Establishing the NO oxidation state in complexes Cl5(NO)Mn-, M = Ru or Ir, through experiments and DFT calculations. Dalton Transactions, 12:1797--1800, 2004. [PUMA: DFT chloro complex complex;nitrosyl electrochem iridium nitrosyl oxidn redn ruthenium state]
Conjugation Length Dependent Ground and Excited State Electronic Behavior in Oligothienyl Ru Complexes. Inorganic Chemistry, (45)18:7044--7046, 2006. [PUMA: bipyridine bipyridyl chain complex excited ground phosphine phosphinothiophene photoexcitation photolysis;oligothienyl ruthenium state]
Sensitive Oxidation State Ambivalence in Unsymmetrical Three-Center (M/Q/M) Systems (acac)2Ru(m-Q)Ru(acac)2n, Q = 1,10-Phenanthroline-5,6-dione or 1,10-Phenanthroline-5,6-diimine (n = +, 0, -, 2-). Inorganic Chemistry, (44)9:3210--3214, 2005. [PUMA: EPR complex dinuclear oxidn phenanthrolinediimine phenanthrolinediimine;ruthenium phenanthrolinedione prepn ruthenium spectroelectrochem state unsym]
Application of a Structure/Oxidation-State Correlation to Complexes of Bridging Azo Ligands. Chemistry - A European Journal, (18)35:11007-11018, S11007/1-S11007/28, 2012. [PUMA: azobispyridine complex complex;ruthenium crystal electron ligand noninnocent oxidn prepn relationship ruthenium state structure;structure transfer]
At the Borderline between Metal-Metal Mixed Valency and a Radical Bridge Situation: Four Charge States of a Diruthenium Complex with a Redox-Active Bis(mer-tridentate) Ligand. Inorganic Chemistry, (57)7:3983--3992, 2018. [PUMA: DFT active;ruthenium analysis bridge charge complex;mixed crystal diruthenium prepn radical redox ruthenium salicyloylhydrazide spectroelectrochem state structure tertbutylterpyridine valency]
RuII(a-diimine) or RuIII(a-diimine·-)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State. European Journal of Inorganic Chemistry, (2014)1:110--119, 2014. [PUMA: ESR acetylacetonato alpha charge complex configuration crystal diazabutadiene excited ground ligand metal mol pentanedionate prepn radical ruthenium spectroelectrochem;diimine state structure;stabilization transfer]
Varying electronic structural forms of ruthenium complexes of non-innocent 9,10-phenanthrenequinonoid ligands. Dalton Transactions, (43)6:2473--2487, 2014. [PUMA: MO acetylacetonato complex crystal electrochem ground magnetism;DFT phenanthrenequinonoid prepn ruthenium state structure]
Varying electronic structural forms of ruthenium complexes of non-innocent 9,10-phenanthrenequinonoid ligands. Dalton Transactions, (43)6:2473--2487, 2014. [PUMA: MO acetylacetonato complex crystal electrochem ground magnetism;DFT phenanthrenequinonoid prepn ruthenium state structure]
RuII(a-diimine) or RuIII(a-diimine·-)? Structural, Spectroscopic, and Theoretical Evidence for the Stabilization of a Prominent Metal-to-Ligand Charge-Transfer Excited-State Configuration in the Ground State. European Journal of Inorganic Chemistry, (2014)1:110--119, 2014. [PUMA: ESR acetylacetonato alpha charge complex configuration crystal diazabutadiene excited ground ligand metal mol pentanedionate prepn radical ruthenium spectroelectrochem;diimine state structure;stabilization transfer]
At the Borderline between Metal-Metal Mixed Valency and a Radical Bridge Situation: Four Charge States of a Diruthenium Complex with a Redox-Active Bis(mer-tridentate) Ligand. Inorganic Chemistry, (57)7:3983--3992, 2018. [PUMA: DFT active;ruthenium analysis bridge charge complex;mixed crystal diruthenium prepn radical redox ruthenium salicyloylhydrazide spectroelectrochem state structure tertbutylterpyridine valency]
Application of a Structure/Oxidation-State Correlation to Complexes of Bridging Azo Ligands. Chemistry - A European Journal, (18)35:11007-11018, S11007/1-S11007/28, 2012. [PUMA: azobispyridine complex complex;ruthenium crystal electron ligand noninnocent oxidn prepn relationship ruthenium state structure;structure transfer]
Sensitive Oxidation State Ambivalence in Unsymmetrical Three-Center (M/Q/M) Systems (acac)2Ru(m-Q)Ru(acac)2n, Q = 1,10-Phenanthroline-5,6-dione or 1,10-Phenanthroline-5,6-diimine (n = +, 0, -, 2-). Inorganic Chemistry, (44)9:3210--3214, 2005. [PUMA: EPR complex dinuclear oxidn phenanthrolinediimine phenanthrolinediimine;ruthenium phenanthrolinedione prepn ruthenium spectroelectrochem state unsym]
Conjugation Length Dependent Ground and Excited State Electronic Behavior in Oligothienyl Ru Complexes. Inorganic Chemistry, (45)18:7044--7046, 2006. [PUMA: bipyridine bipyridyl chain complex excited ground phosphine phosphinothiophene photoexcitation photolysis;oligothienyl ruthenium state]
Establishing the NO oxidation state in complexes Cl5(NO)Mn-, M = Ru or Ir, through experiments and DFT calculations. Dalton Transactions, 12:1797--1800, 2004. [PUMA: DFT chloro complex complex;nitrosyl electrochem iridium nitrosyl oxidn redn ruthenium state]
Sensitive Oxidation State Ambivalence in Unsymmetrical Three-Center (M/Q/M) Systems (acac)2Ru(m-Q)Ru(acac)2n, Q = 1,10-Phenanthroline-5,6-dione or 1,10-Phenanthroline-5,6-diimine (n = +, 0, -, 2-). Inorganic Chemistry, (44)9:3210--3214, 2005. [PUMA: EPR complex dinuclear oxidn phenanthrolinediimine phenanthrolinediimine;ruthenium phenanthrolinedione prepn ruthenium spectroelectrochem state unsym]