An exceedingly stable diiron(II,III) complex ion (tz)Fe(CN)525- with comproportionation constants between 108 (in H2O) and 1019 (in CH3CN). Angewandte Chemie, International Edition, (38)20:3072--3074, 1999. [PUMA: bridged comproportionation decacyano diiron iron pentacyano prepn stability;iron stability;tetrazine tetrazine valence valence;mixed valent]
On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds RkPt(m-L)PtRkn, k = 2 or 4. Organometallics, (17)16:3532--3538, 1998. [PUMA: bridged cyclic dinuclear ligand organo organoplatinum organoplatinum;mixed organoplatinum;platinum prepn;spectroelectrochem pyrazine tetrazine valent voltammetry]