Deprotonated p-phenylenediamines as noninnocent ligands. Metal-to-ligand spin transfer in the ground state and ligand-to-metal charge transfer in the lowest excited state of low-spin manganese(II) complexes. Inorganic Chemistry, (26)21:3596--3600, 1987. [PUMA: MO amide charge complex complex;ESR complex;electron complex;manganese configuration cyclopentadienylmanganese;deprotonation manganese phenylenediamine transfer]
Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: TCNE TCNQ complex complex;MO complex;electron complex;manganese cyclic delocalization manganese voltammetry]
Mixed-valent and radical states of complexes (bpy)2M(m-abpy)M'(bpy)2n+, M,M' = Ru or Os, abpy = 2,2'-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes. Inorganica Chimica Acta, (359)3:821--829, 2006. [PUMA: EPR azobispyridine bridge complex complex;electron complex;hole complex;mixed cyclic electrochem heterobinuclear;osmium homobinuclear osmium prepn redox ruthenium spectroelectrochem;radical transfer valence voltammetry]
What determines the comproportionation constant in molecule-bridged mixed-valence complexes? Evidence for the crucial role of the ligand LUMO in four ruthenium(II)ruthenium(III) dimers. Inorganic Chemistry, (27)7:1146--1148, 1988. [PUMA: azobipyridine bipyridine complex complex;LUMO complex;electron complex;pyridylpyrazine comproportionation;comproportionation comproportionation;pyridyltetrazine comproportionation;sym comproportionation;voltammetry density dinuclear heterocycle mixed nitrogen ruthenium valent voltammetry]
Charge-transfer and electron-transfer properties of d6 metal complexes with m-pyrazine. Mononuclear and binuclear manganese(I) compounds. Inorganic Chemistry, (25)4:498--506, 1986. [PUMA: charge complex complex;ESR complex;MO complex;cyclic complex;electron complex;redox manganese pyrazine transfer voltammetry]
Interaction of two equivalent electron transfer/atom transfer centers via 2,2'-bipyrimidine as bridging ligand. Inorganic Chemistry Communications, (1)8:305--308, 1998. [PUMA: atom bipyrimidine communication complex complex;electrochem complex;electron complex;electronic complex;mol complex;redox crystal cymene dinuclear electrochem mononuclear osmium structure transfer]
Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, (54)16:7936--7944, 2015. [PUMA: UV bipyridine complex complex;IR complex;electron complex;osmium crystal density diaminoanthraquinone dihydroxyanthraquinone osmium phenylazopyridine potential prepn redox spectroelectrochem spin structure]
Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt. Inorganica Chimica Acta, (251)1-2:239--248, 1996. [PUMA: TCNE UV cobalt complex;IR complex;electron complex;magnetic complex;osmium electron ground metal property state transfer transfer;electrochem transfer;ruthenium transfer;vanadium]
When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O. Inorganic Chemistry, (34)7:1924--1933, 1995. [PUMA: azodicarbonyl complex complex;electron complex;mixed complex;substituent configuration dinuclear effect electrochem ruthenium valence]
Electron transfer to complex ligands. Radical anions and organomagnesium radical complexes of 2,2'-bipyridines and 1,10-phenanthrolines. Journal of the American Chemical Society, (104)14:3833--3837, 1982. [PUMA: bipyridine complex complex;electron complex;phenanthroline ligand;ESR magnesium radical transfer]
Electron transfer to complex ligands. Radical anions and organomagnesium radical complexes of 2,2'-bipyridines and 1,10-phenanthrolines. Journal of the American Chemical Society, (104)14:3833--3837, 1982. [PUMA: bipyridine complex complex;electron complex;phenanthroline ligand;ESR magnesium radical transfer]
When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O. Inorganic Chemistry, (34)7:1924--1933, 1995. [PUMA: azodicarbonyl complex complex;electron complex;mixed complex;substituent configuration dinuclear effect electrochem ruthenium valence]
Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt. Inorganica Chimica Acta, (251)1-2:239--248, 1996. [PUMA: TCNE UV cobalt complex;IR complex;electron complex;magnetic complex;osmium electron ground metal property state transfer transfer;electrochem transfer;ruthenium transfer;vanadium]
Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry, (54)16:7936--7944, 2015. [PUMA: UV bipyridine complex complex;IR complex;electron complex;osmium crystal density diaminoanthraquinone dihydroxyanthraquinone osmium phenylazopyridine potential prepn redox spectroelectrochem spin structure]
Interaction of two equivalent electron transfer/atom transfer centers via 2,2'-bipyrimidine as bridging ligand. Inorganic Chemistry Communications, (1)8:305--308, 1998. [PUMA: atom bipyrimidine communication complex complex;electrochem complex;electron complex;electronic complex;mol complex;redox crystal cymene dinuclear electrochem mononuclear osmium structure transfer]
Charge-transfer and electron-transfer properties of d6 metal complexes with m-pyrazine. Mononuclear and binuclear manganese(I) compounds. Inorganic Chemistry, (25)4:498--506, 1986. [PUMA: charge complex complex;ESR complex;MO complex;cyclic complex;electron complex;redox manganese pyrazine transfer voltammetry]
What determines the comproportionation constant in molecule-bridged mixed-valence complexes? Evidence for the crucial role of the ligand LUMO in four ruthenium(II)ruthenium(III) dimers. Inorganic Chemistry, (27)7:1146--1148, 1988. [PUMA: azobipyridine bipyridine complex complex;LUMO complex;electron complex;pyridylpyrazine comproportionation;comproportionation comproportionation;pyridyltetrazine comproportionation;sym comproportionation;voltammetry density dinuclear heterocycle mixed nitrogen ruthenium valent voltammetry]
Mixed-valent and radical states of complexes (bpy)2M(m-abpy)M'(bpy)2n+, M,M' = Ru or Os, abpy = 2,2'-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes. Inorganica Chimica Acta, (359)3:821--829, 2006. [PUMA: EPR azobispyridine bridge complex complex;electron complex;hole complex;mixed cyclic electrochem heterobinuclear;osmium homobinuclear osmium prepn redox ruthenium spectroelectrochem;radical transfer valence voltammetry]
Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn. Inorganic Chemistry, (29)25:5046--5053, 1990. [PUMA: TCNE TCNQ complex complex;MO complex;electron complex;manganese cyclic delocalization manganese voltammetry]
Deprotonated p-phenylenediamines as noninnocent ligands. Metal-to-ligand spin transfer in the ground state and ligand-to-metal charge transfer in the lowest excited state of low-spin manganese(II) complexes. Inorganic Chemistry, (26)21:3596--3600, 1987. [PUMA: MO amide charge complex complex;ESR complex;electron complex;manganese configuration cyclopentadienylmanganese;deprotonation manganese phenylenediamine transfer]