Tetranuclear osmium complexes of tetracyanoquinodimethane TCNQ, 2,2'-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile) and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 22:4455--4460, 1997. [PUMA: charge TCNB tetranuclear;magnetism osmium complex magnetism spectroelectrochem magnetism;TCNQ complex;osmium transfer tetranuclear spectroelectrochem;TCNB TCNQ intervalence prepn]
Tetranuclear osmium complexes of tetracyanoquinodimethane TCNQ, 2,2'-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile) and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, 22:4455--4460, 1997. [PUMA: charge TCNB tetranuclear;magnetism osmium complex magnetism spectroelectrochem magnetism;TCNQ complex;osmium transfer tetranuclear spectroelectrochem;TCNB TCNQ intervalence prepn]
Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation. Inorganic Chemistry, (31)15:3269--3276, 1992. [PUMA: ruthenium TCNE TCNQ complex;ruthenium complex TCNE;ESR electrochem redox]
Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation. Inorganic Chemistry, (31)15:3269--3276, 1992. [PUMA: ruthenium TCNE TCNQ complex;ruthenium complex TCNE;ESR electrochem redox]
Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: voltammetry TCNE complex;manganese complex;MO TCNQ delocalization complex complex;electron manganese cyclic]
Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: voltammetry TCNE complex;manganese complex;MO TCNQ delocalization complex complex;electron manganese cyclic]
Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four fac-Re(CO)3(bpy)+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB). Inorganic Chemistry, (42)22:7018--7025, 2003. [PUMA: rhenium cyano bipyridine crystal TCNQ dinuclear;rhenium electrochem carbonyl prepn structure]
Proof of Innocence for the Quintessential Noninnocent Ligand TCNQ in Its Tetranuclear Complex with Four fac-Re(CO)3(bpy)+ Groups: Unusually Different Reactivity of the TCNX Ligands (TCNX = TCNE, TCNQ, TCNB). Inorganic Chemistry, (42)22:7018--7025, 2003. [PUMA: rhenium cyano bipyridine crystal TCNQ dinuclear;rhenium electrochem carbonyl prepn structure]
The coordination chemistry of TCNE, TCNQ and related polynitrile p acceptors. Coordination Chemistry Reviews, (129)1-2:157--193, 1994. [PUMA: TCNE TCNQ review coordination]
The coordination chemistry of TCNE, TCNQ and related polynitrile p acceptors. Coordination Chemistry Reviews, (129)1-2:157--193, 1994. [PUMA: TCNE TCNQ review coordination]
A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, (206)2:229--230, 1993. [PUMA: MO complex;TCNE complex;spectra complex;magnetic complex complex;frontier structure moment ruthenium TCNQ complex;redox potential electronic]
A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, (206)2:229--230, 1993. [PUMA: MO complex;TCNE complex;spectra complex;magnetic complex complex;frontier structure moment ruthenium TCNQ complex;redox potential electronic]
Tetranuclear Pentaammineruthenium Complexes Bridged by p-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States. Inorganic Chemistry, (34)17:4326--4335, 1995. [PUMA: ligand;ruthenium ruthenium TCNE tetranuclear TCNB TCNQ ligand;redn ligand;oxidn ammine electrochem redox tetracyano]
Tetranuclear Pentaammineruthenium Complexes Bridged by p-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States. Inorganic Chemistry, (34)17:4326--4335, 1995. [PUMA: ligand;ruthenium ruthenium TCNE tetranuclear TCNB TCNQ ligand;redn ligand;oxidn ammine electrochem redox tetracyano]
Electron transfer catalyzed substitution in carbonyl complexes. IV. Mononuclear s- and p-coordinated complexes of manganese, chromium and tungsten with tetracyanoethylene and tetracyano-p-quinodimethane. Journal of Organometallic Chemistry, (366)1-2:155--174, 1989. [PUMA: chromium complex;TCNE IR metal elec manganese redox metal;substitution solvate tungsten tetracyanoethene TCNQ mechanism potential]
Electron transfer catalyzed substitution in carbonyl complexes. IV. Mononuclear s- and p-coordinated complexes of manganese, chromium and tungsten with tetracyanoethylene and tetracyano-p-quinodimethane. Journal of Organometallic Chemistry, (366)1-2:155--174, 1989. [PUMA: chromium complex;TCNE IR metal elec manganese redox metal;substitution solvate tungsten tetracyanoethene TCNQ mechanism potential]