Resolving the Two-Electron Process for the Couple (C5Me5)M(NN̂)Cl+/(C5Me5)M(NN̂) (M = Rh, Ir) into Two One-Electron Steps Using the 2,2'-Azobis(pyridine) NN̂ Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MII Intermediates. Organometallics, (22)11:2240--2244, 2003. [PUMA: ESR;rhodium UV azobispyridine complex electrochem intermediate iridium prepn radical redox rhodium spectroelectrochem]