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What a Difference Ancillary Thienyl Makes: Unexpected Additional Stabilization of the Diruthenium(III,II) but Not the Diosmium(III,II) Mixed-Valent State in Tetrazine Ligand-Bridged Complexes

B. Sarkar, W. Kaim, A. Klein, B. Schwederski, J. Fiedler, C. Duboc-Toia, and G. Lahiri. Inorganic Chemistry, 42 (20): 6172--6174 (2003)
DOI: 10.1021/ic034105p

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Verena Fiedler University of Stuttgart

Tim Janz University of Stuttgart

PD Dr. phil. Frank Janle University of Stuttgart

Isabel Janowsky-Vidovic University of Stuttgart

Hon. -Prof. Dr. Martin Jansen University of Stuttgart

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A distributed personalized news system based on mobile agents.J. Fiedler. ACM Southeast Regional Conference, page 130-135. ACM, (1998)Metal vs. Ligand Reduction in Complexes of 1,3-Dimethylalloxazine (DMA) with Copper(I), Ruthenium(II), and Tungsten(VI). Crystal Structures of (DMA)WO2Cl2 and (Bis(1-methylimidazol-2-yl)ketone)WO2Cl2F. Hornung, O. Heilmann, W. Kaim, S. Zalis, and J. Fiedler. Inorganic Chemistry, 39 (18): 4052--4058 (2000)The complex (m,h2:h2-L)[AuCl2]2, L2- = N,N'-bis(a-picolinoyl)hydrazido(2-), as obtained directly or through ring-opening reaction of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazineA. Dogan, B. Schwederski, T. Schleid, F. Lissner, J. Fiedler, and W. Kaim. Inorganic Chemistry Communications, 7 (2): 220--223 (2004)CpIr(dab) (dab = 1,4-Bis(2,6-dimethylphenyl)-1,4-diazabutadiene): A Coordinatively Unsaturated Six-p-Electron Metallaheteroaromatic Compound?S. Greulich, W. Kaim, A. Stange, H. Stoll, J. Fiedler, and S. Zalis. Inorganic Chemistry, 35 (13): 3998--4002 (1996)Bis(acetylacetonato)ruthenium complexes of noninnocent 1,2-dioxolene ligands: Qualitatively different bonding in relation to monoimino and diimino analoguesD. Das, B. Sarkar, D. Kumbhakar, T. Mondal, S. Mobin, J. Fiedler, F. Urbanos, R. Jimenez-Aparicio, W. Kaim, and G. Lahiri. Chemistry (Weinheim an der Bergstrasse, Germany), 17 (39): 11030--11040 (2011)Double cyclometalation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and propertiesB. Sarkar, T. Schurr, I. Hartenbach, T. Schleid, J. Fiedler, and W. Kaim. Journal of Organometallic Chemistry, 693 (8-9): 1703--1706 (2008)On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds [RkPt(m-L)PtRk]n, k = 2 or 4A. Klein, S. Hasenzahl, W. Kaim, and J. Fiedler. Organometallics, 17 (16): 3532--3538 (1998)Analysis of Multiple Redox Sites in Complexes [M(C5Me5)(Q)(NO)]n, M=Ru or Os, Q=o-QuinonesT. Scherer, I. Hartenbach, F. Lissner, B. Schwederski, R. Huebner, J. Fiedler, S. Zalis, B. Sarkar, and W. Kaim. Zeitschrift fuer Anorganische und Allgemeine Chemie, 647 (8): 867-875 (2021)Structure and Spectroelectrochemistry (UV/Vis, IR, EPR) of the Acceptor-Bridged Heterodinuclear Complex [(h5-C5Me5)ClRh(m-bptz)Re(CO)3Cl](PF6), bptz = 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazineT. Scheiring, J. Fiedler, and W. Kaim. Organometallics, 20 (7): 1437--1441 (2001)Singlet Diradical Complexes of Ruthenium and Osmium: Geometrical and Electronic Structures and their Unexpected Changes on OxidationS. Samanta, P. Singh, J. Fiedler, S. Zalis, W. Kaim, and S. Goswami. Inorganic Chemistry, 47 (5): 1625--1633 (2008)

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