Publications

Wolfgang Kaim, and Michael. Moscherosch. The coordination chemistry of TCNE, TCNQ and related polynitrile p acceptors. Coordination Chemistry Reviews, (129)1-2:157--193, 1994. [PUMA: TCNE TCNQ coordination review]

Frank Baumann, Martina Heilmann, Walther Matheis, Andreas Schulz, Wolfgang Kaim, and Jeanne. Jordanov. Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt. Inorganica Chimica Acta, (251)1-2:239--248, 1996. [PUMA: TCNE UV cobalt complex;IR complex;electron complex;magnetic complex;osmium electron ground metal property state transfer transfer;electrochem transfer;ruthenium transfer;vanadium]

Martina Bubrin, Michael J. Krafft, Lisa Steudle, Ralph Huebner, John S. Field, Stanislav Zalis, and Wolfgang. Kaim. Structural Reassessment of W(CO)5(TCNE): N (s) Coordination Instead of an Olefin (p) Complex. Organometallics, (31)17:6305--6311, 2012. [PUMA: EPR IR TCNE UV Vis;DFT bond complex coordination crystal cyano geometry mol nitrogen optimized pentacarbonyltungsten reassessment;TCNE sigma spectroelectrochem structure]

Sharon E. Bell, John S. Field, Raymond J. Haines, Michael Moscherosch, Walter Matheis, and Wolfgang. Kaim. Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation. Inorganic Chemistry, (31)15:3269--3276, 1992. [PUMA: TCNE TCNE;ESR TCNQ complex complex;ruthenium electrochem redox ruthenium]

Renate Gross-Lannert, Wolfgang Kaim, and Barbara. Olbrich-Deussner. Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: TCNE TCNQ complex complex;MO complex;electron complex;manganese cyclic delocalization manganese voltammetry]

Michael Moscherosch, Eberhard Waldhoer, Herbert Binder, Wolfgang Kaim, and Jan. Fiedler. Tetranuclear Pentaammineruthenium Complexes Bridged by p-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States. Inorganic Chemistry, (34)17:4326--4335, 1995. [PUMA: TCNB TCNE TCNQ ammine electrochem ligand;oxidn ligand;redn ligand;ruthenium redox ruthenium tetracyano tetranuclear]