A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, (206)2:229--230, 1993. [PUMA: MO TCNQ complex complex;TCNE complex;frontier complex;magnetic complex;redox complex;spectra electronic moment potential ruthenium structure]
Electronic structure of a heterotetranuclear copper(I)2-iron(II)2 complex bridged by p-accepting 2,2'-bipyrimidine. Close-lying but orthogonal frontier orbitals. Journal of Organometallic Chemistry, (398)3:293--298, 1990. [PUMA: MO bipyrimidine complex complex;ESR complex;frontier complex;iron configuration copper ferrocene iron tetranuclear tetranuclear;electron]
9-Oxidophenalenone: A Noninnocent b-Diketonate Ligand?. Inorganic Chemistry, (51)7:4390--4397, 2012. [PUMA: MO beta bipyridine complex complex;frontier complex;prepn crystal diketonate electrochem mol noninnocent optimized oxidophenalenone redox ruthenium structure]
Charge delocalization in a heterobimetallic ferrocene-(vinyl)Ru(CO)Cl(PiPr3)2 system. Organometallics, (28)14:4196--4209, 2009. [PUMA: calcn communication complex complex;frontier complex;mixed complex;solvent complex;vinylferrocene conjugation crystal effect electronic electrooxidn;mol ethenylruthenium ferrocenyl mixed orbital oxidn prepn ruthenium sigma spectra structure valence]
(μ-L)RuII(acac)22n, n = 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates. Dalton Transactions, 5:750--753, 2004. [PUMA: DFT IR MO binuclear calcn;near complex complex;EPR complex;frontier complex;ruthenium electrochem paramagnetic prepn redox ruthenium spectroelectrochem tetraiminobiphenyl]
(μ-L)RuII(acac)22n, n = 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates. Dalton Transactions, 5:750--753, 2004. [PUMA: DFT IR MO binuclear calcn;near complex complex;EPR complex;frontier complex;ruthenium electrochem paramagnetic prepn redox ruthenium spectroelectrochem tetraiminobiphenyl]
Charge delocalization in a heterobimetallic ferrocene-(vinyl)Ru(CO)Cl(PiPr3)2 system. Organometallics, (28)14:4196--4209, 2009. [PUMA: calcn communication complex complex;frontier complex;mixed complex;solvent complex;vinylferrocene conjugation crystal effect electronic electrooxidn;mol ethenylruthenium ferrocenyl mixed orbital oxidn prepn ruthenium sigma spectra structure valence]
9-Oxidophenalenone: A Noninnocent b-Diketonate Ligand?. Inorganic Chemistry, (51)7:4390--4397, 2012. [PUMA: MO beta bipyridine complex complex;frontier complex;prepn crystal diketonate electrochem mol noninnocent optimized oxidophenalenone redox ruthenium structure]
Electronic structure of a heterotetranuclear copper(I)2-iron(II)2 complex bridged by p-accepting 2,2'-bipyrimidine. Close-lying but orthogonal frontier orbitals. Journal of Organometallic Chemistry, (398)3:293--298, 1990. [PUMA: MO bipyrimidine complex complex;ESR complex;frontier complex;iron configuration copper ferrocene iron tetranuclear tetranuclear;electron]
A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes (μ4-TCNX)Ru(NH3)548+ (TCNX = TCNE, TCNQ). Inorganica Chimica Acta, (206)2:229--230, 1993. [PUMA: MO TCNQ complex complex;TCNE complex;frontier complex;magnetic complex;redox complex;spectra electronic moment potential ruthenium structure]