Electron-rich olefins. 3. Formation of the first N,N'-persilylated 1,4-diaminoethene via a 1,2,3-triazoline(4) intermediate with 8 cyclically conjugated p electrons and 3 neighboring nitrogen electron pairs. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (44)5:511--518, 1989. [PUMA: photoelectron radical conformation;ring conjugation cation reductive silyl cleavage ESR;conformation silyltriazole;silylation tetrasilylethenediamine silylation spectra;ethenediamine mechanism;triazole tetrasilyl intermediate silyltriazole trisilyl mechanism;triazoline prepn]
Electron-rich olefins. 3. Formation of the first N,N'-persilylated 1,4-diaminoethene via a 1,2,3-triazoline(4) intermediate with 8 cyclically conjugated p electrons and 3 neighboring nitrogen electron pairs. Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences, (44)5:511--518, 1989. [PUMA: photoelectron radical conformation;ring conjugation cation reductive silyl cleavage ESR;conformation silyltriazole;silylation tetrasilylethenediamine silylation spectra;ethenediamine mechanism;triazole tetrasilyl intermediate silyltriazole trisilyl mechanism;triazoline prepn]
Effects of cyclic 8p-electron conjugation in reductively silylated nitrogen heterocycles. Journal of the American Chemical Society, (105)4:707--713, 1983. [PUMA: heterocycle;dihydropyrazine nitrogen antiaromaticity conjugation silyl silylated]
Effects of cyclic 8p-electron conjugation in reductively silylated nitrogen heterocycles. Journal of the American Chemical Society, (105)4:707--713, 1983. [PUMA: heterocycle;dihydropyrazine nitrogen antiaromaticity conjugation silyl silylated]
Charge delocalization in a heterobimetallic ferrocene-(vinyl)Ru(CO)Cl(PiPr3)2 system. Organometallics, (28)14:4196--4209, 2009. [PUMA: sigma electrooxidn;mol crystal orbital complex mixed conjugation valence complex;solvent complex;frontier spectra structure ruthenium complex;vinylferrocene ethenylruthenium ferrocenyl effect calcn complex;mixed oxidn electronic communication prepn]
Charge delocalization in a heterobimetallic ferrocene-(vinyl)Ru(CO)Cl(PiPr3)2 system. Organometallics, (28)14:4196--4209, 2009. [PUMA: sigma electrooxidn;mol crystal orbital complex mixed conjugation valence complex;solvent complex;frontier spectra structure ruthenium complex;vinylferrocene ethenylruthenium ferrocenyl effect calcn complex;mixed oxidn electronic communication prepn]
Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: A case of non-innocence in organometallic chemistry. Journal of the American Chemical Society, (130)1:259--268, 2008. [PUMA: vinylruthenium ESR conjugated complex;ruthenium complex conjugation pyrenylethenyl carbonyl spectra pyridine complex;crystal structure ruthenium styryl effect pi hexenyl electrooxidn;spectroelectrochem complex;mol phosphine oxidn vinyl potential prepn]
Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: A case of non-innocence in organometallic chemistry. Journal of the American Chemical Society, (130)1:259--268, 2008. [PUMA: vinylruthenium ESR conjugated complex;ruthenium complex conjugation pyrenylethenyl carbonyl spectra pyridine complex;crystal structure ruthenium styryl effect pi hexenyl electrooxidn;spectroelectrochem complex;mol phosphine oxidn vinyl potential prepn]