On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds RkPt(m-L)PtRkn, k = 2 or 4. Organometallics, (17)16:3532--3538, 1998. [PUMA: bridged cyclic dinuclear ligand organo organoplatinum organoplatinum;mixed organoplatinum;platinum prepn;spectroelectrochem pyrazine tetrazine valent voltammetry]
Electronic coupling of two Cp*ClM+/Cp*M reaction centers via p conjugated bridging ligands: Similarities and differences between rhodium and iridium analogues. Journal of Organometallic Chemistry, (582)2:153--159, 1999. [PUMA: bidentate binuclear bispyridinyltetrazine center;iridium complex coupling diiridium dirhodium electron intermediate iridium redn redox rhodium spectroelectrochem;mixed tetrazinebispyrinyl valent]
Unconventional mixed-valent complexes of ruthenium and osmium. Angewandte Chemie, International Edition, (46)11:1778--1796, 2007. [PUMA: bridged complex electron exchange intramol ligand mediated mixed osmium review review;review review;valence ruthenium transfer transfer;ruthenium valent]
Probing Mixed Valence in a New tppz-Bridged Diruthenium(III,II) Complex (μ-tppz)Ru(bik)Cl23+ (tppz = 2,3,5,6-Tetrakis(2-pyridyl)pyrazine, bik = 2,2'-Bis(1-methylimidazolyl)ketone): EPR Silence, Intervalence Absorption, and nCO Line Broadening. Inorganic Chemistry, (46)9:3736--3742, 2007. [PUMA: ESR IR UV charge electrochem methylimidazolylketone methylimidazolylketone;intervalence methylimidazolylketone;ruthenium mixed oxidn prepn pyridylpyrazine redn ruthenium transfer transition valent]
Evidence for the dimer-of-(mixed-valent dimers) configuration in tetranuclear (μ4-TCNX)Ru(NH3)548+, TCNX = TCNE and TCNQ, from DFT calculations. Monatshefte fuer Chemie, (140)7:765--773, 2009. [PUMA: complex configuration dimer mixed ruthenium tetracyanoethene tetranuclear valent]