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         "type" : "Publication",
         "id"   : "https://puma.ub.uni-stuttgart.de/bibtex/2ae09c70116dd2cd28996bf4d02346381/brasche",         
         "tags" : [
            "Bismuth","Chain_structures","Conducting_materials","Layered_materials","Magnetoresistance","Subvalent_compounds","chain_structure","layered_materials","magnetoresistance","subvalent_compounds"
         ],
         
         "intraHash" : "ae09c70116dd2cd28996bf4d02346381",
         "interHash" : "5307727e14e27904993c18268fd0d66e",
         "label" : "Optimized Synthesis of the Bismuth Subiodides Bi$_m$I$_4$ (m = 4, 14, 16, 18) and the Electronic Properties of Bi$_14$I$_4$ and Bi$_18$I$_4$",
         "user" : "brasche",
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         "date" : "2024-03-25 12:35:57",
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         "pub-type": "article",
         "journal": "Eur. J. Inorg. Chem.",
         "year": "2017", 
         "url": "https://onlinelibrary.wiley.com/doi/abs/10.1002/ejic.201700999", 
         
         "author": [ 
            "Alexander Weiz","Lê Anh Mai","Martin Kaiser","Bertold Rasche","Thomas Herrmannsdörfer","Thomas Doert","Michael Ruck"
         ],
         "authors": [
         	
            	{"first" : "Alexander",	"last" : "Weiz"},
            	{"first" : "Lê",	"last" : "Anh Mai"},
            	{"first" : "Martin",	"last" : "Kaiser"},
            	{"first" : "Bertold",	"last" : "Rasche"},
            	{"first" : "Thomas",	"last" : "Herrmannsdörfer"},
            	{"first" : "Thomas",	"last" : "Doert"},
            	{"first" : "Michael",	"last" : "Ruck"}
         ],
         "volume": "2017","number": "47","pages": "5609--5615","abstract": "We optimized the syntheses of α? and ??Bi4I4 and transferred the method to the very bismuth?rich iodides Bi14I4, Bi16I4, and Bi18I4. Phase?pure, microcrystalline powders of BimI4 (m = 4, 14, 18) can now by synthesized on a multigram scale. Conditions for the growth of single crystals of Bi16I4 and Bi18I4 were determined. The redetermination of the crystal structure of Bi16I4 hints at a stacking disorder or the presence of 1∞[BimI4] ribbons with m = 14 and 18 among the dominant type along with m = 16. The electronic band structures for m = 14, 16, and 18 were calculated including spin?orbit coupling. They vary markedly with m and show numerous bands crossing the Fermi level, predicting a 3D?metallic behavior. Measurements of the electrical resistivity of a polycrystalline sample of Bi14I4 as well as polycrystalline and single?crystalline samples of Bi18I4 confirmed their metallic nature over the temperature range 300 K to 2 K. For Bi18I4, a positive and strictly linear magnetoresistance at 2 K in static magnetic fields up to 14 T was observed, which could indicate a topologically nontrivial electronic state.",
         "file" : "ejic201700999-sup-0001-SI1.pdf:files/2934/ejic201700999-sup-0001-SI1.pdf:application/pdf;Weiz et al_Optimized Synthesis of the Bismuth Subiodides BimI4 (m = 4, 14, 16, 18) and the.pdf:files/2932/Weiz et al_Optimized Synthesis of the Bismuth Subiodides BimI4 (m = 4, 14, 16, 18) and the.pdf:application/pdf",
         
         "issn" : "1434-1948",
         
         "doi" : "10.1002/ejic.201700999",
         
         "urldate" : "2018-03-21",
         
         "bibtexKey": "weiz_optimized_2017"

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