A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, (206)2:229--230, 1993. [PUMA: MO TCNQ complex complex;TCNE complex;frontier complex;magnetic complex;redox complex;spectra electronic moment potential ruthenium structure]
Tetranuclear Pentaammineruthenium Complexes Bridged by p-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States. Inorganic Chemistry, (34)17:4326--4335, 1995. [PUMA: TCNB TCNE TCNQ ammine electrochem ligand;oxidn ligand;redn ligand;ruthenium redox ruthenium tetracyano tetranuclear]
Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: TCNE TCNQ complex complex;MO complex;electron complex;manganese cyclic delocalization manganese voltammetry]
Tetranuclear osmium complexes of tetracyanoquinodimethane TCNQ, 2,2'-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile) and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 22:4455--4460, 1997. [PUMA: TCNB TCNQ charge complex complex;osmium intervalence magnetism magnetism;TCNQ osmium prepn spectroelectrochem spectroelectrochem;TCNB tetranuclear tetranuclear;magnetism transfer]
Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four fac-Re(CO)3(bpy)+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB). Inorganic Chemistry, (42)22:7018--7025, 2003. [PUMA: TCNQ bipyridine carbonyl crystal cyano dinuclear;rhenium electrochem prepn rhenium structure]
Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation. Inorganic Chemistry, (31)15:3269--3276, 1992. [PUMA: TCNE TCNE;ESR TCNQ complex complex;ruthenium electrochem redox ruthenium]
Electron transfer catalyzed substitution in carbonyl complexes. IV. Mononuclear s- and p-coordinated complexes of manganese, chromium and tungsten with tetracyanoethylene and tetracyano-p-quinodimethane. Journal of Organometallic Chemistry, (366)1-2:155--174, 1989. [PUMA: IR TCNQ chromium complex;TCNE elec manganese mechanism metal metal;substitution potential redox solvate tetracyanoethene tungsten]
The coordination chemistry of TCNE, TCNQ and related polynitrile p acceptors. Coordination Chemistry Reviews, (129)1-2:157--193, 1994. [PUMA: TCNE TCNQ coordination review]
The coordination chemistry of TCNE, TCNQ and related polynitrile p acceptors. Coordination Chemistry Reviews, (129)1-2:157--193, 1994. [PUMA: TCNE TCNQ coordination review]
Electron transfer catalyzed substitution in carbonyl complexes. IV. Mononuclear s- and p-coordinated complexes of manganese, chromium and tungsten with tetracyanoethylene and tetracyano-p-quinodimethane. Journal of Organometallic Chemistry, (366)1-2:155--174, 1989. [PUMA: IR TCNQ chromium complex;TCNE elec manganese mechanism metal metal;substitution potential redox solvate tetracyanoethene tungsten]
Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation. Inorganic Chemistry, (31)15:3269--3276, 1992. [PUMA: TCNE TCNE;ESR TCNQ complex complex;ruthenium electrochem redox ruthenium]
Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four fac-Re(CO)3(bpy)+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB). Inorganic Chemistry, (42)22:7018--7025, 2003. [PUMA: TCNQ bipyridine carbonyl crystal cyano dinuclear;rhenium electrochem prepn rhenium structure]
Tetranuclear osmium complexes of tetracyanoquinodimethane TCNQ, 2,2'-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile) and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 22:4455--4460, 1997. [PUMA: TCNB TCNQ charge complex complex;osmium intervalence magnetism magnetism;TCNQ osmium prepn spectroelectrochem spectroelectrochem;TCNB tetranuclear tetranuclear;magnetism transfer]
Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: TCNE TCNQ complex complex;MO complex;electron complex;manganese cyclic delocalization manganese voltammetry]
Tetranuclear Pentaammineruthenium Complexes Bridged by p-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States. Inorganic Chemistry, (34)17:4326--4335, 1995. [PUMA: TCNB TCNE TCNQ ammine electrochem ligand;oxidn ligand;redn ligand;ruthenium redox ruthenium tetracyano tetranuclear]
A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, (206)2:229--230, 1993. [PUMA: MO TCNQ complex complex;TCNE complex;frontier complex;magnetic complex;redox complex;spectra electronic moment potential ruthenium structure]