Mixed-valent and radical states of complexes (bpy)2M(m-abpy)M'(bpy)2n+, M,M' = Ru or Os, abpy = 2,2'-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes. Inorganica Chimica Acta, (359)3:821--829, 2006. [PUMA: EPR azobispyridine bridge complex complex;electron complex;hole complex;mixed cyclic electrochem heterobinuclear;osmium homobinuclear osmium prepn redox ruthenium spectroelectrochem;radical transfer valence voltammetry]
Resolving the Two-Electron Process for the Couple (C5Me5)M(NN̂)Cl+/(C5Me5)M(NN̂) (M = Rh, Ir) into Two One-Electron Steps Using the 2,2'-Azobis(pyridine) NN̂ Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MII Intermediates. Organometallics, (22)11:2240--2244, 2003. [PUMA: ESR;rhodium UV azobispyridine complex electrochem intermediate iridium prepn radical redox rhodium spectroelectrochem]
Structural and spectroscopic evidence for marginal metal-to-ligand charge transfer in complexes Pt(abpy)Me3X, abpy = 2,2'-azobispyridine, X = Cl, Br, I. Zeitschrift fuer Anorganische und Allgemeine Chemie, (634)14:2527--2531, 2008. [PUMA: ESR azobispyridine bromo complex complex;platinum crystal electrochem halotrimethyl iodo platinum prepn prepn;mol redn structure trimethyl]
Configuration-dependent electron hopping between equivalent ligands in isomeric ruthenium(II) complexes. Journal of the Chemical Society, Faraday Transactions, (92)21:4227--4231, 1996. [PUMA: ESR azobispyridine bipyridine configurational electrochem electron hopping isomer;ESR isomer;electron isomer;ruthenium redn ruthenium]
Configuration-dependent electron hopping between equivalent ligands in isomeric ruthenium(II) complexes. Journal of the Chemical Society, Faraday Transactions, (92)21:4227--4231, 1996. [PUMA: ESR azobispyridine bipyridine configurational electrochem electron hopping isomer;ESR isomer;electron isomer;ruthenium redn ruthenium]
Structural and spectroscopic evidence for marginal metal-to-ligand charge transfer in complexes Pt(abpy)Me3X, abpy = 2,2'-azobispyridine, X = Cl, Br, I. Zeitschrift fuer Anorganische und Allgemeine Chemie, (634)14:2527--2531, 2008. [PUMA: ESR azobispyridine bromo complex complex;platinum crystal electrochem halotrimethyl iodo platinum prepn prepn;mol redn structure trimethyl]
Resolving the Two-Electron Process for the Couple (C5Me5)M(NN̂)Cl+/(C5Me5)M(NN̂) (M = Rh, Ir) into Two One-Electron Steps Using the 2,2'-Azobis(pyridine) NN̂ Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MII Intermediates. Organometallics, (22)11:2240--2244, 2003. [PUMA: ESR;rhodium UV azobispyridine complex electrochem intermediate iridium prepn radical redox rhodium spectroelectrochem]
Mixed-valent and radical states of complexes (bpy)2M(m-abpy)M'(bpy)2n+, M,M' = Ru or Os, abpy = 2,2'-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes. Inorganica Chimica Acta, (359)3:821--829, 2006. [PUMA: EPR azobispyridine bridge complex complex;electron complex;hole complex;mixed cyclic electrochem heterobinuclear;osmium homobinuclear osmium prepn redox ruthenium spectroelectrochem;radical transfer valence voltammetry]