Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, (54)16:7936--7944, 2015. [PUMA: UV bipyridine phenylazopyridine crystal osmium complex diaminoanthraquinone density complex;electron complex;IR redox spectroelectrochem dihydroxyanthraquinone structure complex;osmium spin potential prepn]
Structural Reassessment of W(CO)5(TCNE): N (s) Coordination Instead of an Olefin (p) Complex. Organometallics, (31)17:6305--6311, 2012. [PUMA: UV cyano sigma TCNE Vis;DFT crystal nitrogen EPR optimized IR mol complex reassessment;TCNE pentacarbonyltungsten bond spectroelectrochem coordination structure geometry]
Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation. Inorganic Chemistry, (47)5:1625--1633, 2008. [PUMA: UV diradical ESR crystal spectroelectrochem;phenylaminophenylazopyridine osmium electrochem metal phenylaminophenylazopyridine;group structure ruthenium singlet phenylaminophenylazopyridine 8 oxidn prepn]
Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex (μ-tppz)Ru(bik)Cl23+ (tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2'-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and nCO Line Broadening. Inorganic Chemistry, (46)9:3736--3742, 2007. [PUMA: UV ESR charge IR electrochem redn mixed valent transition ruthenium transfer methylimidazolylketone;ruthenium pyridylpyrazine methylimidazolylketone;intervalence methylimidazolylketone oxidn prepn]
Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II). Inorganica Chimica Acta, (358)9:2609--2617, 2005. [PUMA: UV UV;palladium crystal dithiocarbamate complex complex;naphthylarsine structure luminescence platinum naphthylarsine palladium UV;platinum phosphine complexation prepn]
Molecule-Bridged Mixed-Valent Intermediates Involving the RuI Oxidation State. Journal of the American Chemical Society, (126)45:14706--14707, 2004. [PUMA: UV voltammetry charge iminomethylpyrazine complex;ruthenium arene complex dimer;cyclic mixed valence spectra azobispyridine transition areneruthenium transfer complex;redox dimer;EPR bridged diruthenium potential prepn]
The conjugative bridging of organometallic reaction centers in heterodinuclear complexes (OC)3ClRe(m-L)MCl(C5Me5)+, M = Rh or Ir - Spectroscopic consequences of reductive activation. Zeitschrift fuer Anorganische und Allgemeine Chemie, (630)12:1883--1893, 2004. [PUMA: UV ESR arom prepn;redn conjugated heterobinuclear nitrogen IR electrochem sandwich heterocyclic ligand;rhodium pyrimidine tetrazole chelate;rhenium complex;spectroelectrochem rhenium half chelate complex bis prepn;pyrazine iridium compd chelate;redox bridged rhodium potential]
Resolving the Two-Electron Process for the Couple (C5Me5)M(NN̂)Cl+/(C5Me5)M(NN̂) (M = Rh, Ir) into Two One-Electron Steps Using the 2,2'-Azobis(pyridine) NN̂ Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MII Intermediates. Organometallics, (22)11:2240--2244, 2003. [PUMA: ESR;rhodium UV iridium radical complex electrochem intermediate redox rhodium spectroelectrochem azobispyridine prepn]
Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(ii) and platinum(ii): Synthesis, spectroscopy, photochemistry and structures. New Journal of Chemistry, (27)11:1584--1591, 2003. [PUMA: UV allylarsine crystal allylarsine;palladium pyrazolate methylallylarsine structure NMR platinum palladium ethylcarbamate UV;platinum prepn]
Widely differing stabilities of molecule-bridged cyanodiiron(III,II) species in non-aqueous solvents. Inorganica Chimica Acta, (291)1-2:66--73, 1999. [PUMA: UV cyano bipyridine pyridylethene ESR pyrimidyltetrazine IR const;mixed electrochem redox;electrochem redox valence redox;pyridylethene comproportionation redox;pyrimidyltetrazine pyrazine pyrimidyltetrazine;iron iron pyrimidyltetrazine;pyrazine prepn]