Valence Delocalization despite Weak Metal-Metal Coupling in a Bis(organoosmium(III,II)) Complex with a Pyrazine Bridge. Organometallics, (17)23:4923--4925, 1998. [PUMA: dinuclear complex;osmium pyrazine delocalization;spectroelectrochem osmium complex electrochem complex;mixed bridged valence oxidn prepn]
Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, (54)16:7936--7944, 2015. [PUMA: UV bipyridine phenylazopyridine crystal osmium complex diaminoanthraquinone density complex;electron complex;IR redox spectroelectrochem dihydroxyanthraquinone structure complex;osmium spin potential prepn]
Oxidation State Analysis of a Four-Component Redox Series Os(pap)2(Q)n Involving Two Different Non-Innocent Ligands on a Redox-Active Transition Metal. Inorganic Chemistry, (50)15:7090--7098, 2011. [PUMA: voltammetry ESR phenylazopyridine crystal osmium complex iminobenzoquinone spectra structure complex;osmium NIR cyclic prepn]
Tetranuclear osmium complexes of tetracyanoquinodimethane TCNQ, 2,2'-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile) and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 22:4455--4460, 1997. [PUMA: charge TCNB tetranuclear;magnetism osmium complex magnetism spectroelectrochem magnetism;TCNQ complex;osmium transfer tetranuclear spectroelectrochem;TCNB TCNQ intervalence prepn]
Effect of metal exchange (Os vs. Ru) and co-ligand variation (Cl- vs. acac-) on the oxidation state distribution in complexes of an o-phenylenediamido(2-)/o-quinonediimine redox system. Dalton Transactions, 37:7778--7785, 2009. [PUMA: visible crystal osmium optimized complex;geometry complex complex;electronic quinonediimine structure ruthenium complex;osmium complex;electroredn complex;ESR prepn;UV structure;ruthenium complex;valence complex;electrooxidn prepn]
Widely Separated Reduction Processes of abpy-Coupled Areneosmium(II) Reaction Centers (abpy = 2,2'-Azobispyridine): Stabilization of the Radical Intermediate and of the Os0OsII State. Organometallics, (24)8:1966--1973, 2005. [PUMA: arene osmium EPR complex diosmium mixed cation redox valence bipyrimidine spectra azobispyridine potential;radical complex;osmium binuclear bridged]