Publications

Wolfgang. Kaim. Metal compounds of the TCNX redox systems - from electron transfer to spin distribution and magnetism. Journal of the Chilean Chemical Society, (53)1:1353--1355, 2008. [PUMA: TCNX compd electron magnetism metal redox spin system transfer]

Electron transfer-induced coordination changes in organometallic complexes with noninnocent hemilabile ligands: Adv. Organomet. Chem. Catal. In Wolfgang Kaim, Martina Bubrin, and Ralph. Huebner (Eds.), John Wiley & Sons, Inc, 2014. [PUMA: change complex coordination electron hemilabileligand noninnocent organometallic review transfer]

Wolfgang. Kaim. Electron transfer by Grignard reagents: Direct detection of organomagnesium radical complexes. Angewandte Chemie, (94)2:150, 1982. [PUMA: Grignard;ESR complex electron magnesiopyrazine pyrazine radical transfer]

Amarendra N. Maity, Brigitte Schwederski, Biprajit Sarkar, Stanislav Zalis, Jan Fiedler, Sanjib Kar, Goutam K. Lahiri, Carole Duboc, Matthias Grunert, Philipp Guetlich, and Wolfgang. Kaim. Tetranuclear Complexes of Fe(CO)2(C5H5)+ with TCNX Ligands (TCNX = TCNE, TCNQ, TCNB): Intramolecular Electron Transfer Alternatives in Compounds (m4-TCNX)MLn4. Inorganic Chemistry, (46)18:7312--7320, 2007. [PUMA: DFT EPR cyclopentadienyl dicarbonyl electrochem electron geometry iron redox structure tetracyanoethene tetracyanoquinodimethane transfer transfer;Moessbauer transfer;electronic transfer;optimized]

Wolfgang. Kaim. Thermal and light induced electron transfer reactions of Main Group metal hydrides and organometallics. Topics in Current Chemistry, (169)Electron Transfer I:231--251, 1994. [PUMA: Group Main electron hydride induced light review;organometallic review;review transfer]

Heiko Hartmann, Biprajit Sarkar, Wolfgang Kaim, and Jan. Fiedler. Electron transfer reactions of (C5R5)2(CO)2Ti (R = H or Me) with TCNE or TCNQ spectroelectrochemical assignment of metal and ligand oxidation states in (C5Me5)2(CO)Ti(TCNX)2-/-/o/+. Journal of Organometallic Chemistry, (687)1:100--107, 2003. [PUMA: EPR carbonyl complex cyclopentadienyl electrochem electron redox tetracyanoethene tetracyanoquinodimethane titanium;IR titanium;titanium transfer]

Wolfgang Kaim, and Goutam Kumar. Lahiri. Unconventional mixed-valent complexes of ruthenium and osmium. Angewandte Chemie, International Edition, (46)11:1778--1796, 2007. [PUMA: bridged complex electron exchange intramol ligand mediated mixed osmium review review;review review;valence ruthenium transfer transfer;ruthenium valent]

Infrared spectroelectrochemical investigations of ultrafast electron transfer in mixed-valence complexes: Spectroelectrochem. In J. Catherine Salsman, and Clifford P. Kubiak (Eds.), Royal Society of Chemistry, 2008. [PUMA: IR cell design;ultrafast electron mixed reflectance review spectroelectrochem transfer valence]

Wolfgang. Kaim. Complete and partial electron transfer involving coordinated NOx. Advances in Inorganic Chemistry, (67):295--313, 2015. [PUMA: electron nitrogen oxide transfer]

Wolfgang Kaim, Matthias Wanner, Axel Knodler, and Stanislav. Zalis. Copper complexes with non-innocent ligands: Probing CuII/catecholato-CuI/o-semiquinonato redox isomer equilibria with EPR spectroscopy. Inorganica Chimica Acta, (337):163--172, 2002. [PUMA: EPR;crystal aminoethylphosphine catecholato complex copper electron prepn semiquinonato structure structure;copper transfer]

Spectroelectrochemistry of metalloporphyrins: Spectroelectrochem. In Axel. Klein (Eds.), Royal Society of Chemistry, 2008. [PUMA: electron metalloporphyrin porphyrin review spectroelectrochem spectroscopy transfer]

Frank Elbe, Juergen Keck, Anja P. Fluegge, Horst E. A. Kramer, Peter Fischer, Pascal Hayoz, David Leppard, Gerhard Rytz, Wolfgang Kaim, and Michael. Ketterle. Photochemical and Photophysical Deactivation of 2,4,6-Triaryl-1,3,5-triazines. Journal of Physical Chemistry A, (104)35:8296--8306, 2000. [PUMA: aryltriazine;triazine effect electron fluorescence intramol photoinduced protonation quenching transfer twisted]

Thomas Stahl, Volker Kasack, and Wolfgang. Kaim. Conformational equilibria of 2,5-bis1-(phenylimino)ethylpyrazine anion radical (bpip·-). An electron paramagnetic resonance/electron-nuclear double resonance study of bpip·-, (bpip·-)(RMg+)2, and of the related anion radical of N-tert-butylpyridine-2-carbaldimine (But-pyca). Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry, 12:2127--2131, 1995. [PUMA: ENDOR ENDOR;conformation ENDOR;electron ENDOR;pyridinecarboxaldimine ESR anion butyl diimine diimine;pyrazine ditolyl ditolylmagnesium;magnesium electron phenyliminoethyl radical transfer]

Wolfgang Kaim, and Stephen. Kohlmann. Design and evaluation of conjugated bridging p systems. Molecular orbital characterization and electrochemical determination of the pentacarbonyltungsten binding site in two new ambidentate ligands. Inorganic Chemistry, (29)10:1898--1902, 1990. [PUMA: azopyridine bispyridyltetrazine bridging carbonyl complex complex;MO cyclic electron pi potential system;elec transfer tungsten voltammetry;conjugated]

Prasenjit Mondal, Sebastian Plebst, Ritwika Ray, Shaikh M. Mobin, Wolfgang Kaim, and Goutam Kumar. Lahiri. Uncommon cis Configuration of a Metal-Metal Bridging Noninnocent Nindigo Ligand. Inorganic Chemistry, (53)17:9348--9356, 2014. [PUMA: acac bipyridine crystal dinuclear;ruthenium electron electronic mononuclear noninnocent phenylimineindigo prepn ruthenium spectroelectrochem structure transfer]

Wolfgang Kaim, and Wolfgang. Lubitz. Radical products in single electron transfer reactions of lithium triethylhydridoborate as detected by ESR and multinuclear (proton, boron-10, boron-11, and nitrogen-14) ENDOR spectroscopy. Angewandte Chemie, (95)11:915--916, 1983. [PUMA: ENDOR;electron bipyridine bipyridine;ENDOR bipyridine;boron borohydride complex coupling electron hyperfine lithium transfer triethyl triethylhydridoborate triethylhydridoborate;ESR triethylhydridoborate;TRIPLE]

Biprajit Sarkar, Srikanta Patra, Jan Fiedler, Raghavan B. Sunoj, Deepa Janardanan, Goutam Kumar Lahiri, and Wolfgang. Kaim. Mixed-Valent Metals Bridged by a Radical Ligand: Fact or Fiction Based on Structure-Oxidation State Correlations. Journal of the American Chemical Society, (130)11:3532--3542, 2008. [PUMA: acetylacetonate azobispyridine azobispyrimidine complex complex;ESR complex;MO complex;geometry complex;ruthenium electron optimized prepn ruthenium transfer]

Amit Das, Thomas Michael Scherer, Shaikh M. Mobin, Wolfgang Kaim, and Goutam Kumar. Lahiri. Application of a Structure/Oxidation-State Correlation to Complexes of Bridging Azo Ligands. Chemistry - A European Journal, (18)35:11007-11018, S11007/1-S11007/28, 2012. [PUMA: azobispyridine complex complex;ruthenium crystal electron ligand noninnocent oxidn prepn relationship ruthenium state structure;structure transfer]

Wolfgang Kaim, Barbara Olbrich-Deussner, Renate Gross, Sylvia Ernst, Stephan Kohlmann, and Christian. Bessenbacher. Electron transfer induced metal addition and ligand exchange in organometallic anion radical complexes. NATO ASI Series, Series C: Mathematical and Physical Sciences, (257)Paramagn. Organomet. Species Act./Sel., Catal:283--294, 1989. [PUMA: anion complex electron formation metal reaction review;polynuclear review;review transfer transition]

Frank Baumann, Martina Heilmann, Walther Matheis, Andreas Schulz, Wolfgang Kaim, and Jeanne. Jordanov. Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt. Inorganica Chimica Acta, (251)1-2:239--248, 1996. [PUMA: TCNE UV cobalt complex;IR complex;electron complex;magnetic complex;osmium electron ground metal property state transfer transfer;electrochem transfer;ruthenium transfer;vanadium]