Chemistry of C-trimethylsilyl-substituted heterocarboranes. 10. Syntheses, structures, and properties of anionic chromium(III) and neutral chromium(IV) sandwiched metallacarborane complexes 1,1'-commo-Cr[2-(SiMe3)-3-(R)-2,3-C2B4H4]2- and 1,1'-commo-Cr[2,3-(SiMe3)2-2,3-C2B4H4]2 (R = SiMe3, Me, and H). Organometallics, (11)12:4202--4213, 1992. [PUMA: chromium sandwich;MO susceptibility crystal sandwich;mol metallacarborane Hall Fenske sandwich structure;magnetic structure]
Chemistry of C-trimethylsilyl-substituted heterocarboranes. 10. Syntheses, structures, and properties of anionic chromium(III) and neutral chromium(IV) sandwiched metallacarborane complexes 1,1'-commo-Cr[2-(SiMe3)-3-(R)-2,3-C2B4H4]2- and 1,1'-commo-Cr[2,3-(SiMe3)2-2,3-C2B4H4]2 (R = SiMe3, Me, and H). Organometallics, (11)12:4202--4213, 1992. [PUMA: chromium sandwich;MO susceptibility crystal sandwich;mol metallacarborane Hall Fenske sandwich structure;magnetic structure]