Publications

Frank Baumann, Andreas Stange, and Wolfgang. Kaim. Interaction of two equivalent electron transfer/atom transfer centers via 2,2'-bipyrimidine as bridging ligand. Inorganic Chemistry Communications, (1)8:305--308, 1998. [PUMA: crystal osmium electrochem complex complex;electrochem complex;electron complex;electronic bipyrimidine cymene structure dinuclear transfer complex;redox complex;mol atom mononuclear communication]

Arijit Singha Hazari, Abhishek Mandal, Katharina Beyer, Alexa Paretzki, Wolfgang Kaim, and Goutam Kumar. Lahiri. Metal-Metal Bridging Using the DPPP Dye System: Electronic Configurations within Multiple Redox Series. Inorganic Chemistry, (56)5:2992--3004, 2017. [PUMA: frontier bipyridine phenylazopyridine crystal complex;ruthenium orbital mol dihydrodipyridylpyrrolopyrroledione structure ruthenium complex;redox pentanedionato complex;optimized potential prepn]

Markus Gloeckle, Wolfgang Kaim, Nestor E. Katz, Monica Garcia Posse, Edgardo H. Cutin, and Jan. Fiedler. The FeIII/FeII vs. Fe22.5 Formulation in Mixed-Valent Species (NC)4Fe(BL)Fe(CN)43-, BL = 2,2'-Bipyrimidine and 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Distance and Size Do Not Always Matter. Inorganic Chemistry, (38)14:3270--3274, 1999. [PUMA: complex;spectroelectrochem cyano complex;redn electrochem complex bipyrimidine complex;iron dinuclear tetrazinebispyridine complex;redox iron prepn;oxidn spectro potential]

Mohd. Asif Ansari, Abhishek Mandal, Katharina Beyer, Alexa Paretzki, Brigitte Schwederski, Wolfgang Kaim, and Goutam Kumar. Lahiri. Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand. Dalton Transactions, (46)44:15589--15598, 2017. [PUMA: frontier crystal complex;ruthenium orbital mol complex structure multinuclear ruthenium complex;redox complex;optimized tetraazapentacenequinone potential prepn]

Amarendra Nath Maity, Brigitte Schwederski, and Wolfgang. Kaim. The redox pair (μ4-TCNE)Fe(CO)2(C5H5)44+/3+: Surprisingly small metal-ligand interaction and the first resolved EPR hyperfine structure (13C, 14N, 57Fe) of a tetranuclear complex with TCNE-. Inorganic Chemistry Communications, (8)7:600--602, 2005. [PUMA: hyperfine complex;tetracyanoethylene charge nitrogen complex;metal MLCT dicarbonyl tetracyanoethylene transfer spectrum complex;redox iron coordinated complex;EPR interaction prepn complex ligand coupling tetranuclear cyclopentadienyl cyclopentadienyliron band bridged potential]

Sascha Berger, Thomas Scheiring, Jan Fiedler, and Wolfgang. Kaim. Coupling of organometallic reaction centers through the non-planar bridging ligand 2,3-bis(2-pyridyl)pyrazine. Zeitschrift fuer Anorganische und Allgemeine Chemie, (630)13-14:2409--2417, 2004. [PUMA: half crystal complex bis sandwich structure iridium pentamethylcyclopentadienyl complex;rhodium pyridylpyrazine binuclear complex;redox complex;mol rhodium potential mononuclear prepn]

Sascha Berger, Thomas Scheiring, Jan Fiedler, and Wolfgang. Kaim. Coupling of organometallic reaction centers through the non-planar bridging ligand 2,3-bis(2-pyridyl)pyrazine. Zeitschrift fuer Anorganische und Allgemeine Chemie, (630)13-14:2409--2417, 2004. [PUMA: half crystal complex bis sandwich structure iridium pentamethylcyclopentadienyl complex;rhodium pyridylpyrazine binuclear complex;redox complex;mol rhodium potential mononuclear prepn]

Walter Matheis, and Wolfgang. Kaim. Electronic structure of heterodinuclear complexes (bpy)2RuII(m-bpym)MLn; bpy = 2,2'-bipyridine; bpym = 2,2'-bipyrimidine; MLn = Cu(PPh3)2, Mo(CO)4, Re(CO)3Cl. Inorganica Chimica Acta, (181)1:15--21, 1991. [PUMA: bipyridine ESR heterobinuclear complex;ruthenium heterobinuclear;rhenium electrochem complex metal complex;molybdenum heterodinuclear bipyrimidine transition ruthenium complex;redox complex;copper]

Michael Moscherosch, and Wolfgang. Kaim. A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, (206)2:229--230, 1993. [PUMA: MO complex;TCNE complex;spectra complex;magnetic complex complex;frontier structure moment ruthenium TCNQ complex;redox potential electronic]