Publications

Renate Gross, and Wolfgang. Kaim. Deprotonated p-phenylenediamines as noninnocent ligands. Metal-to-ligand spin transfer in the ground state and ligand-to-metal charge transfer in the lowest excited state of low-spin manganese(II) complexes. Inorganic Chemistry, (26)21:3596--3600, 1987. [PUMA: MO amide charge complex complex;ESR complex;electron complex;manganese configuration cyclopentadienylmanganese;deprotonation manganese phenylenediamine transfer]

Renate Gross-Lannert, Wolfgang Kaim, and Barbara. Olbrich-Deussner. Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: TCNE TCNQ complex complex;MO complex;electron complex;manganese cyclic delocalization manganese voltammetry]

Martina Heilmann, Stephanie Frantz, Wolfgang Kaim, Jan Fiedler, and Carole. Duboc. Mixed-valent and radical states of complexes (bpy)2M(m-abpy)M'(bpy)2n+, M,M' = Ru or Os, abpy = 2,2'-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes. Inorganica Chimica Acta, (359)3:821--829, 2006. [PUMA: EPR azobispyridine bridge complex complex;electron complex;hole complex;mixed cyclic electrochem heterobinuclear;osmium homobinuclear osmium prepn redox ruthenium spectroelectrochem;radical transfer valence voltammetry]

Sylvia Ernst, Volker Kasack, and Wolfgang. Kaim. What determines the comproportionation constant in molecule-bridged mixed-valence complexes? Evidence for the crucial role of the ligand LUMO in four ruthenium(II)ruthenium(III) dimers. Inorganic Chemistry, (27)7:1146--1148, 1988. [PUMA: azobipyridine bipyridine complex complex;LUMO complex;electron complex;pyridylpyrazine comproportionation;comproportionation comproportionation;pyridyltetrazine comproportionation;sym comproportionation;voltammetry density dinuclear heterocycle mixed nitrogen ruthenium valent voltammetry]

Renate Gross, and Wolfgang. Kaim. Charge-transfer and electron-transfer properties of d6 metal complexes with m-pyrazine. Mononuclear and binuclear manganese(I) compounds. Inorganic Chemistry, (25)4:498--506, 1986. [PUMA: charge complex complex;ESR complex;MO complex;cyclic complex;electron complex;redox manganese pyrazine transfer voltammetry]