Heterohexanuclear (Cu3Fe3) Complexes of Substituted Hexaazatrinaphthylene (HATN) Ligands: Twofold BF4- Association in the Solid and Stepwise Oxidation (3e) or Reduction (2e) to Spectroelectrochemically Characterized Species. Chemistry - A European Journal, (15)28:6932-6939, S6932/1-S6932/7, 2009. [PUMA: EPR;reversible MO couple;trisferrocenylcopper crystal deriv energy ferrocene ferrocenium hexaazatrinaphthylene level ligand mol oxidn prepn redn spectroelectrochem structure;unsubstituted tetrafluoroborate trisferrocenylcopper]
9-Oxidophenalenone: A Noninnocent b-Diketonate Ligand?. Inorganic Chemistry, (51)7:4390--4397, 2012. [PUMA: MO beta bipyridine complex complex;frontier complex;prepn crystal diketonate electrochem mol noninnocent optimized oxidophenalenone redox ruthenium structure]
Stabilization of a Cobalt-Cobalt Bond by Two Cyclic Alkyl Amino Carbenes. Journal of the American Chemical Society, (136)5:1770--1773, 2014. [PUMA: MO alkyl amino bond cAAC carbene cation cobalt crystal cyclic dinuclear electrochem mol prepn prepn;stabilization radical redox;mol redox;optimized structure]
Strong metal-metal coupling in mixed-valent intermediates Cl(L)Ru(m-tppz)Ru(L)Cl+, L = b-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. Dalton Transactions, (41)43:13429--13440, 2012. [PUMA: DFT;optimized MO MO;dinuclear acetylacetonate acetylacetonato crystal diketonate dinuclear electrochem mixed mol prepn pyridylpyrazine redox ruthenium structure valence]