Electron Paramagnetic Resonance and Spectroscopic Characteristics of Electrogenerated Mixed-Valent Systems (h5-C5Me5)M(m-L)M(h5-C5Me5)+ (M = Rh, Ir; L = 2,5-Diiminopyrazines) in Relation to the Radicals (h5-C5Me5)ClM(m-L)MCl(h5-C5Me5)+ and (h5-C5Me5)M(m-L)MCl(h5-C5Me5)2+. Inorganic Chemistry, (39)12:2516--2521, 2000. [PUMA: bpip bxip chloro cyclopentadienyl diiminopyrazine electrochem iridium mixed pentamethylcyclopentadienyl pentamethylcyclopentadienyl;iminoethyl prepn pyrazine redn redn;ESR rhodium valent]
On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds RkPt(m-L)PtRkn, k = 2 or 4. Organometallics, (17)16:3532--3538, 1998. [PUMA: bridged cyclic dinuclear ligand organo organoplatinum organoplatinum;mixed organoplatinum;platinum prepn;spectroelectrochem pyrazine tetrazine valent voltammetry]