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         "volume": "25","number": "13","pages": "2577--2582","abstract": "The ligand bis(1-methyl-2-imidazolyl) ketone (bik) was studied by DFT with respect to the energy min. conformation in the neutral and the anion radical state.  The hitherto unknown crystal structure of bik is reported.  X-ray diffraction studies of cationic dichlorogold(III) complexes with bik and the related bis(1-methyl-2-imidazolyl)methoxymethane and bis(1-methyl-2-imidazolyl)hydroxymethane ligands showed the DFT-supported N,N'-coordination to form six-membered chelate rings.  The LUMO of [(bik)AuCl2]+ was calcd. as Au-Cl centered in agreement with electrochem. and EPR results. [on SciFinder(R)]",
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