Four-Center Oxidation State Combinations and Near-Infrared Absorption in Ru(pap)(Q)2n (Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine, pap = 2-Phenylazopyridine). Chemistry - A European Journal, (19)23:7384--7394, 2013. [PUMA: NIR benzoquinoneimine cationic complex crystal ligand neutral noninnocent phenylazopyridine prepn;electrochem redox ruthenium structure]
Oxidation State Analysis of a Four-Component Redox Series Os(pap)2(Q)n Involving Two Different Non-Innocent Ligands on a Redox-Active Transition Metal. Inorganic Chemistry, (50)15:7090--7098, 2011. [PUMA: ESR NIR complex complex;osmium crystal cyclic iminobenzoquinone osmium phenylazopyridine prepn spectra structure voltammetry]
Noninnocently Behaving Bridging Anions of the Widely Distributed Antioxidant Ellagic Acid in Diruthenium Complexes. Inorganic Chemistry, (54)20:10049--10057, 2015. [PUMA: DFT bipyridine complex crystal electrochem ellagate pentanedionate phenylazopyridine phenylazopyridine;ruthenium prepn ruthenium structure]
Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes A2Ru(m-L)RuA2n, A = 2,4-pentanedionato or 2-phenylazopyridine, L2- = 2,5-bis(2-oxidophenyl)pyrazine. Dalton Transactions, 23:2411--2418, 2007. [PUMA: acetylacetonate complex crystal dinuclear electrochem hydroxyphenyl mononuclear pentanedionate phenylazopyridine prepn pyrazine pyrazine;ruthenium redox;spectroelectrochem ruthenium structure]
Metal-Metal Bridging Using the DPPP Dye System: Electronic Configurations within Multiple Redox Series. Inorganic Chemistry, (56)5:2992--3004, 2017. [PUMA: bipyridine complex;optimized complex;redox complex;ruthenium crystal dihydrodipyridylpyrrolopyrroledione frontier mol orbital pentanedionato phenylazopyridine potential prepn ruthenium structure]
Different manifestations of enhanced p-acceptor ligation at every redox level of Os(9-OP)L2n, n = 2+, +, 0, - (9-OP- = 9-oxidophenalenone and L = bpy or pap). Dalton Transactions, (45)45:18241--18251, 2016. [PUMA: bipyridine complex crystal electrochem mol optimization osmium oxidophenalenone phenylazopyridine phenylazopyridine;ESR phenylazopyridine;osmium prepn structure]
Noninnocence of Indigo: Dehydroindigo Anions as Bridging Electron-Donor Ligands in Diruthenium Complexes. Inorganic Chemistry, (55)6:3105--3116, 2016. [PUMA: complex;ruthenium crystal dehydroindigo dinuclear electrochem electronic mononuclear phenylazopyridine prepn ruthenium spectroelectrochem structure]
Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, (54)16:7936--7944, 2015. [PUMA: UV bipyridine complex complex;IR complex;electron complex;osmium crystal density diaminoanthraquinone dihydroxyanthraquinone osmium phenylazopyridine potential prepn redox spectroelectrochem spin structure]
Experimental- and DFT Evidence for the Fractional Non-Innocence of a b-Diketonate Ligand. Chemistry - A European Journal, (18)45:14434-14443, S14434/1-S14434/24, 2012. [PUMA: calcn complex complex;ruthenium cyclic diketonate electron exchange ligand noninnocent oxidophenalenone oxidophenalenone;DFT oxidophenalenone;EPR oxidophenalenone;noninnocence phenylazopyridine prepn ruthenium voltammetry]
Ancillary Ligand Control of Electronic Structure in o-Benzoquinonediimine-Ruthenium Complex Redox Series: Structures, Electron Paramagnetic Resonance (EPR), and Ultraviolet-Visible-Near-Infrared (UV-vis-NIR) Spectroelectrochemistry. Inorganic Chemistry, (54)7:3376--3386, 2015. [PUMA: acetylacetonate benzoquinonediimine bipyridine complex complex;DFT complex;ruthenium crystal electrochem electron phenylazopyridine prepn;spectroelectrochem ruthenium structure transition]
Ancillary Ligand Control of Electronic Structure in o-Benzoquinonediimine-Ruthenium Complex Redox Series: Structures, Electron Paramagnetic Resonance (EPR), and Ultraviolet-Visible-Near-Infrared (UV-vis-NIR) Spectroelectrochemistry. Inorganic Chemistry, (54)7:3376--3386, 2015. [PUMA: acetylacetonate benzoquinonediimine bipyridine complex complex;DFT complex;ruthenium crystal electrochem electron phenylazopyridine prepn;spectroelectrochem ruthenium structure transition]
Experimental- and DFT Evidence for the Fractional Non-Innocence of a b-Diketonate Ligand. Chemistry - A European Journal, (18)45:14434-14443, S14434/1-S14434/24, 2012. [PUMA: calcn complex complex;ruthenium cyclic diketonate electron exchange ligand noninnocent oxidophenalenone oxidophenalenone;DFT oxidophenalenone;EPR oxidophenalenone;noninnocence phenylazopyridine prepn ruthenium voltammetry]
Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, (54)16:7936--7944, 2015. [PUMA: UV bipyridine complex complex;IR complex;electron complex;osmium crystal density diaminoanthraquinone dihydroxyanthraquinone osmium phenylazopyridine potential prepn redox spectroelectrochem spin structure]
Noninnocence of Indigo: Dehydroindigo Anions as Bridging Electron-Donor Ligands in Diruthenium Complexes. Inorganic Chemistry, (55)6:3105--3116, 2016. [PUMA: complex;ruthenium crystal dehydroindigo dinuclear electrochem electronic mononuclear phenylazopyridine prepn ruthenium spectroelectrochem structure]
Different manifestations of enhanced p-acceptor ligation at every redox level of Os(9-OP)L2n, n = 2+, +, 0, - (9-OP- = 9-oxidophenalenone and L = bpy or pap). Dalton Transactions, (45)45:18241--18251, 2016. [PUMA: bipyridine complex crystal electrochem mol optimization osmium oxidophenalenone phenylazopyridine phenylazopyridine;ESR phenylazopyridine;osmium prepn structure]
Metal-Metal Bridging Using the DPPP Dye System: Electronic Configurations within Multiple Redox Series. Inorganic Chemistry, (56)5:2992--3004, 2017. [PUMA: bipyridine complex;optimized complex;redox complex;ruthenium crystal dihydrodipyridylpyrrolopyrroledione frontier mol orbital pentanedionato phenylazopyridine potential prepn ruthenium structure]
Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes A2Ru(m-L)RuA2n, A = 2,4-pentanedionato or 2-phenylazopyridine, L2- = 2,5-bis(2-oxidophenyl)pyrazine. Dalton Transactions, 23:2411--2418, 2007. [PUMA: acetylacetonate complex crystal dinuclear electrochem hydroxyphenyl mononuclear pentanedionate phenylazopyridine prepn pyrazine pyrazine;ruthenium redox;spectroelectrochem ruthenium structure]
Noninnocently Behaving Bridging Anions of the Widely Distributed Antioxidant Ellagic Acid in Diruthenium Complexes. Inorganic Chemistry, (54)20:10049--10057, 2015. [PUMA: DFT bipyridine complex crystal electrochem ellagate pentanedionate phenylazopyridine phenylazopyridine;ruthenium prepn ruthenium structure]
Oxidation State Analysis of a Four-Component Redox Series Os(pap)2(Q)n Involving Two Different Non-Innocent Ligands on a Redox-Active Transition Metal. Inorganic Chemistry, (50)15:7090--7098, 2011. [PUMA: ESR NIR complex complex;osmium crystal cyclic iminobenzoquinone osmium phenylazopyridine prepn spectra structure voltammetry]
Four-Center Oxidation State Combinations and Near-Infrared Absorption in Ru(pap)(Q)2n (Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine, pap = 2-Phenylazopyridine). Chemistry - A European Journal, (19)23:7384--7394, 2013. [PUMA: NIR benzoquinoneimine cationic complex crystal ligand neutral noninnocent phenylazopyridine prepn;electrochem redox ruthenium structure]