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         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/225a31d4324246e10d958f5628432afa2/huebleriac",         
         "tags" : [
            "aminoethane","aminoethaneselenolate","complex","complex;electrochem","complex;fluxionality","complex;palladium","crystal","decompn","oxidn","palladium","phosphine","prepn;selenolate","prepn;thermal","structure"
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         "intraHash" : "25a31d4324246e10d958f5628432afa2",
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         "label" : "2-(Dimethylamino)ethaneselenolates of palladium(II): Synthesis, structure, spectroscopy and transformation into palladium selenide",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
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         "pub-type": "article",
         "journal": "Journal of the Chemical Society, Dalton Transactions",
         "year": "2001", 
         "url": "", 
         
         "author": [ 
            "Sandip Dey","Vimal K. Jain","Satyajeet Chaudhury","Axel Knoedler","Falk Lissner","Wolfgang. Kaim"
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         "authors": [
         	
            	{"first" : "Sandip",	"last" : "Dey"},
            	{"first" : "Vimal K.",	"last" : "Jain"},
            	{"first" : "Satyajeet",	"last" : "Chaudhury"},
            	{"first" : "Axel",	"last" : "Knoedler"},
            	{"first" : "Falk",	"last" : "Lissner"},
            	{"first" : "Wolfgang.",	"last" : "Kaim"}
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         "number": "5","pages": "723--728","abstract": "Bis[2-(dimethylamino)ethyl] diselenide was prepd. by the reaction of Na2Se2 with ClCH2CH2NMe2.  2-(Dimethylamino)ethaneselenolate complexes of Pd(II) [PdCl(SeCH2CH2NMe2)]3 1, [PdCl(SeCH2CH2NMe2)(PR3)] 2, [Pd2Cl3(SeCH2CH2NMe2)(PR3)2] 3 and [Pd(SeCH2CH2NMe2)2(PPh3)2] 4 were synthesized and characterized by elemental anal., IR and NMR (1H, 31P, 77Se) spectroscopy.  The structures of orange 1 and of violet (lmax = 514 nm) 2 (PR3 = PPh3) were established by single crystal x-ray diffraction analyses.  The trimer 1 contains a six-membered Pd3Se3 ring in twist conformation.  The thermal behavior of three complexes, yielding Pd17Se15 was studied. [on SciFinder(R)]",
         "issn" : "1472-7773",
         
         "doi" : "10.1039/b008310k",
         
         "bibtexKey": "Dey.2001"

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         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2acb9d483a3a86d4d11a7fbdf85a87b42/huebleriac",         
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         "intraHash" : "acb9d483a3a86d4d11a7fbdf85a87b42",
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         "label" : "Compounds of silicon and homologues, 134. Supersilyl compounds of boron and homologues, 10. Tri(supersilyl)dialanyl (tBu3Si)3Al2· and tetra(supersilyl)cyclotrialanyl (tBu3Si)4Al3· - new stable radicals of a group 13 element from thermolysis of (tBu3Si)4Al2",
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         "journal": "European Journal of Inorganic Chemistry",
         "year": "2000", 
         "url": "", 
         
         "author": [ 
            "Nils Wiberg","Thomas Blank","Wolfgang Kaim","Brigitte Schwederski","Gerald. Linti"
         ],
         "authors": [
         	
            	{"first" : "Nils",	"last" : "Wiberg"},
            	{"first" : "Thomas",	"last" : "Blank"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Gerald.",	"last" : "Linti"}
         ],
         "number": "7","pages": "1475--1481","abstract": "The thermolysis of tetra(supersilyl)dialane R2Al-AlR2 (R = SitBu3 = Supersilyl) in heptane or cyclohexane at 50° leads under Al-Al dissocn. reversibly to monoalanyl radicals [R2Al].bul., which could be trapped by hydrogen or iodine (formation of R2AlH, R2AlI).  Simultaneously, SiAl dissocn. and elimination of supersilyl radicals tBu3Si.bul. leads irreversibly and slowly to radicals [R2Al-AlR].bul., the existence of which could be established by ESR spectroscopy.  The structure was clarified by ab initio calcns. (nearly planar Si2Al-AlSi and linear Al-Al-Si skeleton; short Al-Al distance).  By thermolyzing R2Al-AlR2 at 100°, the radical [R4Al3].bul. (ESR spectroscopically detected) and the tetrahedro-tetraalane R4Al4 (NMR spectroscopically seen) are formed via radicals [R3Al2].bul.; the supersilyl radicals tBu3Si.bul., formed at the same time, are stabilized by dimerization to superdisilane R-R and by taking up hydrogen, giving supersilane R-H.  According to x-ray structure anal., the Al atoms in [R4Al3].bul. are located at the corners of a triangle; one Al atom is connected with two groups R, the remaining two Al atoms each bind one substituent R in different ways. [on SciFinder(R)]",
         "issn" : "1434-1948",
         
         "doi" : "10.1002/1099-0682(200007)2000:7\\textless1475::AID-EJIC1475\\textgreater3.0.CO;2-N",
         
         "bibtexKey": "Wiberg.2000"

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         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2f81158b3b5a4f63f3f2f794ae83d052a/huebleriac",         
         "tags" : [
            "crystal","decompn","prepn","thermal","zinc","aminoethylselenolate","aminoethylselenolato","complex;selenide","precursor;zinc","structure"
         ],
         
         "intraHash" : "f81158b3b5a4f63f3f2f794ae83d052a",
         "interHash" : "299f7a5e3922fbc2bc4972e93da5c6da",
         "label" : "Synthesis and structure of bis(2-N,N-dimethylaminoethylselenolato)zinc and its transformation to ZnSe",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
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         "count" : 3,
         "pub-type": "article",
         "journal": "Polyhedron",
         "year": "2003", 
         "url": "", 
         
         "author": [ 
            "Sandip Dey","Vimal K. Jain","Satyajeet Chaudhury","Axel Knoedler","Wolfgang. Kaim"
         ],
         "authors": [
         	
            	{"first" : "Sandip",	"last" : "Dey"},
            	{"first" : "Vimal K.",	"last" : "Jain"},
            	{"first" : "Satyajeet",	"last" : "Chaudhury"},
            	{"first" : "Axel",	"last" : "Knoedler"},
            	{"first" : "Wolfgang.",	"last" : "Kaim"}
         ],
         "volume": "22","number": "4","pages": "489--491","abstract": "The crystal structure of the air-stable compd. [Zn(SeCH2CH2NMe2)2] (1), which was prepd. from Zn(OAc)2·2H2O and 2 equiv of NaSeCH2CH2NMe2 shows that the complex consists of monomeric mols. with a characteristically distorted tetrahedral zinc atom coordinated to two selenium and two nitrogen atoms.  On thermolysis 1 yields ZnSe which was characterized by XRD. [on SciFinder(R)]",
         "issn" : "0277-5387",
         
         "doi" : "10.1016/S0277-5387(02)01379-7",
         
         "bibtexKey": "Dey.2003"

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         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2f9e76992879fa1967eaf7bb5713a3c4b/huebleriac",         
         "tags" : [
            "aminopropyl","aminopropylchalcogenolate","aminopropylselenolate;dichalcogenide","aminopropylthiolate","crystal","decompn","isomerism;platinum","isomerism;thermal","multiple","palladium","platinum","platinum;palladium","prepn","regioisomer","structure","thiolation"
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         "label" : "Structural variety and multiple isomerism in 1-(dimethylamino)propyl-2-chalcogenolate and 2-(dimethylamino)propyl-1-chalcogenolate complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures",
         "user" : "huebleriac",
         "description" : "",
         "date" : "2022-06-15 11:26:56",
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         "count" : 3,
         "pub-type": "article",
         "journal": "European Journal of Inorganic Chemistry",
         "year": "2004", 
         "url": "", 
         
         "author": [ 
            "Sandip Dey","Liladhar B. Kumbhare","Vimal K. Jain","Thilo Schurr","Wolfgang Kaim","Axel Klein","Ferdinand. Belaj"
         ],
         "authors": [
         	
            	{"first" : "Sandip",	"last" : "Dey"},
            	{"first" : "Liladhar B.",	"last" : "Kumbhare"},
            	{"first" : "Vimal K.",	"last" : "Jain"},
            	{"first" : "Thilo",	"last" : "Schurr"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Axel",	"last" : "Klein"},
            	{"first" : "Ferdinand.",	"last" : "Belaj"}
         ],
         "number": "22","pages": "4510--4520","abstract": "Isomeric dichalcogenides [Me2NCH(Me)CH2E]2 [(N$\\cap$E**)2] and [Me2NCH2CH(Me)E]2 [(N$\\cap$E*)2] (E = S, Se, Te) were obtained by the reactions of NaSH or M'2E2 (M' = Na or K) with Me2NCH2CHMeCl.  The former reaction affords mainly (N$\\cap$E**)2 (E = S) while from the latter mixts. of (N$\\cap$E**)2 and (N$\\cap$E*)2 [referred to as (N$\\cap$E)2, E = S, Se, Te] were isolated, the ratios in the mixts. depending on the chalcogen.  Reactions of (N$\\cap$E)Na with [M2Cl2(m-Cl)2(PR3)2] gave [MCl(N$\\cap$E)(PR3)] (M = Pd or Pt).  These chiral, mixed-ligand complexes were characterized by elemental anal., IR, UV/visible and NMR (1H, 13C, 31P, 77Se, 125Te, 195Pt) spectroscopy, and, in part, by x-ray structure anal.  The complexes display a typical pattern of mutually trans-oriented neutral (P and N) and anionic (Cl and E) donor atoms in an approx. square-planar environment.  In contrast to the Pt(II) analogs, the x-ray structures of [PdCl(N$\\cap$E)(PMePh2)] (E = S or Se) revealed both a conformational isomerism of the five-membered chelate ring and, for Se, the co-crystn. of complexes with both the N$\\cap$E* and N$\\cap$E** isomeric ligands.  The thermal behavior of some complexes was studied. [on SciFinder(R)]",
         "issn" : "1434-1948",
         
         "doi" : "10.1002/ejic.200400524",
         
         "bibtexKey": "Dey.2004"

      }
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         "label" : "Structural variety and multiple isomerism in 1-(dimethylamino)propyl-2-chalcogenolate and 2-(dimethylamino)propyl-1-chalcogenolate complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
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         "pub-type": "article",
         "journal": "European Journal of Inorganic Chemistry",
         "year": "2004", 
         "url": "", 
         
         "author": [ 
            "Sandip Dey","Liladhar B. Kumbhare","Vimal K. Jain","Thilo Schurr","Wolfgang Kaim","Axel Klein","Ferdinand. Belaj"
         ],
         "authors": [
         	
            	{"first" : "Sandip",	"last" : "Dey"},
            	{"first" : "Liladhar B.",	"last" : "Kumbhare"},
            	{"first" : "Vimal K.",	"last" : "Jain"},
            	{"first" : "Thilo",	"last" : "Schurr"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Axel",	"last" : "Klein"},
            	{"first" : "Ferdinand.",	"last" : "Belaj"}
         ],
         "number": "22","pages": "4510--4520","abstract": "Isomeric dichalcogenides [Me2NCH(Me)CH2E]2 [(N$\\cap$E**)2] and [Me2NCH2CH(Me)E]2 [(N$\\cap$E*)2] (E = S, Se, Te) were obtained by the reactions of NaSH or M'2E2 (M' = Na or K) with Me2NCH2CHMeCl.  The former reaction affords mainly (N$\\cap$E**)2 (E = S) while from the latter mixts. of (N$\\cap$E**)2 and (N$\\cap$E*)2 [referred to as (N$\\cap$E)2, E = S, Se, Te] were isolated, the ratios in the mixts. depending on the chalcogen.  Reactions of (N$\\cap$E)Na with [M2Cl2(m-Cl)2(PR3)2] gave [MCl(N$\\cap$E)(PR3)] (M = Pd or Pt).  These chiral, mixed-ligand complexes were characterized by elemental anal., IR, UV/visible and NMR (1H, 13C, 31P, 77Se, 125Te, 195Pt) spectroscopy, and, in part, by x-ray structure anal.  The complexes display a typical pattern of mutually trans-oriented neutral (P and N) and anionic (Cl and E) donor atoms in an approx. square-planar environment.  In contrast to the Pt(II) analogs, the x-ray structures of [PdCl(N$\\cap$E)(PMePh2)] (E = S or Se) revealed both a conformational isomerism of the five-membered chelate ring and, for Se, the co-crystn. of complexes with both the N$\\cap$E* and N$\\cap$E** isomeric ligands.  The thermal behavior of some complexes was studied. [on SciFinder(R)]",
         "issn" : "1434-1948",
         
         "doi" : "10.1002/ejic.200400524",
         
         "bibtexKey": "Dey.2004"

      }
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         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2f81158b3b5a4f63f3f2f794ae83d052a/b_schwederski",         
         "tags" : [
            "prepn","zinc","aminoethylselenolate","aminoethylselenolato","complex;selenide","crystal","decompn","precursor;zinc","structure","thermal"
         ],
         
         "intraHash" : "f81158b3b5a4f63f3f2f794ae83d052a",
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         "label" : "Synthesis and structure of bis(2-N,N-dimethylaminoethylselenolato)zinc and its transformation to ZnSe",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
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         "count" : 3,
         "pub-type": "article",
         "journal": "Polyhedron",
         "year": "2003", 
         "url": "", 
         
         "author": [ 
            "Sandip Dey","Vimal K. Jain","Satyajeet Chaudhury","Axel Knoedler","Wolfgang. Kaim"
         ],
         "authors": [
         	
            	{"first" : "Sandip",	"last" : "Dey"},
            	{"first" : "Vimal K.",	"last" : "Jain"},
            	{"first" : "Satyajeet",	"last" : "Chaudhury"},
            	{"first" : "Axel",	"last" : "Knoedler"},
            	{"first" : "Wolfgang.",	"last" : "Kaim"}
         ],
         "volume": "22","number": "4","pages": "489--491","abstract": "The crystal structure of the air-stable compd. [Zn(SeCH2CH2NMe2)2] (1), which was prepd. from Zn(OAc)2·2H2O and 2 equiv of NaSeCH2CH2NMe2 shows that the complex consists of monomeric mols. with a characteristically distorted tetrahedral zinc atom coordinated to two selenium and two nitrogen atoms.  On thermolysis 1 yields ZnSe which was characterized by XRD. [on SciFinder(R)]",
         "issn" : "0277-5387",
         
         "doi" : "10.1016/S0277-5387(02)01379-7",
         
         "bibtexKey": "Dey.2003"

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         "label" : "Compounds of silicon and homologues, 134. Supersilyl compounds of boron and homologues, 10. Tri(supersilyl)dialanyl (tBu3Si)3Al2· and tetra(supersilyl)cyclotrialanyl (tBu3Si)4Al3· - new stable radicals of a group 13 element from thermolysis of (tBu3Si)4Al2",
         "user" : "b_schwederski",
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         "date" : "2019-07-15 13:41:23",
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         "author": [ 
            "Nils Wiberg","Thomas Blank","Wolfgang Kaim","Brigitte Schwederski","Gerald. Linti"
         ],
         "authors": [
         	
            	{"first" : "Nils",	"last" : "Wiberg"},
            	{"first" : "Thomas",	"last" : "Blank"},
            	{"first" : "Wolfgang",	"last" : "Kaim"},
            	{"first" : "Brigitte",	"last" : "Schwederski"},
            	{"first" : "Gerald.",	"last" : "Linti"}
         ],
         "number": "7","pages": "1475--1481","abstract": "The thermolysis of tetra(supersilyl)dialane R2Al-AlR2 (R = SitBu3 = Supersilyl) in heptane or cyclohexane at 50° leads under Al-Al dissocn. reversibly to monoalanyl radicals [R2Al].bul., which could be trapped by hydrogen or iodine (formation of R2AlH, R2AlI).  Simultaneously, SiAl dissocn. and elimination of supersilyl radicals tBu3Si.bul. leads irreversibly and slowly to radicals [R2Al-AlR].bul., the existence of which could be established by ESR spectroscopy.  The structure was clarified by ab initio calcns. (nearly planar Si2Al-AlSi and linear Al-Al-Si skeleton; short Al-Al distance).  By thermolyzing R2Al-AlR2 at 100°, the radical [R4Al3].bul. (ESR spectroscopically detected) and the tetrahedro-tetraalane R4Al4 (NMR spectroscopically seen) are formed via radicals [R3Al2].bul.; the supersilyl radicals tBu3Si.bul., formed at the same time, are stabilized by dimerization to superdisilane R-R and by taking up hydrogen, giving supersilane R-H.  According to x-ray structure anal., the Al atoms in [R4Al3].bul. are located at the corners of a triangle; one Al atom is connected with two groups R, the remaining two Al atoms each bind one substituent R in different ways. [on SciFinder(R)]",
         "issn" : "1434-1948",
         
         "doi" : "10.1002/1099-0682(200007)2000:7\\textless1475::AID-EJIC1475\\textgreater3.0.CO;2-N",
         
         "bibtexKey": "Wiberg.2000"

      }
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         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/225a31d4324246e10d958f5628432afa2/b_schwederski",         
         "tags" : [
            "aminoethane","aminoethaneselenolate","complex","complex;electrochem","complex;fluxionality","complex;palladium","crystal","decompn","oxidn","palladium","phosphine","prepn;selenolate","prepn;thermal","structure"
         ],
         
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         "interHash" : "c7cdd8b284b997e507387fbce587dad8",
         "label" : "2-(Dimethylamino)ethaneselenolates of palladium(II): Synthesis, structure, spectroscopy and transformation into palladium selenide",
         "user" : "b_schwederski",
         "description" : "",
         "date" : "2019-07-15 13:41:23",
         "changeDate" : "2019-07-15 11:42:10",
         "count" : 3,
         "pub-type": "article",
         "journal": "Journal of the Chemical Society, Dalton Transactions",
         "year": "2001", 
         "url": "", 
         
         "author": [ 
            "Sandip Dey","Vimal K. Jain","Satyajeet Chaudhury","Axel Knoedler","Falk Lissner","Wolfgang. Kaim"
         ],
         "authors": [
         	
            	{"first" : "Sandip",	"last" : "Dey"},
            	{"first" : "Vimal K.",	"last" : "Jain"},
            	{"first" : "Satyajeet",	"last" : "Chaudhury"},
            	{"first" : "Axel",	"last" : "Knoedler"},
            	{"first" : "Falk",	"last" : "Lissner"},
            	{"first" : "Wolfgang.",	"last" : "Kaim"}
         ],
         "number": "5","pages": "723--728","abstract": "Bis[2-(dimethylamino)ethyl] diselenide was prepd. by the reaction of Na2Se2 with ClCH2CH2NMe2.  2-(Dimethylamino)ethaneselenolate complexes of Pd(II) [PdCl(SeCH2CH2NMe2)]3 1, [PdCl(SeCH2CH2NMe2)(PR3)] 2, [Pd2Cl3(SeCH2CH2NMe2)(PR3)2] 3 and [Pd(SeCH2CH2NMe2)2(PPh3)2] 4 were synthesized and characterized by elemental anal., IR and NMR (1H, 31P, 77Se) spectroscopy.  The structures of orange 1 and of violet (lmax = 514 nm) 2 (PR3 = PPh3) were established by single crystal x-ray diffraction analyses.  The trimer 1 contains a six-membered Pd3Se3 ring in twist conformation.  The thermal behavior of three complexes, yielding Pd17Se15 was studied. [on SciFinder(R)]",
         "issn" : "1472-7773",
         
         "doi" : "10.1039/b008310k",
         
         "bibtexKey": "Dey.2001"

      }
	  
   ]
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