005. [PUMA: acetylacetonate azobispyridine complex complex;electrochem complex;electronic complex;geometry complex;ruthenium crystal isomeric optimized prepn redox ruthenium structure]
Widely Separated Reduction Processes of abpy-Coupled Areneosmium(II) Reaction Centers (abpy = 2,2'-Azobispyridine): Stabilization of the Radical Intermediate and of the Os0OsII State. Organometallics, (24)8:1966--1973, 2005. [PUMA: EPR arene azobispyridine binuclear bipyrimidine bridged cation complex complex;osmium diosmium mixed osmium potential;radical redox spectra valence]