EPR study of electron transfer and group transfer in organoplatinum(II) and (IV) compounds. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12:2573--2577, 1997. [PUMA: photochem chelate radical electrochem redn chelate;electron diazabutadiene;methyl transfer anion;ESR 4 platinum organoplatinum radical;photohomolysis methyl diazabutadiene chelate;homolysis group mesityl diazabutadiene;platinum]
Reactions of New Organoplatinum(II) and -(IV) Complexes of 1,4-Diaza-1,3-butadienes with Light and Electrons. Emission vs Photochemistry and the Electronic Structures of Ground, Reduced, Oxidized, and Low-Lying Charge-Transfer Excited States. Organometallics, (17)2:237--247, 1998. [PUMA: MO charge excited chelate aryl structure chelate;DAB transfer low chelate;diazabutadiene reaction;DFT platinum organoplatinum chelate;oxidized alkyl diazabutadiene HF prepn;electronic lying prepn]
RuII(a-diimine) or RuIII(a-diimine·-)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State. European Journal of Inorganic Chemistry, (2014)1:110--119, 2014. [PUMA: acetylacetonato ESR charge structure;stabilization crystal configuration excited radical mol complex metal spectroelectrochem;diimine ligand ruthenium transfer alpha state ground diazabutadiene pentanedionate prepn]
Reactivity of \dqGaI\dq Toward N-Substituted 1,4-Diazabuta-1,3-dienes: Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions. Organometallics, (21)15:3169--3172, 2002. [PUMA: reaction ESR situ in mol formation gallium B3LYP diazabutadiene;heterocycle heterocycle;gallium spectra structure monoanion iodide calcn heterocycle;crystal diazabutadiene paramagnetic prepn]
Organometallic complex cations (hn-CnR'n)M(RN:CHCH:NR)Cl+ of 1,4-diazabutadienes (M = Os and n = 6 or M = Rh, Ir and n = 5, R = 2,6-dialkylphenyl). Structures and reduction to neutral compounds (hn-CnR'n)M(RNCH:CHNR). Zeitschrift fuer Anorganische und Allgemeine Chemie, (627)4:620--630, 2001. [PUMA: structure;iridium crystal azabutadiene osmium diisopropylphenyl complex;redn redox;mol mol complex redox structure iridium redox;crystal complex;rhodium complex;redox complex;diazabutadiene diazabutadiene potential prepn]
CpIr(dab) (dab = 1,4-Bis(2,6-dimethylphenyl)-1,4-diazabutadiene): A Coordinatively Unsaturated Six-p-Electron Metallaheteroaromatic Compound?. Inorganic Chemistry, (35)13:3998--4002, 1996. [PUMA: ab voltammetry MO complex;cyclic complex structure;mol complex;crystal structure iridium pentamethylcyclopentadienyl cyclopentadienyl complex;diazabutadiene initio diazabutadiene prepn]
Ancillary ligand determination of the spin location in both oxidised and reduced forms of diruthenium complexes bridged by bis-bidentate 1,4-bis(2-phenolato)-1,4-diazabutadiene. Dalton Transactions, 19:1934--1938, 2007. [PUMA: dinuclear hydroxyanil ruthenium bipyridine redox;ruthenium complex electrochem redox;spin hydroxyphenyl diazabutadiene glyoxalbis prepn]
Replacement of 2,2'-Bipyridine by 1,4-Diazabutadiene Acceptor Ligands: Why the Bathochromic Shift for (NN̂)IrCl(C5Me5)+ Complexes but the Hypsochromic Shift for (NN̂)Ir(C5Me5)?. Inorganic Chemistry, (42)17:5185--5191, 2003. [PUMA: bipyridine charge complex;DFT complex HOMO LUMO hypsochromic shift;orbital DFT iridium transfer bathochromic cationic cyclopentadienyl chloro interaction diazabutadiene]
Geometrical and ground state electronic structures of nitrosylcobalt complexes (RNCHCHNR)Co(NO)(CO) (R = isopropyl, 2,6-diisopropylphenyl or p-tolyl) from experiment and DFT-calculations. Zeitschrift fuer Anorganische und Allgemeine Chemie, (628)11:2360--2364, 2002. [PUMA: crystal mol complex cobalt structure DFT nitrosyl complex;nitrosylcobalt calcn state ground diazabutadiene electronic prepn]
Oxidation and reduction response of a-diimine complexes with tricarbonylrhenium halides and pseudohalides. Journal of Organometallic Chemistry, (751):678--685, 2014. [PUMA: diimine rhenium charge crystal complex redn pseudohalide spectroelectrochem carbonyl structure DFT halide transfer;rhenium diazabutadiene oxidn prepn]
A tale of two complexes, PtMen(RN=CHCH=NR) (n = 2 and n = 4, R = cyclohexyl): Why do PtII and PtIV complexes exhibit virtually identical redox behavior and colors?. Chemistry - A European Journal, (1)1:95--99, 1995. [PUMA: charge complex complex;electrochem complex;crystal structure transfer complex;MO platinum property complex;EPR methyl diazabutadiene complex;mol complex;platinum prepn]
Theoretical and experimental study of diamagnetic and paramagnetic products from thermal and light-induced alkyl transfer between zinc or magnesium dialkyls and 1,4-diaza-1,3-butadiene substrates. Journal of the American Chemical Society, (113)15:5606--5618, 1991. [PUMA: diorganozinc photochem dimethylzinc organometallic;mol structure zinc;crystal moment adduct transfer diazabutadiene;magnesium thermal alkyl diazabutadiene dimethylzinc;dipole thermal;MO diorganomagnesium]