Publications

Wolfgang. Kaim. The chemistry and biochemistry of the copper-radical interaction. Dalton Transactions, 5:761--768, 2003. [PUMA: biochem chem copper enzyme interaction radical review]

Doyel Kumbhakar, Biprajit Sarkar, Somnath Maji, Shaikh M. Mobin, Jan Fiedler, Francisco A. Urbanos, Reyes Jimenez-Aparicio, Wolfgang Kaim, and Goutam Kumar. Lahiri. Intramolecular Valence and Spin Interaction in meso and rac Diastereomers of a p-Quinonoid-Bridged Diruthenium Complex. Journal of the American Chemical Society, (130)51:17575--17583, 2008. [PUMA: bridged crystal diastereoisomer diastereoisomer;electrochem diastereoisomer;magnetic diastereoisomer;quinonoid diruthenium interaction intramol prepn property quinonoid redox spin structure valence]

Amarendra Nath Maity, Brigitte Schwederski, and Wolfgang. Kaim. The redox pair (μ4-TCNE)Fe(CO)2(C5H5)44+/3+: Surprisingly small metal-ligand interaction and the first resolved EPR hyperfine structure (13C, 14N, 57Fe) of a tetranuclear complex with TCNE-. Inorganic Chemistry Communications, (8)7:600--602, 2005. [PUMA: MLCT band bridged charge complex complex;EPR complex;metal complex;redox complex;tetracyanoethylene coordinated coupling cyclopentadienyl cyclopentadienyliron dicarbonyl hyperfine interaction iron ligand nitrogen potential prepn spectrum tetracyanoethylene tetranuclear transfer]

Priti Singh, Biprajit Sarkar, Monika Sieger, Mark Niemeyer, Jan Fiedler, Stanislav Zalis, and Wolfgang. Kaim. The Metal-NO Interaction in the Redox Systems Cl5Os(NO)n-, n = 1-3, and cis-(bpy)2ClOs(NO)2+/+: Calculations, Structural, Electrochemical, and Spectroscopic Results. Inorganic Chemistry, (45)12:4602--4609, 2006. [PUMA: acetonitrile bond chloro complex crystal electrochem electroredn interaction iridium lengthening;metal nitrosyl osmium potential ruthenium salt solvate spectroscopy;osmate structure structure;redox tetraphenylphosphonium]

Stanislav Zalis, Monika Sieger, Stefan Greulich, Hermann Stoll, and Wolfgang. Kaim. Replacement of 2,2'-Bipyridine by 1,4-Diazabutadiene Acceptor Ligands: Why the Bathochromic Shift for (NN̂)IrCl(C5Me5)+ Complexes but the Hypsochromic Shift for (NN̂)Ir(C5Me5)?. Inorganic Chemistry, (42)17:5185--5191, 2003. [PUMA: DFT HOMO LUMO bathochromic bipyridine cationic charge chloro complex complex;DFT cyclopentadienyl diazabutadiene hypsochromic interaction iridium shift;orbital transfer]

Matthias Wanner, Ingo Hartenbach, Jan Fiedler, Thomas Schleid, and Wolfgang. Kaim. Dinuclear and trinuclear organometallic complexes (ReS4)MCl(C5Me5), M = Rh, Ir, and (m-WS4)IrCl(C5Me5)2. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (56)9:940--946, 2001. [PUMA: charge crystal cyclopentadienyl dinuclear interaction iridium mol potential prepn redn rhodium structure structure;tetrathiotungstate tetrathiorhenate;electrochem tetrathiorhenate;tetrathiorhenate tetrathiotungstate transfer]

Wolfgang Kaim, and Biprajit. Sarkar. Mixed valency in ruthenium complexes - Coordinative aspects. Coordination Chemistry Reviews, (251)3+4:584--594, 2007. [PUMA: complex interaction metal mixed review ruthenium valence]

T. Sixt, and W. Kaim. Copper(I) complexes with N,O-donor Schiff base ligands related to intermediate forms of the TPQ cofactor in amine oxidases. Inorganica Chimica Acta, (300-302):762--768, 2000. [PUMA: aminated amine benzylideneiminophenol benzylideneiminoresorcinol bond copper dihydroxyisopropylphenylacetamide dihydroxyisopropylphenylacetamide;copper interaction intermediate intermediate;topaquinone model oxidase prepn;crystal prepn;ring structure topaquinone triphenylphosphine triphenylphosphine;Schiff triphenylphosphine;hydrogen triphenylphosphine;hydroxyisopropylphenylacetamide]

Oliver Heilmann, Fridmann M. Hornung, Wolfgang Kaim, and Jan. Fiedler. Structure, EPR and UV-VIS and IR spectroelectrochemistry of reversibly reducible compounds (C5Me5)IrCl(L)(PF6), L= 1,3-dimethyllumazine or 1,3-dimethylalloxazine. Journal of the Chemical Society, Faraday Transactions, (92)21:4233--4238, 1996. [PUMA: EPR;crystal alloxazine complex complex;electrochem complex;flavin complex;pterin cyclopentadienyl cyclopentadienyl;EPR interaction iridium lumazine metal model;iridium model;spectroelectrochem prepn redn spectroelectrochem spectroelectrochem;lumazine spectroelectrochem;mol structure]