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         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2d93a351cbf2cd7378a923d4141a353a5/huebleriac",         
         "tags" : [
            "Carbenes","Carbenes;isolation","DFT","ESR","Germanium","acyclic","cyclicAlkylamino","radical","stabilized","transient"
         ],
         
         "intraHash" : "d93a351cbf2cd7378a923d4141a353a5",
         "interHash" : "6f9a0d63bff80ebb3016d356c59494fc",
         "label" : "Isolation of Transient Acyclic Germanium(I) Radicals Stabilized by Cyclic Alkyl(amino) Carbenes",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
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         "count" : 5,
         "pub-type": "article",
         "journal": "Journal of the American Chemical Society",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Mujahuddin M. Siddiqui","Samir Kumar Sarkar","Soumen Sinhababu","Paul Niklas Ruth","Regine Herbst-Irmer","Dietmar Stalke","Munmun Ghosh","Mingxing Fu","Lili Zhao","David Casanova","Gernot Frenking","Brigitte Schwederski","Wolfgang Kaim","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Mujahuddin M.",	"last" : "Siddiqui"},
            	{"first" : "Samir Kumar",	"last" : "Sarkar"},
            	{"first" : "Soumen",	"last" : "Sinhababu"},
            	{"first" : "Paul Niklas",	"last" : "Ruth"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Munmun",	"last" : "Ghosh"},
            	{"first" : "Mingxing",	"last" : "Fu"},
            	{"first" : "Lili",	"last" : "Zhao"},
            	{"first" : "David",	"last" : "Casanova"},
            	{"first" : "Gernot",	"last" : "Frenking"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "141","number": "5","pages": "1908--1912","abstract": "Despite the notable progress in the stabilization of main group radicals by NHCs and cyclicalkyl(amino) carbenes (cAACs), no germanium radicals have been isolated so far due to synthetic challenges.  Stabilization of neutral [:EIR].bul. (E = Si, Ge) radicals is an uphill task, as these reactive transient species are highly susceptible to dimerization.  Herein, we report the synthesis of acyclic neutral germanium(I) radicals Cy-cAAC:GeN(SiMe3)Dip I (1) and Me-cAAC:GeN(SiPh3)Mes II (2) obtained by the redn. of [Ar(SiR3)NGeCl3] with KC8 in the presence of cAAC.  Compds. 1 and 2 are well characterized by single crystal X-ray structural anal., cyclic voltammetry, and EPR spectroscopy.  Furthermore, the structure and bonding of compds. 1 and 2 have been investigated by theor. methods. [on SciFinder(R)]",
         "issn" : "0002-7863",
         
         "doi" : "10.1021/jacs.8b13434",
         
         "bibtexKey": "Siddiqui.2019"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2540240c0ea3adeb060f3d6c04440165a/huebleriac",         
         "tags" : [
            "anion","azodicarboxylate","copper","phosphine","radical","review;crystal","review;phenanthrolinesemidione","review;pyridylterazine","review;review","stabilization","stabilized","structure"
         ],
         
         "intraHash" : "540240c0ea3adeb060f3d6c04440165a",
         "interHash" : "50ec6d0551633a83328f0b80ed0d9ee9",
         "label" : "Unusual stabilization of anion radicals by copper(I)",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
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         "count" : 3,
         "pub-type": "article",
         "journal": "Special Publication - Royal Society of Chemistry",
         "year": "1993", 
         "url": "", 
         
         "author": [ 
            "W. Kaim","M. Moscherosch","S. Kohlmann","J. S. Field","D. Fenske"
         ],
         "authors": [
         	
            	{"first" : "W.",	"last" : "Kaim"},
            	{"first" : "M.",	"last" : "Moscherosch"},
            	{"first" : "S.",	"last" : "Kohlmann"},
            	{"first" : "J. S.",	"last" : "Field"},
            	{"first" : "D.",	"last" : "Fenske"}
         ],
         "volume": "131","number": "Chemistry of the Copper and Zinc Triads","pages": "248--251","abstract": "A review with 10 refs. discusses the stabilization of Cu(PPh3)2+ by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine radical anion (L) and 4,7-phenanthroline-5,6-semidione (Q) as [Cu(PPh3)2]2L+ (I) and [Cu(PPh3)2]2Q+, resp., and of Cu[Ph2P(CH2)6PPh2]+ by Me3COC(O)NNC(O)OCMe3.bul. (Z) as Cu[Ph2P(CH2)6PPh2]2Z (II).  The crystal structures of I and II as BF4- salts are discussed. [on SciFinder(R)]",
         "issn" : "0260-6291",
         
         "bibtexKey": "Kaim.1993"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/22440397638c878c9486c46b18eab953d/huebleriac",         
         "tags" : [
            "alkyl","amino","carbene","chloride","chloride;cyclic","chromium","crystal","cyclic","mol","prepn","stabilized","structure"
         ],
         
         "intraHash" : "2440397638c878c9486c46b18eab953d",
         "interHash" : "d398cdbc120ff5106da8746730bdd0d6",
         "label" : "Cr(I)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
         "changeDate" : "2022-06-15 09:26:56",
         "count" : 3,
         "pub-type": "article",
         "journal": "Chemical Science",
         "year": "2015", 
         "url": "", 
         
         "author": [ 
            "Prinson P. Samuel","Roman Neufeld","Kartik Chandra Mondal","Herbert W. Roesky","Regine Herbst-Irmer","Dietmar Stalke","Serhiy Demeshko","Franc Meyer","Vallyanga Chalil Rojisha","Susmita De","Pattiyil Parameswaran","A. Claudia Stueckl","Wolfgang Kaim","Jonathan H. Christian","Jasleen K. Bindra","Naresh S. Dalal"
         ],
         "authors": [
         	
            	{"first" : "Prinson P.",	"last" : "Samuel"},
            	{"first" : "Roman",	"last" : "Neufeld"},
            	{"first" : "Kartik",	"last" : "Chandra Mondal"},
            	{"first" : "Herbert W.",	"last" : "Roesky"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Serhiy",	"last" : "Demeshko"},
            	{"first" : "Franc",	"last" : "Meyer"},
            	{"first" : "Vallyanga Chalil",	"last" : "Rojisha"},
            	{"first" : "Susmita",	"last" : "De"},
            	{"first" : "Pattiyil",	"last" : "Parameswaran"},
            	{"first" : "A. Claudia",	"last" : "Stueckl"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Jonathan H.",	"last" : "Christian"},
            	{"first" : "Jasleen K.",	"last" : "Bindra"},
            	{"first" : "Naresh S.",	"last" : "Dalal"}
         ],
         "volume": "6","number": "5","pages": "3148--3153","abstract": "Cr(I)Cl is a very unstable species.  The present work describes the stabilization of Cr(I)Cl in the low coordinate environment of cyclic alkyl(amino) carbene ligands and its synthetic application to yield an unprecedented cationic complex with a two coordinate Cr(I).  One electron redn. of (cAAC)2CrCl2 (1) with equiv. amt. of KC8 results in the formation of (cAAC)2CrCl (2), with a distorted trigonal planar configuration at the metal center.  SQUID, EPR and theor. studies reveal a Cr(I) center with S = 5/2 spin ground state for 2.  It represents the first example of a mononuclear Cr complex showing slow relaxation of magnetization under an applied magnetic field.  The chlorine atom in 2 is expected to be prone to further reactions with appropriate reagents.  This qualifies 2 as a promising precursor for the prepn. of various interesting complexes with Cr(I) in a low coordinate environment.  The first example of this metathesis reaction is obsd. when 2 is treated with Na[B(C6H3(CF3)2)4] resulting in [(cAAC)2Cr]+[B(C6H3(CF3)2)4]-, a linear cationic complex with two coordinate Cr(I) and an S = 5/2 spin ground state. [on SciFinder(R)]",
         "issn" : "2041-6520",
         
         "doi" : "10.1039/C5SC00646E",
         
         "bibtexKey": "Samuel.2015"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/28c8dd9e06f8c85cb1f3727f8d478367b/huebleriac",         
         "tags" : [
            "DFT","ESR","MS;crystal","alkylaminocarbene","compd","compd;mol","compd;optimized","geometry","monoradical","organosilicon","prepn","stabilized","structure"
         ],
         
         "intraHash" : "8c8dd9e06f8c85cb1f3727f8d478367b",
         "interHash" : "65462c069bc70f505712193262b32e14",
         "label" : "Cyclic Alkyl(amino) Carbene-Stabilized Monoradicals of Organosilicon(IV) Compounds with Small Substituents",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
         "changeDate" : "2022-06-15 09:26:56",
         "count" : 2,
         "pub-type": "article",
         "journal": "Organometallics",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Wenling Li","Subrata Kundu","Christian Kohler","Jiancheng Li","Sayan Dutta","Zhi Yang","Dietmar Stalke","Regine Herbst-Irmer","A. Claudia Stuckl","Brigitte Schwederski","Debasis Koley","Wolfgang Kaim","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Wenling",	"last" : "Li"},
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Christian",	"last" : "Kohler"},
            	{"first" : "Jiancheng",	"last" : "Li"},
            	{"first" : "Sayan",	"last" : "Dutta"},
            	{"first" : "Zhi",	"last" : "Yang"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "A. Claudia",	"last" : "Stuckl"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Debasis",	"last" : "Koley"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "38","number": "9","pages": "1939--1945","abstract": "Radicals and biradicals can easily be obtained when Si(IV) compds. are reduced and stabilized by the Lewis base cyclic(alkyl)(amino)carbene (cAAC = C(CH2)(CMe2)2N-Dipp, Dipp = 2,6-i-Pr2C6H3) featuring strong s-donor and p-acceptor properties.  To obtain the cAAC-stabilized monoradicals with halogen and alkyl substituents at the Si(IV) atoms, the Ar substituent (Ar = o-C6H4NMe2) was employed to act as a side-arm N donor ligand.  The resulting monoradicals ArSiCl2(cAAC) (4) and ArSiRCl(cAAC) (R = Me 5; Et 6) were isolated by the redn. of ArSiCl2 (1) and ArSiRCl2 (R = Me 2; Et 3) with KC8 in the presence of cAAC with a strict ratio of 1:1:1.  The three room-temp. stable radicals were kept for at least 3 mo in the solid state under dry N2 atmosphere without decompn.  All the compds. were fully characterized by liq. injection field desorption/ionization-mass spectrometry, ESR spectroscopy, UV/visible spectroscopy, elemental anal., and single-crystal x-ray crystallog. studies. [on SciFinder(R)]",
         "issn" : "0276-7333",
         
         "doi" : "10.1021/acs.organomet.9b00041",
         
         "bibtexKey": "Li.2019"

      }
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      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/274686dcffa571609a83a1a40e3482ae6/huebleriac",         
         "tags" : [
            "DFT","EPR;crystal","base","cation","electrochem","fluoroborylene","mol","optimized","prepn","radical","stabilized","structure"
         ],
         
         "intraHash" : "74686dcffa571609a83a1a40e3482ae6",
         "interHash" : "d9e54347198a7444d4de47c5a29eb705",
         "label" : "Isolation of base stabilized fluoroborylene and its radical cation",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
         "changeDate" : "2022-06-15 09:26:56",
         "count" : 3,
         "pub-type": "article",
         "journal": "Dalton Transactions",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Samir Kumar Sarkar","Mujahuddin M. Siddiqui","Subrata Kundu","Munmun Ghosh","Johannes Kretsch","Peter Stollberg","Regine Herbst-Irmer","Dietmar Stalke","A. Claudia Stueckl","Brigitte Schwederski","Wolfgang Kaim","Sagar Ghorai","Eluvathingal D. Jemmis","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Samir Kumar",	"last" : "Sarkar"},
            	{"first" : "Mujahuddin M.",	"last" : "Siddiqui"},
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Munmun",	"last" : "Ghosh"},
            	{"first" : "Johannes",	"last" : "Kretsch"},
            	{"first" : "Peter",	"last" : "Stollberg"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "A. Claudia",	"last" : "Stueckl"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Sagar",	"last" : "Ghorai"},
            	{"first" : "Eluvathingal D.",	"last" : "Jemmis"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "48","number": "24","pages": "8551--8555","abstract": "Herein, we report the synthesis and characterization of the metal free low valent fluoroborylene [(Me-cAAC)2BF] (1) stabilized by cyclic (alkyl)(amino) carbene (cAAC).  The fluoroborylene 1 is obtained by the reductive defluorination of Me-cAAC:BF3 with 2.0 equiv of KC8 in the presence of 1.0 equiv of Me-cAAC.  Due to its highly electron rich nature, 1 underwent one-electron oxidn. with 1.0 equiv of lithium tetrakis(pentafluorophenyl)borate [LiB(C6F5)4] to form the radical cation [(Me-cAAC)2BF] ̇+[B(C6F5)4]- (2).  DFT studies suggested that the lone pair of electrons is localized on the boron atom in 1, which explains its unprecedented reactivity.  Both compds. 1 and 2 were characterized by X-ray crystallog.  The radical cation 2 was studied by EPR spectroscopy. [on SciFinder(R)]",
         "issn" : "1477-9226",
         
         "doi" : "10.1039/c9dt01899a",
         
         "bibtexKey": "Sarkar.2019b"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2d91c6dcd4c3234a3d625712fe16862e3/huebleriac",         
         "tags" : [
            "cAAC","complex;mol","complex;silyl","crystal","dimer","diradical","disilane","prepn","pyrrolidinylidene","radical","stabilized","structure"
         ],
         
         "intraHash" : "d91c6dcd4c3234a3d625712fe16862e3",
         "interHash" : "33ee766750671c25f6c66667fe83c2f7",
         "label" : "Organosilicon Radicals with Si-H and Si-Me Bonds from Commodity Precursors",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
         "changeDate" : "2022-06-15 09:26:56",
         "count" : 3,
         "pub-type": "article",
         "journal": "Journal of the American Chemical Society",
         "year": "2017", 
         "url": "", 
         
         "author": [ 
            "Subrata Kundu","Prinson P. Samuel","Soumen Sinhababu","Anna V. Luebben","Birger Dittrich","Diego M. Andrada","Gernot Frenking","A. Claudia Stueckl","Brigitte Schwederski","Alexa Paretzki","Wolfgang Kaim","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Prinson P.",	"last" : "Samuel"},
            	{"first" : "Soumen",	"last" : "Sinhababu"},
            	{"first" : "Anna V.",	"last" : "Luebben"},
            	{"first" : "Birger",	"last" : "Dittrich"},
            	{"first" : "Diego M.",	"last" : "Andrada"},
            	{"first" : "Gernot",	"last" : "Frenking"},
            	{"first" : "A. Claudia",	"last" : "Stueckl"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Alexa",	"last" : "Paretzki"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "139","number": "32","pages": "11028--11031","abstract": "The cyclic alkyl(amino) carbene (cAAC) stabilized biradicals of compn. (cAAC)2SiH2 (1), (cAAC)SiMe2-SiMe2(cAAC) (2), and (cAAC)SiMeCl-SiMeCl(cAAC) (3, for 1-3, cAAC = 1-Dipp-3,3,5,5-tetramethyl-2-pyrrolidinylidene) have been isolated as mol. species.  All the compds. are stable at room temp. for more than 6 mo under inert conditions in the solid state.  All radical species were fully characterized by single-crystal X-ray structure anal. and EPR spectroscopy.  Furthermore, the structure and bonding of compds. 1-3 have been investigated by theor. methods.  Compd. 1 contains the SiH2 moiety and this is the first instance, where we have isolated 1 without an acceptor mol. [on SciFinder(R)]",
         "issn" : "0002-7863",
         
         "doi" : "10.1021/jacs.7b06610",
         
         "bibtexKey": "Kundu.2017"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/23197dd2ac817518488943d64b4b2f27a/huebleriac",         
         "tags" : [
            "aminyl","biochem","electron","metal","nitrogen","odd","prepn","radical","review;review","stabilized"
         ],
         
         "intraHash" : "3197dd2ac817518488943d64b4b2f27a",
         "interHash" : "c8805d34695a0449925b3ef7ea757dbb",
         "label" : "Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
         "changeDate" : "2022-06-15 09:26:56",
         "count" : 3,
         "pub-type": "article",
         "journal": "Science (Washington, DC, United States)",
         "year": "2005", 
         "url": "", 
         
         "author": [ 
            "Wolfgang. Kaim"
         ],
         "authors": [
         	
            	{"first" : "Wolfgang.",	"last" : "Kaim"}
         ],
         "volume": "307","number": "5707","pages": "216--217","abstract": "A review of metal-stabilized aminyl radical and their potential to be discovered in a biol. context.  Chem. properties of metal-stabilized aminyl radicals are intermediate between those metal-nteracting carbon- and oxygen-centered radicals, which are well established in biochem. [on SciFinder(R)]",
         "issn" : "0036-8075",
         
         "doi" : "10.1126/science.1107345",
         
         "bibtexKey": "Kaim.2005c"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/25bcf725af942fcb73c57dc589b080f83/huebleriac",         
         "tags" : [
            "alkylaminocarbene","biradical","cAAC","complex","complex;EPR","complex;mol","complex;silylene","crystal","cyclic","prepn","radical","silylene","spectra","stabilized","structure"
         ],
         
         "intraHash" : "5bcf725af942fcb73c57dc589b080f83",
         "interHash" : "c8ae395be3eef839864b3934f0bc15a2",
         "label" : "Synthesis of cAAC stabilized biradical of \\textquotedblMe2Si\\textquotedbl and \\textquotedblMe2SiCl\\textquotedbl monoradical from Me2SiCl2 - an important feedstock material",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
         "changeDate" : "2022-06-15 09:26:56",
         "count" : 2,
         "pub-type": "article",
         "journal": "Chemical Communications (Cambridge, United Kingdom)",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Soumen Sinhababu","Subrata Kundu","Mujahuddin M. Siddiqui","Alexander N. Paesch","Regine Herbst-Irmer","Brigitte Schwederski","Pinaki Saha","Lili Zhao","Gernot Frenking","Wolfgang Kaim","Dietmar Stalke","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Soumen",	"last" : "Sinhababu"},
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Mujahuddin M.",	"last" : "Siddiqui"},
            	{"first" : "Alexander N.",	"last" : "Paesch"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Pinaki",	"last" : "Saha"},
            	{"first" : "Lili",	"last" : "Zhao"},
            	{"first" : "Gernot",	"last" : "Frenking"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "55","number": "31","pages": "4534--4537","abstract": "The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)2Me2Si (1, cAAC = 1-Dipp-2,2,4,4-tetramethyl-2-pyrrolidinylidene), synthesized from the redn. of Me2SiCl2 using two equiv. of KC8 in the presence of two equiv of cAAC.  The redn. of Me2SiCl2 by one equiv of KC8 in the presence of one equiv of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2). [on SciFinder(R)]",
         "issn" : "1359-7345",
         
         "doi" : "10.1039/c9cc01448a",
         
         "bibtexKey": "Sinhababu.2019"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/25bcf725af942fcb73c57dc589b080f83/b_schwederski",         
         "tags" : [
            "alkylaminocarbene","biradical","cAAC","complex","complex;EPR","complex;mol","complex;silylene","crystal","cyclic","prepn","radical","silylene","spectra","stabilized","structure"
         ],
         
         "intraHash" : "5bcf725af942fcb73c57dc589b080f83",
         "interHash" : "c8ae395be3eef839864b3934f0bc15a2",
         "label" : "Synthesis of cAAC stabilized biradical of \\textquotedblMe2Si\\textquotedbl and \\textquotedblMe2SiCl\\textquotedbl monoradical from Me2SiCl2 - an important feedstock material",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2020-08-21 15:54:44",
         "changeDate" : "2020-08-21 13:55:39",
         "count" : 2,
         "pub-type": "article",
         "journal": "Chemical Communications (Cambridge, United Kingdom)",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Soumen Sinhababu","Subrata Kundu","Mujahuddin M. Siddiqui","Alexander N. Paesch","Regine Herbst-Irmer","Brigitte Schwederski","Pinaki Saha","Lili Zhao","Gernot Frenking","Wolfgang Kaim","Dietmar Stalke","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Soumen",	"last" : "Sinhababu"},
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Mujahuddin M.",	"last" : "Siddiqui"},
            	{"first" : "Alexander N.",	"last" : "Paesch"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Pinaki",	"last" : "Saha"},
            	{"first" : "Lili",	"last" : "Zhao"},
            	{"first" : "Gernot",	"last" : "Frenking"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "55","number": "31","pages": "4534--4537","abstract": "The cyclic alkyl(amino) carbene (cAAC) coordinated biradical of dimethylsilicon was isolated as (cAAC)2Me2Si (1, cAAC = 1-Dipp-2,2,4,4-tetramethyl-2-pyrrolidinylidene), synthesized from the redn. of Me2SiCl2 using two equiv. of KC8 in the presence of two equiv of cAAC.  The redn. of Me2SiCl2 by one equiv of KC8 in the presence of one equiv of cAAC resulted in the stable dimethylsiliconchloride monoradical (cAAC)Me2SiCl (2). [on SciFinder(R)]",
         "issn" : "1359-7345",
         
         "doi" : "10.1039/c9cc01448a",
         
         "bibtexKey": "Sinhababu.2019"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/23197dd2ac817518488943d64b4b2f27a/b_schwederski",         
         "tags" : [
            "aminyl","biochem","electron","metal","nitrogen","odd","prepn","radical","review;review","stabilized"
         ],
         
         "intraHash" : "3197dd2ac817518488943d64b4b2f27a",
         "interHash" : "c8805d34695a0449925b3ef7ea757dbb",
         "label" : "Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 3,
         "pub-type": "article",
         "journal": "Science (Washington, DC, United States)",
         "year": "2005", 
         "url": "", 
         
         "author": [ 
            "Wolfgang. Kaim"
         ],
         "authors": [
         	
            	{"first" : "Wolfgang.",	"last" : "Kaim"}
         ],
         "volume": "307","number": "5707","pages": "216--217","abstract": "A review of metal-stabilized aminyl radical and their potential to be discovered in a biol. context.  Chem. properties of metal-stabilized aminyl radicals are intermediate between those metal-nteracting carbon- and oxygen-centered radicals, which are well established in biochem. [on SciFinder(R)]",
         "issn" : "0036-8075",
         
         "doi" : "10.1126/science.1107345",
         
         "bibtexKey": "Kaim.2005c"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2d91c6dcd4c3234a3d625712fe16862e3/b_schwederski",         
         "tags" : [
            "cAAC","complex;mol","complex;silyl","crystal","dimer","diradical","disilane","prepn","pyrrolidinylidene","radical","stabilized","structure"
         ],
         
         "intraHash" : "d91c6dcd4c3234a3d625712fe16862e3",
         "interHash" : "33ee766750671c25f6c66667fe83c2f7",
         "label" : "Organosilicon Radicals with Si-H and Si-Me Bonds from Commodity Precursors",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 3,
         "pub-type": "article",
         "journal": "Journal of the American Chemical Society",
         "year": "2017", 
         "url": "", 
         
         "author": [ 
            "Subrata Kundu","Prinson P. Samuel","Soumen Sinhababu","Anna V. Luebben","Birger Dittrich","Diego M. Andrada","Gernot Frenking","A. Claudia Stueckl","Brigitte Schwederski","Alexa Paretzki","Wolfgang Kaim","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Prinson P.",	"last" : "Samuel"},
            	{"first" : "Soumen",	"last" : "Sinhababu"},
            	{"first" : "Anna V.",	"last" : "Luebben"},
            	{"first" : "Birger",	"last" : "Dittrich"},
            	{"first" : "Diego M.",	"last" : "Andrada"},
            	{"first" : "Gernot",	"last" : "Frenking"},
            	{"first" : "A. Claudia",	"last" : "Stueckl"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Alexa",	"last" : "Paretzki"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "139","number": "32","pages": "11028--11031","abstract": "The cyclic alkyl(amino) carbene (cAAC) stabilized biradicals of compn. (cAAC)2SiH2 (1), (cAAC)SiMe2-SiMe2(cAAC) (2), and (cAAC)SiMeCl-SiMeCl(cAAC) (3, for 1-3, cAAC = 1-Dipp-3,3,5,5-tetramethyl-2-pyrrolidinylidene) have been isolated as mol. species.  All the compds. are stable at room temp. for more than 6 mo under inert conditions in the solid state.  All radical species were fully characterized by single-crystal X-ray structure anal. and EPR spectroscopy.  Furthermore, the structure and bonding of compds. 1-3 have been investigated by theor. methods.  Compd. 1 contains the SiH2 moiety and this is the first instance, where we have isolated 1 without an acceptor mol. [on SciFinder(R)]",
         "issn" : "0002-7863",
         
         "doi" : "10.1021/jacs.7b06610",
         
         "bibtexKey": "Kundu.2017"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/274686dcffa571609a83a1a40e3482ae6/b_schwederski",         
         "tags" : [
            "DFT","EPR;crystal","base","cation","electrochem","fluoroborylene","mol","optimized","prepn","radical","stabilized","structure"
         ],
         
         "intraHash" : "74686dcffa571609a83a1a40e3482ae6",
         "interHash" : "d9e54347198a7444d4de47c5a29eb705",
         "label" : "Isolation of base stabilized fluoroborylene and its radical cation",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 3,
         "pub-type": "article",
         "journal": "Dalton Transactions",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Samir Kumar Sarkar","Mujahuddin M. Siddiqui","Subrata Kundu","Munmun Ghosh","Johannes Kretsch","Peter Stollberg","Regine Herbst-Irmer","Dietmar Stalke","A. Claudia Stueckl","Brigitte Schwederski","Wolfgang Kaim","Sagar Ghorai","Eluvathingal D. Jemmis","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Samir Kumar",	"last" : "Sarkar"},
            	{"first" : "Mujahuddin M.",	"last" : "Siddiqui"},
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Munmun",	"last" : "Ghosh"},
            	{"first" : "Johannes",	"last" : "Kretsch"},
            	{"first" : "Peter",	"last" : "Stollberg"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "A. Claudia",	"last" : "Stueckl"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Sagar",	"last" : "Ghorai"},
            	{"first" : "Eluvathingal D.",	"last" : "Jemmis"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "48","number": "24","pages": "8551--8555","abstract": "Herein, we report the synthesis and characterization of the metal free low valent fluoroborylene [(Me-cAAC)2BF] (1) stabilized by cyclic (alkyl)(amino) carbene (cAAC).  The fluoroborylene 1 is obtained by the reductive defluorination of Me-cAAC:BF3 with 2.0 equiv of KC8 in the presence of 1.0 equiv of Me-cAAC.  Due to its highly electron rich nature, 1 underwent one-electron oxidn. with 1.0 equiv of lithium tetrakis(pentafluorophenyl)borate [LiB(C6F5)4] to form the radical cation [(Me-cAAC)2BF] ̇+[B(C6F5)4]- (2).  DFT studies suggested that the lone pair of electrons is localized on the boron atom in 1, which explains its unprecedented reactivity.  Both compds. 1 and 2 were characterized by X-ray crystallog.  The radical cation 2 was studied by EPR spectroscopy. [on SciFinder(R)]",
         "issn" : "1477-9226",
         
         "doi" : "10.1039/c9dt01899a",
         
         "bibtexKey": "Sarkar.2019b"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/28c8dd9e06f8c85cb1f3727f8d478367b/b_schwederski",         
         "tags" : [
            "DFT","ESR","MS;crystal","alkylaminocarbene","compd","compd;mol","compd;optimized","geometry","monoradical","organosilicon","prepn","stabilized","structure"
         ],
         
         "intraHash" : "8c8dd9e06f8c85cb1f3727f8d478367b",
         "interHash" : "65462c069bc70f505712193262b32e14",
         "label" : "Cyclic Alkyl(amino) Carbene-Stabilized Monoradicals of Organosilicon(IV) Compounds with Small Substituents",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 2,
         "pub-type": "article",
         "journal": "Organometallics",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Wenling Li","Subrata Kundu","Christian Kohler","Jiancheng Li","Sayan Dutta","Zhi Yang","Dietmar Stalke","Regine Herbst-Irmer","A. Claudia Stuckl","Brigitte Schwederski","Debasis Koley","Wolfgang Kaim","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Wenling",	"last" : "Li"},
            	{"first" : "Subrata",	"last" : "Kundu"},
            	{"first" : "Christian",	"last" : "Kohler"},
            	{"first" : "Jiancheng",	"last" : "Li"},
            	{"first" : "Sayan",	"last" : "Dutta"},
            	{"first" : "Zhi",	"last" : "Yang"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "A. Claudia",	"last" : "Stuckl"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Debasis",	"last" : "Koley"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "38","number": "9","pages": "1939--1945","abstract": "Radicals and biradicals can easily be obtained when Si(IV) compds. are reduced and stabilized by the Lewis base cyclic(alkyl)(amino)carbene (cAAC = C(CH2)(CMe2)2N-Dipp, Dipp = 2,6-i-Pr2C6H3) featuring strong s-donor and p-acceptor properties.  To obtain the cAAC-stabilized monoradicals with halogen and alkyl substituents at the Si(IV) atoms, the Ar substituent (Ar = o-C6H4NMe2) was employed to act as a side-arm N donor ligand.  The resulting monoradicals ArSiCl2(cAAC) (4) and ArSiRCl(cAAC) (R = Me 5; Et 6) were isolated by the redn. of ArSiCl2 (1) and ArSiRCl2 (R = Me 2; Et 3) with KC8 in the presence of cAAC with a strict ratio of 1:1:1.  The three room-temp. stable radicals were kept for at least 3 mo in the solid state under dry N2 atmosphere without decompn.  All the compds. were fully characterized by liq. injection field desorption/ionization-mass spectrometry, ESR spectroscopy, UV/visible spectroscopy, elemental anal., and single-crystal x-ray crystallog. studies. [on SciFinder(R)]",
         "issn" : "0276-7333",
         
         "doi" : "10.1021/acs.organomet.9b00041",
         
         "bibtexKey": "Li.2019"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/22440397638c878c9486c46b18eab953d/b_schwederski",         
         "tags" : [
            "alkyl","amino","carbene","chloride","chloride;cyclic","chromium","crystal","cyclic","mol","prepn","stabilized","structure"
         ],
         
         "intraHash" : "2440397638c878c9486c46b18eab953d",
         "interHash" : "d398cdbc120ff5106da8746730bdd0d6",
         "label" : "Cr(I)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 3,
         "pub-type": "article",
         "journal": "Chemical Science",
         "year": "2015", 
         "url": "", 
         
         "author": [ 
            "Prinson P. Samuel","Roman Neufeld","Kartik Chandra Mondal","Herbert W. Roesky","Regine Herbst-Irmer","Dietmar Stalke","Serhiy Demeshko","Franc Meyer","Vallyanga Chalil Rojisha","Susmita De","Pattiyil Parameswaran","A. Claudia Stueckl","Wolfgang Kaim","Jonathan H. Christian","Jasleen K. Bindra","Naresh S. Dalal"
         ],
         "authors": [
         	
            	{"first" : "Prinson P.",	"last" : "Samuel"},
            	{"first" : "Roman",	"last" : "Neufeld"},
            	{"first" : "Kartik",	"last" : "Chandra Mondal"},
            	{"first" : "Herbert W.",	"last" : "Roesky"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Serhiy",	"last" : "Demeshko"},
            	{"first" : "Franc",	"last" : "Meyer"},
            	{"first" : "Vallyanga Chalil",	"last" : "Rojisha"},
            	{"first" : "Susmita",	"last" : "De"},
            	{"first" : "Pattiyil",	"last" : "Parameswaran"},
            	{"first" : "A. Claudia",	"last" : "Stueckl"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Jonathan H.",	"last" : "Christian"},
            	{"first" : "Jasleen K.",	"last" : "Bindra"},
            	{"first" : "Naresh S.",	"last" : "Dalal"}
         ],
         "volume": "6","number": "5","pages": "3148--3153","abstract": "Cr(I)Cl is a very unstable species.  The present work describes the stabilization of Cr(I)Cl in the low coordinate environment of cyclic alkyl(amino) carbene ligands and its synthetic application to yield an unprecedented cationic complex with a two coordinate Cr(I).  One electron redn. of (cAAC)2CrCl2 (1) with equiv. amt. of KC8 results in the formation of (cAAC)2CrCl (2), with a distorted trigonal planar configuration at the metal center.  SQUID, EPR and theor. studies reveal a Cr(I) center with S = 5/2 spin ground state for 2.  It represents the first example of a mononuclear Cr complex showing slow relaxation of magnetization under an applied magnetic field.  The chlorine atom in 2 is expected to be prone to further reactions with appropriate reagents.  This qualifies 2 as a promising precursor for the prepn. of various interesting complexes with Cr(I) in a low coordinate environment.  The first example of this metathesis reaction is obsd. when 2 is treated with Na[B(C6H3(CF3)2)4] resulting in [(cAAC)2Cr]+[B(C6H3(CF3)2)4]-, a linear cationic complex with two coordinate Cr(I) and an S = 5/2 spin ground state. [on SciFinder(R)]",
         "issn" : "2041-6520",
         
         "doi" : "10.1039/C5SC00646E",
         
         "bibtexKey": "Samuel.2015"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2540240c0ea3adeb060f3d6c04440165a/b_schwederski",         
         "tags" : [
            "anion","azodicarboxylate","copper","phosphine","radical","review;crystal","review;review","stabilization","stabilized","structure","review;phenanthrolinesemidione","review;pyridylterazine"
         ],
         
         "intraHash" : "540240c0ea3adeb060f3d6c04440165a",
         "interHash" : "50ec6d0551633a83328f0b80ed0d9ee9",
         "label" : "Unusual stabilization of anion radicals by copper(I)",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 3,
         "pub-type": "article",
         "journal": "Special Publication - Royal Society of Chemistry",
         "year": "1993", 
         "url": "", 
         
         "author": [ 
            "W. Kaim","M. Moscherosch","S. Kohlmann","J. S. Field","D. Fenske"
         ],
         "authors": [
         	
            	{"first" : "W.",	"last" : "Kaim"},
            	{"first" : "M.",	"last" : "Moscherosch"},
            	{"first" : "S.",	"last" : "Kohlmann"},
            	{"first" : "J. S.",	"last" : "Field"},
            	{"first" : "D.",	"last" : "Fenske"}
         ],
         "volume": "131","number": "Chemistry of the Copper and Zinc Triads","pages": "248--251","abstract": "A review with 10 refs. discusses the stabilization of Cu(PPh3)2+ by 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine radical anion (L) and 4,7-phenanthroline-5,6-semidione (Q) as [Cu(PPh3)2]2L+ (I) and [Cu(PPh3)2]2Q+, resp., and of Cu[Ph2P(CH2)6PPh2]+ by Me3COC(O)NNC(O)OCMe3.bul. (Z) as Cu[Ph2P(CH2)6PPh2]2Z (II).  The crystal structures of I and II as BF4- salts are discussed. [on SciFinder(R)]",
         "issn" : "0260-6291",
         
         "bibtexKey": "Kaim.1993"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2d93a351cbf2cd7378a923d4141a353a5/b_schwederski",         
         "tags" : [
            "Carbenes","Carbenes;isolation","DFT","ESR","Germanium","acyclic","cyclicAlkylamino","radical","stabilized","transient"
         ],
         
         "intraHash" : "d93a351cbf2cd7378a923d4141a353a5",
         "interHash" : "6f9a0d63bff80ebb3016d356c59494fc",
         "label" : "Isolation of Transient Acyclic Germanium(I) Radicals Stabilized by Cyclic Alkyl(amino) Carbenes",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 5,
         "pub-type": "article",
         "journal": "Journal of the American Chemical Society",
         "year": "2019", 
         "url": "", 
         
         "author": [ 
            "Mujahuddin M. Siddiqui","Samir Kumar Sarkar","Soumen Sinhababu","Paul Niklas Ruth","Regine Herbst-Irmer","Dietmar Stalke","Munmun Ghosh","Mingxing Fu","Lili Zhao","David Casanova","Gernot Frenking","Brigitte Schwederski","Wolfgang Kaim","Herbert W. Roesky"
         ],
         "authors": [
         	
            	{"first" : "Mujahuddin M.",	"last" : "Siddiqui"},
            	{"first" : "Samir Kumar",	"last" : "Sarkar"},
            	{"first" : "Soumen",	"last" : "Sinhababu"},
            	{"first" : "Paul Niklas",	"last" : "Ruth"},
            	{"first" : "Regine",	"last" : "Herbst-Irmer"},
            	{"first" : "Dietmar",	"last" : "Stalke"},
            	{"first" : "Munmun",	"last" : "Ghosh"},
            	{"first" : "Mingxing",	"last" : "Fu"},
            	{"first" : "Lili",	"last" : "Zhao"},
            	{"first" : "David",	"last" : "Casanova"},
            	{"first" : "Gernot",	"last" : "Frenking"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Herbert W.",	"last" : "Roesky"}
         ],
         "volume": "141","number": "5","pages": "1908--1912","abstract": "Despite the notable progress in the stabilization of main group radicals by NHCs and cyclicalkyl(amino) carbenes (cAACs), no germanium radicals have been isolated so far due to synthetic challenges.  Stabilization of neutral [:EIR].bul. (E = Si, Ge) radicals is an uphill task, as these reactive transient species are highly susceptible to dimerization.  Herein, we report the synthesis of acyclic neutral germanium(I) radicals Cy-cAAC:GeN(SiMe3)Dip I (1) and Me-cAAC:GeN(SiPh3)Mes II (2) obtained by the redn. of [Ar(SiR3)NGeCl3] with KC8 in the presence of cAAC.  Compds. 1 and 2 are well characterized by single crystal X-ray structural anal., cyclic voltammetry, and EPR spectroscopy.  Furthermore, the structure and bonding of compds. 1 and 2 have been investigated by theor. methods. [on SciFinder(R)]",
         "issn" : "0002-7863",
         
         "doi" : "10.1021/jacs.8b13434",
         
         "bibtexKey": "Siddiqui.2019"

      }
,
      {
         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/23197dd2ac817518488943d64b4b2f27a/galaktoze",         
         "tags" : [
            "aminyl","biochem","electron","metal","nitrogen","odd","prepn","radical","review;review","stabilized"
         ],
         
         "intraHash" : "3197dd2ac817518488943d64b4b2f27a",
         "interHash" : "c8805d34695a0449925b3ef7ea757dbb",
         "label" : "Chemistry: Odd electron on nitrogen: A metal-stabilized aminyl radical",
         "user" : "galaktoze",
         "description" : "",
         "date" : "2018-08-09 10:59:25",
         "changeDate" : "2018-08-09 13:02:07",
         "count" : 3,
         "pub-type": "article",
         "journal": "Science (Washington, DC, United States)",
         "year": "2005", 
         "url": "", 
         
         "author": [ 
            "Wolfgang. Kaim"
         ],
         "authors": [
         	
            	{"first" : "Wolfgang.",	"last" : "Kaim"}
         ],
         "volume": "307","number": "5707","pages": "216--217","abstract": "A review of metal-stabilized aminyl radical and their potential to be discovered in a biol. context.  Chem. properties of metal-stabilized aminyl radicals are intermediate between those metal-nteracting carbon- and oxygen-centered radicals, which are well established in biochem. [on SciFinder(R)]",
         "issn" : "0036-8075",
         
         "doi" : "10.1126/science.1107345",
         
         "bibtexKey": "Kaim.2005c"

      }
	  
   ]
}