The conjugative bridging of organometallic reaction centers in heterodinuclear complexes (OC)3ClRe(m-L)MCl(C5Me5)+, M = Rh or Ir - Spectroscopic consequences of reductive activation. Zeitschrift fuer Anorganische und Allgemeine Chemie, (630)12:1883--1893, 2004. [PUMA: ESR IR UV arom bis bridged chelate chelate;redox chelate;rhenium compd complex complex;spectroelectrochem conjugated electrochem half heterobinuclear heterocyclic iridium ligand;rhodium nitrogen potential prepn;pyrazine prepn;redn pyrimidine rhenium rhodium sandwich tetrazole]
Molecule-Bridged Mixed-Valent Intermediates Involving the RuI Oxidation State. Journal of the American Chemical Society, (126)45:14706--14707, 2004. [PUMA: UV arene areneruthenium azobispyridine bridged charge complex complex;redox complex;ruthenium dimer;EPR dimer;cyclic diruthenium iminomethylpyrazine mixed potential prepn spectra transfer transition valence voltammetry]
A study of the reduced states of four isomeric bidiazines (diaza-2,2'-bipyridines) by UV-VIS/NIR-spectroelectrochemistry. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 11:2007--2010, 1992. [PUMA: IR IR;reduced UV bidiazine bipyrazine bipyridazine bipyrimidine isomer reduced]
Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt. Inorganica Chimica Acta, (251)1-2:239--248, 1996. [PUMA: TCNE UV cobalt complex;IR complex;electron complex;magnetic complex;osmium electron ground metal property state transfer transfer;electrochem transfer;ruthenium transfer;vanadium]
Electronic Structure of p-Conjugated Redox Systems with Borane/Borataalkene End Groups. Inorganic Chemistry, (35)10:3039--3043, 1996. [PUMA: IR IR;borane IR;conformation UV anion borane borataalkene;MO conjugated dimesitylphenylborane dimesitylphenylborane;electronic dimesitylphenylborane;spectroelectrochem mesityl mesitylphenylborane mesitylphenylborane;crystal model phenyl radical redox spectroelectrochem structure system;mol]
Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, (54)16:7936--7944, 2015. [PUMA: UV bipyridine complex complex;IR complex;electron complex;osmium crystal density diaminoanthraquinone dihydroxyanthraquinone osmium phenylazopyridine potential prepn redox spectroelectrochem spin structure]
Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on Oxidation. Inorganic Chemistry, (47)5:1625--1633, 2008. [PUMA: 8 ESR UV crystal diradical electrochem metal osmium oxidn phenylaminophenylazopyridine phenylaminophenylazopyridine;group prepn ruthenium singlet spectroelectrochem;phenylaminophenylazopyridine structure]
Complexes of a-diimines with pentamethylcyclopentadienylrhodium in different oxidation states. Zeitschrift fuer Anorganische und Allgemeine Chemie, (619)12:1998--2005, 1993. [PUMA: UV complex complex;diazabutadiene cyclic diimine electrochem;rhodium pentamethylcyclopentadienyl pentamethylcyclopentadienylrhodium prepn voltammetry]
Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex (μ-tppz)Ru(bik)Cl23+ (tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2'-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and nCO Line Broadening. Inorganic Chemistry, (46)9:3736--3742, 2007. [PUMA: ESR IR UV charge electrochem methylimidazolylketone methylimidazolylketone;intervalence methylimidazolylketone;ruthenium mixed oxidn prepn pyridylpyrazine redn ruthenium transfer transition valent]
Structural Reassessment of W(CO)5(TCNE): N (s) Coordination Instead of an Olefin (p) Complex. Organometallics, (31)17:6305--6311, 2012. [PUMA: EPR IR TCNE UV Vis;DFT bond complex coordination crystal cyano geometry mol nitrogen optimized pentacarbonyltungsten reassessment;TCNE sigma spectroelectrochem structure]
Electrochemistry and spectroelectrochemistry (EPR, UV-visible-near-IR) of platinum(II) 2,2'-bipyridine and ring-metalated bipyridine complexes: PtII(L-) and PtI(L-) but not PtI(L). Inorganic Chemistry, (31)24:5084--5088, 1992. [PUMA: ESR;platinum UV bipyridine complex dimethylbipyridine elec electrochem electroredn;dimethylaminobipyridine phenathroline platinum potential;redn pyridine redox reversible spectrum;diaminoethane]
Resolving the Two-Electron Process for the Couple (C5Me5)M(NN̂)Cl+/(C5Me5)M(NN̂) (M = Rh, Ir) into Two One-Electron Steps Using the 2,2'-Azobis(pyridine) NN̂ Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MII Intermediates. Organometallics, (22)11:2240--2244, 2003. [PUMA: ESR;rhodium UV azobispyridine complex electrochem intermediate iridium prepn radical redox rhodium spectroelectrochem]
Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II). Inorganica Chimica Acta, (358)9:2609--2617, 2005. [PUMA: UV UV;palladium UV;platinum complex complex;naphthylarsine complexation crystal dithiocarbamate luminescence naphthylarsine palladium phosphine platinum prepn structure]
Widely differing stabilities of molecule-bridged cyanodiiron(III,II) species in non-aqueous solvents. Inorganica Chimica Acta, (291)1-2:66--73, 1999. [PUMA: ESR IR UV bipyridine comproportionation const;mixed cyano electrochem iron prepn pyrazine pyridylethene pyrimidyltetrazine pyrimidyltetrazine;iron pyrimidyltetrazine;pyrazine redox redox;electrochem redox;pyridylethene redox;pyrimidyltetrazine valence]
Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(ii) and platinum(ii): Synthesis, spectroscopy, photochemistry and structures. New Journal of Chemistry, (27)11:1584--1591, 2003. [PUMA: NMR UV UV;platinum allylarsine allylarsine;palladium crystal ethylcarbamate methylallylarsine palladium platinum prepn pyrazolate structure]
Electronic absorption spectroscopy of some exceptionally stable 1,4-dialkyl-1,4-dihydro-1,4-diazinium radical cations: Assignment of transitions, vibrational structure and effects of p-p dimerization. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 1:135--138, 1994. [PUMA: UV absorption cation cation;transition cation;vibrational dialkyldihydrodiazinium dimerization electronic pi radical stable structure]
N,N'-Dialkylpyrazinium and quinoxalinium salts. N-Heterocyclic redox systems with the radical cation intermediate as most persistent oxidation state. Heterocycles, (23)6:1363--1366, 1985. [PUMA: ESR UV alkylpyrazinium alkylquinoxalinium;pyrazinium cation electrochem redox redox;quinoxalinium redox;radical]